Results 81 to 90 of about 2,302 (180)
Rotational-state-selected Carbon Astrochemistry
The addition of individual quanta of rotational excitation to a molecule has been shown to markedly change its reactivity by significantly modifying the intermolecular interactions. So far, it has only been possible to observe these rotational effects in
Jutta Toscano
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Gas-surface interactions and heterogeneous chemistry on interstellar grains analogues
Detailed laboratory studies and progress in surface science technique, have allowed in recent years the first experimental confirmation of surface reaction schemes, as introduced by Tielens, Hagen and Charnley [1,2].
Cazaux S. +3 more
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Carbonaceous meteorites provide the best glimpse into the solar system’s earliest physical and chemical processes. These ancient objects, ~4.56 billion years old, contain evidence of phenomena ranging from solar system formation to the synthesis of
George Cooper +2 more
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Interstellar dust grains are enveloped by ices of frozen molecules in cold, dense regions of the interstellar medium (ISM), which are also observed in the gas phase. Whether a species is in the solid or gaseous state is governed by its binding energy (BE)
Harjasnoor Kakkar +4 more
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The formation of C4H3N isomers (1-cyano-cyclopropene, propargyl cyanide, cyanoallene, cyanopropyne, and their isonitrile analogs) via radical association and hydrogen migration reactions between propargyl (CH2CCH) and cyano (CN) radicals was investigated
Parmanand Pandey +8 more
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Organic synthesis applied to space sciences
About 160 molecules have been detected in the interstellar medium, the comae and the atmospheres of planets. The presence of these compounds leads to imagine a chemistry of these media to explain the formation of these species and to predict the possible
Guillemin J.-C.
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Can Cyanide Radicals Drive Molecular Backbone Growth on Interstellar Icy Grains?
Motivated by the value of CN-bearing molecules as tracers of interstellar physical conditions, we investigate the reactions of adsorbed CN radicals with acetylene and ethylene (C _2 H _2 and C _2 H _4 ) on interstellar dust-grain analogs using quantum ...
Germán Molpeceres, Joan Enrique-Romero
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Hydrogen chloride (HCl) is a key repository of chlorine in the interstellar medium. Accurate determinations of its abundance are critical to assessing the chlorine elemental abundance and constraining stellar nucleosynthesis models.
Daniel Hoffman +7 more
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Carbon-chain chemistry in the interstellar medium
AbstractThe presence of carbon-chain molecules in the interstellar medium (ISM) has been known since the early 1970s and $>130$ > 130 such species have been identified to date, making up $\sim 43$ ∼ 43 % of the total of detected ISM molecules.
Taniguchi, Kotomi +2 more
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