Results 61 to 70 of about 2,262 (175)

Accelerated Discovery‐to‐Unveiling of High‐Performance and Affordable Ammonia Electrode Process by Human–Machine Collaboration Framework

Angewandte Chemie, Volume 138, Issue 25, 15 June 2026.
By employing dimensionally reduced reaction descriptors, a human–machine collaboration framework for efficient electrochemical nitrate reduction to NH3 electrocatalysts screening is established and drastically shorten the discovery timeframe. A new kinetic model is established in combination with a rotating ring‐disk electrode, unveiling the pivotal ...
Yingying Cheng, Masaki Takeguchi, Abraham Castro Garcia, Ken Sakaushi   +3 more
wiley   +2 more sources

Organic Chemistry in the H2-bearing, CO-rich Interstellar Ice Layer at Temperatures Relevant to Dense Cloud Interiors

The Astrophysical Journal
Ice chemistry in the dense, cold interstellar medium (ISM) is probably responsible for the formation of interstellar complex organic molecules (COMs). Recent laboratory experiments performed at T ∼ 4 K have shown that irradiation of CO:N _2 ice samples ...
Rafael Martín-Doménech, Alexander DelFranco, Karin I. Öberg, Mahesh Rajappan   +3 more
doaj   +1 more source

Energy Landscapes in Chemical Reactions and Transport

ChemPhysChem, Volume 26, Issue 6, March 15, 2025.
Kinetics/dynamics of chemical reactivity and transport of chemical species in a solid are both determined by the energy landscape in which they take place. Discussing common grounds but also distinct differences may help in advancing the understanding in both fields.
Karl‐Michael Weitzel
wiley   +1 more source

Chemical Kinetics of 2‐, 4‐, and 2,4‐Seleno‐Uracils at Low Temperatures: Tautomerizations and Rotamerizations on Inert Matrices

International Journal of Chemical Kinetics, EarlyView.
ABSTRACT In the interstellar medium, chemical reactions proceed under conditions vastly different to those on Earth; these include extremely low temperatures and densities and take place in the gas phase and on water–ice grains. Understanding the energetics and more importantly the kinetics of such reactions is of relevance to the consequences on how ...
Judith Wurmel, John M. Simmie
wiley   +1 more source

A Theoretical Approach to the Complex Chemical Evolution of Phosphorus in the Interstellar Medium

The Astrophysical Journal, 2023
The study of phosphorus chemistry in the interstellar medium has become a topic of growing interest in astrobiology because it is plausible that a wide range of P-bearing molecules were introduced in the early Earth by the impact of asteroids and comets ...
Marina Fernández-Ruz, Izaskun Jiménez-Serra, Jacobo Aguirre   +2 more
doaj   +1 more source

Size Matters: Barrier Heights and Widths in the Kinetics Of Tautomerisation and Rotamerisation of Thiotropolone and Its Five‐ and Three‐Membered Cyclic Analogues

International Journal of Chemical Kinetics, EarlyView.
ABSTRACT Recent experiments by Nunes et al. have demonstrated that unprecedented control of chemical reactions is possible by narrowband infrared vibrational photo‐excitation at low temperatures in inert matrices. The generated higher energy level conformers may then undergo rotamerisation and tautomerisation reactions which provide extremely useful ...
Judith Wurmel, John M. Simmie
wiley   +1 more source

Strong inverse kinetic isotope effect observed in ammonia charge exchange reactions

Nature Communications, 2020
Inverse kinetic isotope effects (KIEs) are rarely observed. Here, the authors report an inverse KIE in the charge transfer reaction of $${{\rm{Xe}}}^{+}$$ Xe+ with ammonia.
L. S. Petralia, A. Tsikritea, J. Loreau, T. P. Softley, B. R. Heazlewood   +4 more
doaj   +1 more source

From Flybys to Sample Return: A Review of Space Probes and Robotic Sampling Technologies for Small Bodies

Journal of Field Robotics, EarlyView.
ABSTRACT As a crucial puzzle piece of deep space exploration, exploring small bodies can provide significant scientific insights and valuable mineral resources. Unlike missions to the Moon and Mars, small‐body missions pose distinct technical challenges, including communication delays, weak gravity, and uncertain environments. This paper reviews a full
Xin Zhang, Hao Zhou, Dalin Zhou, Zhaojie Ju   +3 more
wiley   +1 more source

Different Frontier, Same Legal Script? On the Course of Replicating Earth's Patterns in Space

The Modern Law Review, EarlyView.
As states and private actors expand their activities in outer space, the international legal framework governing this domain risks extending longstanding structures of global inequality beyond Earth. This article examines how international space law, shaped by a broader disciplinary pattern of reactive legal development, is poised to reproduce ...
Sivan Shlomo‐Agon, Michal Saliternik
wiley   +1 more source

The nature of interstellar dust as revealed by light scattering

Atti della Accademia Peloritana dei Pericolanti : Classe di Scienze Fisiche, Matematiche e Naturali, 2011
Interstellar dust was first identified through the extinction that it causes of optical starlight. Initially, observational and theoretical studies of extinction were made to identify simple ways of removing the effect of extinction.
D. A. Williams
doaj   +1 more source