Results 141 to 150 of about 104,018 (309)

Aggregation in carbon dots

open access: yesAggregate, Volume 3, Issue 6, December 2022., 2022
Carbon dots (CDs) has excellent photoluminescence properties. Aggregation plays an important role in both the formation of CDs and their fluorescence, yet is seldom studied in detail. This review aims to fill this knowledge gap. We first discuss how aggregation leads to the formation of different types of CDs, and the impact on morphology, luminescence,
Yi Ru   +2 more
wiley   +1 more source

Thermally Activated Delayed Fluorescence and Beyond. Photophysics and Material Design Strategies.

open access: yesAdvanced Photonics Research, EarlyView.
Photophysical properties of TADF molecules are determined by characteristic parameters that are discussed in detail(. Moreover, using femtosecond time‐resolved spectroscopy, quantum mechanical considerations, and state‐of‐art calculations, deeper understanding allows us to design breakthrough Cu(I) and organic TADF‐ OLED materials. For the latter ones,
Hartmut Yersin, Uwe Monkowius
wiley   +1 more source

Brønsted Acid‐Catalyzed Enantioselective and Para‐Selective Addition of Phenols to 1‐Alkynylnaphth‐2‐Ols

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract A chiral Brønsted acid‐catalyzed synthesis of axially chiral alkenes was developed via an enantioselective and para‐selective Friedel–Crafts reaction between phenols and 1‐alkynylnaphth‐2‐ols. This methodology features an efficient hydroarylation with high functional group tolerance, complete para‐selectivity, excellent yields (up to 99%), and
Anjali Dahiya   +8 more
wiley   +1 more source

Modular Synthesis of 2,3,4,6‐Tetrasubstituted Thieno[2,3‐c]furans Based on Formal [3+2] Cycloaddition Utilizing [1,2]‐Phospha‐Brook Rearrangement / Brønsted Base‐Mediated Cyclization Strategy

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract A modular synthesis of 2,3,4,6‐tetrasubstituted thieno[2,3‐c]furans, which employs a formal [3+2] cycloaddition utilizing the [1,2]‐phospha‐Brook rearrangement and a subsequent Brønsted base‐mediated cyclization, has been established, providing an efficient access to a wide range of densely functionalized thieno[2,3‐c]furans that are otherwise
Azusa Kondoh   +2 more
wiley   +1 more source

Picomolar Detection of Tau Protein Using 1D Photonic Crystal Biochips for Alzheimer's Disease Diagnosis

open access: yesAdvanced Sensor Research, EarlyView.
Elevated levels of Tau in cerebrospinal fluids or other body fluids are associated with the progression of Alzheimer's disease. An optical technique, based on a dual label‐free and fluorescence operation mode, is developed to detect Tau protein in both standard running buffer and cerebrospinal fluid.
Alberto Sinibaldi   +7 more
wiley   +1 more source

Synthesis of Rhodamine TEMPO Conjugates via Isonitrile‐Based Multicomponent‐Reactions for Mitochondria‐Targeted ROS‐Detection in Cancer Cells

open access: yesAdvanced Sensor Research, EarlyView.
This article explores the development of rhodamine TEMPO conjugates via the Ugi‐multicomponent reaction to detect reactive oxygen species (ROS) in living cells. The sensors are highly selective for mitochondria in both cancer and normal cell lines, with fluorescence quenching and EPR spectroscopy offering precise ROS detection.
Haider N. Sultani   +6 more
wiley   +1 more source

High‐Sensitivity Dopamine Detection with Copper Terephthalate‐Modified Carbon Electrode

open access: yesAdvanced Sensor Research, EarlyView.
This work introduces a facile synthesis of a copper‐terephthalate with a flake‐like morphology and layered topology. The Cu‐BDC demonstrates exceptional performance as a glassy carbon electrode modifier, enabling highly sensitive and reliable dopamine detection.
Aleksander Ejsmont   +3 more
wiley   +1 more source

Upcycling Canola: Closed‐Loop Water Retting System for Sustainable Fiber Production from Waste Canola Stalks

open access: yesAdvanced Sustainable Systems, EarlyView.
The closed‐loop gravitational retting system accelerates fiber extraction, making it the fastest known water retting technique. It efficiently produces high‐quality canola fiber while preserving its structure. Additionally, it minimizes carbon emissions, supporting sustainability.
Md Shadhin   +7 more
wiley   +1 more source

Insights into the Dynamics and Binding Mechanisms of the Alkhumra Virus NS2B/NS3 Protease: A Molecular Dynamics Study

open access: yesAdvanced Theory and Simulations, EarlyView.
The ΔRMSF$\Delta {\rm RMSF}$ analysis reveals significant flexibility differences between free NS3 and the NS2B/NS3 complex, with notable deviations in specific regions. Key residues driving NS2B binding are identified, and the protonation state of catalytic serine affects oxyanion hole formation.
Jurica Novak   +2 more
wiley   +1 more source

Mechanochemistry: Fundamental Principles and Applications

open access: yesAdvanced Science, EarlyView.
In this review, the physicochemical principles of mechanochemistry are first clarified. Based on this foundation, the research basis and cutting‐edge scientific achievements in four areas are introduced: solid‐state organic chemistry, polymers, interface science, and biomechanochemistry.
Liang Dong   +4 more
wiley   +1 more source

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