Mid-infrared Spectroscopy of Protonated Benzonitrile, 2-Cyanonaphthalene, and 9-Cyanoanthracene for Astrochemical Consideration. [PDF]
Experimental infrared absorption spectra of three protonated cyano‐substituted PAHs measured by infrared multiple photon dissociation using the free‐electron laser Free‐Electron Laser for Infrared eXperiments are studied. These spectra are compared to an emission spectrum measured by JWST, and the largest measured protonated cyano‐PAH, cyanoanthracene,
Rasmussen AP +6 more
europepmc +2 more sources
Shaken or Stirred: The Diffuse Interstellar Medium with Exceptionally High SiO Abundance
Interstellar shocks, a key element of stellar feedback processes, shape the structure of the interstellar medium (ISM) and are essential for the chemistry, thermodynamics, and kinematics of interstellar gas.
Daniel R. Rybarczyk +2 more
doaj +1 more source
Atomistic Modeling of Methyl Formate and Glycolaldehyde Formation on Interstellar Dirty Ice Mantles via a "Radical + Ice" Mechanism. [PDF]
The presence of interstellar complex organic molecules (COMs) has been baffling astrochemists for a long time. Methyl formate and glycolaldehyde are widely detected but their abundances mismatch kinetic astrochemical model predictions. Here, the formation of these two COMs is characterized onto a mixed ice surface, highlighting the importance of ...
Perrero J +3 more
europepmc +2 more sources
Molecular Precursors of the RNA-World in Space: New Nitriles in the G+0.693−0.027 Molecular Cloud
Nitriles play a key role as molecular precursors in prebiotic experiments based on the RNA-world scenario for the origin of life. These chemical compounds could have been partially delivered to the young Earth from extraterrestrial objects, stressing the
Víctor M. Rivilla +15 more
doaj +1 more source
The interstellar cloud surrounding the Sun: a new perspective [PDF]
Aims: We offer a new, simpler picture of the local interstellar medium, made of a single continuous cloud enveloping the Sun. This new outlook enables the description of a diffuse cloud from within and brings to light some unexpected properties. Methods:
C. Gry +2 more
semanticscholar +1 more source
Profiles of interstellar cloud filaments. Observational effects in synthetic sub-millimetre observations [PDF]
Sub-millimetre observations suggest that the filaments of interstellar clouds have rather uniform widths and can be described with the so-called Plummer profiles. The shapes of the filament profiles are linked to their physical state.
M. Juvela, J. Malinen, T. Lunttila
semanticscholar +1 more source
Diffuse Interstellar Clouds [PDF]
AbstractDiffuse clouds are interstellar objects through which starlight is not greatly extinguished. As a result, many studies rely on ultraviolet and visible measurements. The focus of this review is on spectroscopic work involving atomic and molecular lines. From these measurements, the physical and chemical makeup of the clouds is derived.
David L. Lambert, S. R. Federman
openaire +1 more source
High‐Pressure Carbonaceous Phases as Minerals
This book is Open Access. A digital copy can be downloaded for free from Wiley Online Library.
Explores the behavior of carbon in minerals, melts, and fluids under extreme conditions
Carbon trapped in diamonds and carbonate-bearing rocks in subduction zones are examples of the continuing exchange of substantial carbon ...
Oliver Tschauner
wiley +1 more source
Gas-grain chemistry in cold interstellar cloud cores with a microscopic Monte Carlo approach to surface chemistry [PDF]
Aims. We have recently developed a microscopic Monte Carlo approach to study surface chemistry on interstellar grains and the morphology of ice mantles.
Q. Chang +8 more
semanticscholar +1 more source
Inhomogeneity within Local Interstellar Clouds*
Abstract Analysis of interstellar absorption lines observed in high-resolution Hubble Space Telescope spectra of nearby stars provides temperatures, turbulent velocities, and kinetic properties of warm interstellar clouds. A new analysis of 97 interstellar-velocity components reveals a wide range of temperatures and turbulent velocities ...
Jeffrey L. Linsky +3 more
openaire +2 more sources

