Results 111 to 120 of about 28,603 (262)

High‐Efficiency TADF Dendritic Emitters Enabled by Synchronously Inhibiting Degenerated Triplet Excited States and Structural Relaxation Toward Solution‐Processed OLEDs with EQE Over 33%

open access: yesAdvanced Science, EarlyView.
Asymmetrical thermally activated delated fluorescence dendritic emitters are delicately constructed through symmetry breaking strategy, and near‐unity photoluminescence efficiency and excellent reverse intersystem crossing process are achieved via breaking the degeneracy of vibrational levels and boosting the spin flip of triplet excitons.
Xiaoxiang Yu   +9 more
wiley   +1 more source

Photochemical Cyclization of Tertiary Buta‐2,3‐dienamides to β‐Lactams Upon Triplet Energy Transfer

open access: yesAngewandte Chemie, EarlyView.
Energy transfer is the key to the successful photocyclization of the title compounds to 3,4‐disubstituted 2‐azetidinones. If the substituent at the nitrogen atom is primary (R2 = H), trans products are formed exclusively. The triplet state of xanthen‐9‐one (XT) was found to be quenched by an allene amide (R, R2 = H, R1 = Bn, and R3 = Ph) with a ...
Johannes Hofer   +3 more
wiley   +2 more sources

Highly sensitive switching of solid-state luminescence by controlling intersystem crossing

open access: yesNature Communications, 2018
The development of intelligent materials, in particular those showing the highly sensitive mechanoresponsive luminescence (MRL), remains challenging. Here the authors report a strategy for constructing high performance On-Off MRL materials by introducing
Weijun Zhao   +10 more
doaj   +1 more source

Magnetocatalytic Adiabatic Spin Torque Orbital Transformations for Novel Chemical and Catalytic Reaction Dynamics: The Little Effect [PDF]

open access: yes, 2006
In this manuscript the theory and phenomena associated with the Little Effect are introduced as the spin induced orbital dynamics of confined fermions under strong magnetic and thermal environments.
Little, Reginald B.
core  

Aggregation‐Induced Resonance Energy Transfer in Polymer Dots to Boost Electrochemiluminescence Performance for Bioimaging of Glycan on Cells

open access: yesAdvanced Science, EarlyView.
This study pioneers an aggregation‐induced resonance energy transfer mechanism by synergistically integrating aggregation‐induced emission (AIE), resonance energy transfer (RET), and thermally activated delayed fluorescence (TADF) within co‐reactant conjugated polymers to develop self‐enhanced ECL emitters, which achieves an ECL efficiency up to 92.6 ...
Chao Wang   +6 more
wiley   +1 more source

Integrated Optoelectronic Model to Predict the External Quantum Efficiency of Single‐Layer TADF Organic Light‐Emitting Diodes

open access: yesAdvanced Electronic Materials, EarlyView.
An experimentally validated optoelectronic device model is presented to describe the efficiency and roll‐off behavior of single‐layer TADF OLEDs. By coupling charge transport, exciton dynamics, and optical outcoupling, the model reproduces the External Quantum Efficiency (EQE) across different emission layer thicknesses and temperatures, offering ...
Jawid Nikan   +4 more
wiley   +1 more source

Extended Fused Carbazole‐BODIPY, High Brightness NIR Organic Dyes

open access: yesAngewandte Chemie, EarlyView.
Highly fused boron‐dipyrromethene (BODIPY) with a strong donor group has been synthesized, and their photophysical behaviors fully characterized. They exhibit outstanding brightness for fluorophores emitting in the NIR region. Water‐soluble nanoparticles filled with one of these dyes demonstrate high efficiency as the NIR II visualization agent ...
Fabien Ceugniet   +9 more
wiley   +2 more sources

Bodipy Derivatives as Triplet Photosensitizers and the Related Intersystem Crossing Mechanisms

open access: yesFrontiers in Chemistry, 2019
Recently varieties of Bodipy derivatives showing intersystem crossing (ISC) have been reported as triplet photosensitizers, and the application of these compounds in photocatalysis, photodynamic therapy (PDT), and photon upconversion are promising.
Kepeng Chen   +8 more
doaj   +1 more source

A program to evaluate dye lasers as high power, pulsed, visible light sources [PDF]

open access: yes
Spectral emission of visible from Q switched dye ...
Bass, M., Deutsch, T., Weber, M.
core   +1 more source

Near‐Infrared‐Light‐Driven Photochemistry and Photocatalysis: Mechanisms, Recent Applications, and Opportunities in Organic Synthesis and Biology

open access: yesAngewandte Chemie, EarlyView.
This minireview highlights recent advances in catalyst development and mechanistic strategies that enable photochemical and photocatalytic reactivity under 700–1000 nm NIR light, emphasizing how long‐wavelength excitation expands opportunities in both synthetic chemistry and biology.
Santosh K. Pagire   +3 more
wiley   +2 more sources

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