Results 31 to 40 of about 4,278 (180)

The Rich Chemistry of Ionized Methanol With Sulfur Dioxide: Pathways to Prebiotic and Elusive Species in Earth's Atmosphere and Space

open access: yesChemistry – A European Journal, EarlyView.
The reaction between the methanol radical cation and sulfur dioxide is remarkably fast and forms several ionic and neutral products (HOSOH+, CH2OSO+, CH2OH+, CH2O, H2O, HSO2). The chemistry goes beyond simple proton or hydrogen transfer, revealing a close interaction between the two species, relevant to atmospheric and astrochemical environments where ...
Mauro Satta   +3 more
wiley   +1 more source

Clathrate hydrate crystallization

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Clathrate hydrate crystallization has been an area of interest to chemical engineers from the point of view of crystal structure, thermophysical properties, phase equilibria, kinetics, industrial applications, and environmental (climate change) implications.
Peter Englezos
wiley   +1 more source

First Photometric, Orbital Period, and Tidal Instability Investigations for Four Contact Binaries with Extremely Low Mass Ratios

open access: yesThe Astronomical Journal
Contact binaries with extremely low mass ratios, known as the most plausible progenitors of luminous red novae, are critical targets for refining theoretical models of binary mergers and investigating the lower mass ratio limit of contact binaries.
Yun-Xia Yu   +5 more
doaj   +1 more source

Charge State Influence on Stability and Isomerism in Dehydrogenated PAHs: Insights from Anthracene, Acridine, and Phenazine

open access: yesChemPhysChem, Volume 26, Issue 6, March 15, 2025.
The ionization of anthracene, acridine, and phenazine has been explored, along with the removal of one and two hydrogen atoms, to provide valuable information for astrochemists and to understand the behavior of the resulting structures and their electronic reorganization. Abstract In this study, we systematically explored the stability and isomerism of
Khaldia Zghida   +3 more
wiley   +1 more source

Energy Landscapes in Chemical Reactions and Transport

open access: yesChemPhysChem, Volume 26, Issue 6, March 15, 2025.
Kinetics/dynamics of chemical reactivity and transport of chemical species in a solid are both determined by the energy landscape in which they take place. Discussing common grounds but also distinct differences may help in advancing the understanding in both fields.
Karl‐Michael Weitzel
wiley   +1 more source

Interstellar Pathfinder — A Mission to the Inner Edge of the Interstellar Medium [PDF]

open access: yesAIP Conference Proceedings, 2003
Interstellar Pathfinder (ISP), our first step into the interstellar medium, is a scientific investigation to study the outer boundary of our heliosphere and the interstellar matter that flows into it. A wind of interstellar neutral gas penetrates to within several astronomical units (AU) of the Sun, giving us a direct sample of present‐day galactic ...
McComas, D. J.   +18 more
openaire   +4 more sources

Chemical Kinetics of 2‐, 4‐, and 2,4‐Seleno‐Uracils at Low Temperatures: Tautomerizations and Rotamerizations on Inert Matrices

open access: yesInternational Journal of Chemical Kinetics, EarlyView.
ABSTRACT In the interstellar medium, chemical reactions proceed under conditions vastly different to those on Earth; these include extremely low temperatures and densities and take place in the gas phase and on water–ice grains. Understanding the energetics and more importantly the kinetics of such reactions is of relevance to the consequences on how ...
Judith Wurmel, John M. Simmie
wiley   +1 more source

Size Matters: Barrier Heights and Widths in the Kinetics Of Tautomerisation and Rotamerisation of Thiotropolone and Its Five‐ and Three‐Membered Cyclic Analogues

open access: yesInternational Journal of Chemical Kinetics, EarlyView.
ABSTRACT Recent experiments by Nunes et al. have demonstrated that unprecedented control of chemical reactions is possible by narrowband infrared vibrational photo‐excitation at low temperatures in inert matrices. The generated higher energy level conformers may then undergo rotamerisation and tautomerisation reactions which provide extremely useful ...
Judith Wurmel, John M. Simmie
wiley   +1 more source

Turbulence in the molecular interstellar medium [PDF]

open access: yesProceedings of the International Astronomical Union, 2006
AbstractThe observational record of turbulence within the molecular gas phase of the interstellar medium is summarized. We briefly review the analysis methods used to recover the velocity structure function from spectroscopic imaging and the application of these tools on sets of cloud data.
Heyer, M. H., Brunt, C.
openaire   +2 more sources

From Flybys to Sample Return: A Review of Space Probes and Robotic Sampling Technologies for Small Bodies

open access: yesJournal of Field Robotics, EarlyView.
ABSTRACT As a crucial puzzle piece of deep space exploration, exploring small bodies can provide significant scientific insights and valuable mineral resources. Unlike missions to the Moon and Mars, small‐body missions pose distinct technical challenges, including communication delays, weak gravity, and uncertain environments. This paper reviews a full
Xin Zhang   +3 more
wiley   +1 more source

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