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Chemistry on interstellar grains
In this review, our current knowledge of the chemistry that occurs on cold interstellar grain surfaces is examined. The formation of molecular hydrogen from hydrogen atoms is emphasized. Various methods of modeling diffusive reactions on grain surfaces are illustrated, including the rate equation method, and two basic stochastic approaches. The results
E Herbst, Q Chang, H M Cuppen
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Enols represent highly reactive intermediates toward the synthesis of complex organic molecules in the interstellar medium (ISM) and serve as key tracers of nonequilibrium chemistry driven by Galactic cosmic rays.
Michela Nonne +10 more
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Observations of phosphorus-bearing molecules in the interstellar medium
The chemistry of phosphorus (31P) in space is particularly significant due to the key role it plays in biochemistry on Earth. Utilising radio and infrared spectroscopic observations, several key phosphorus-containing molecules have been detected in ...
Francesco Fontani +2 more
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Although oxygenated benzene derivatives are key precursors in the abiotic synthesis of biorelevant molecules and fundamental building blocks of functionalized polycyclic aromatic hydrocarbons, their formation mechanisms under interstellar conditions have
Jia Wang +3 more
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The chemistry of interstellar HnO+: Beyond the galaxy [PDF]
The astrochemistry of the HnO+ (n=1..3) ions is important as the main gas-phase formation route for water, and as tracer of the interstellar ionization rate by cosmic rays and other processes. While interstellar H3O+ has been known since the early 1990's, interstellar OH+ and H2O+ have only recently been detected using the Herschel space observatory ...
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Rotational-state-selected Carbon Astrochemistry
The addition of individual quanta of rotational excitation to a molecule has been shown to markedly change its reactivity by significantly modifying the intermolecular interactions. So far, it has only been possible to observe these rotational effects in
Jutta Toscano
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Gas-surface interactions and heterogeneous chemistry on interstellar grains analogues
Detailed laboratory studies and progress in surface science technique, have allowed in recent years the first experimental confirmation of surface reaction schemes, as introduced by Tielens, Hagen and Charnley [1,2].
Cazaux S. +3 more
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The Chemistry of Cold, Dark Interstellar Clouds [PDF]
In recent years the nearby cold, dark clouds have been shown to possess a rich chemistry, with interesting differences with respect to warmer massive-star-forming regions and also among the cold clouds themselves. 39 molecular species are now known in these regions.
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Carbonaceous meteorites provide the best glimpse into the solar system’s earliest physical and chemical processes. These ancient objects, ~4.56 billion years old, contain evidence of phenomena ranging from solar system formation to the synthesis of
George Cooper +2 more
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Interstellar molecules: guides for new chemistry
Interstellar space is among the most remarkable chemical laboratories in the universe. The existence of many unstable species with low-valent main group elements in the interstellar medium inspired us to investigate the feasibility of laboratory synthesis of such unstable molecules.
Mandal, Swadhin K., Roesky, Herbert W.
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