Electrochemical Functionalization of Graphene‐on‐Cu(111): Reactivity, Onset Potentials, and Mechanistic Insights [PDF]
Electrochemical functionalization of graphene facilitates simple and various modifications of graphene properties. However, the scope of the available functional groups and the electrochemical behavior of graphene is not fully understood.
Minhyeok Kim +4 more
doaj +2 more sources
Parallel Palladium-Catalyzed Synthesis of Carboxylic Acids from Aryl Iodides, Bromides, and Vinyl Triflates Using Acetic Anhydride and Formate Anion as an External Condensed Source of Carbon Monoxide [PDF]
Aryl iodides, bromides and vinyl-triflates are usually converted in high to excellent yields into the corresponding carboxylic acids through a parallel palladium-catalyzed hydroxycarbonylation using lithium formate and acetic anhydride as external ...
Antonia Iazzetti +6 more
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Assembly of (hetero)aryl sulfilimines via copper-catalyzed enantioselective S-arylation of sulfenamides with (hetero)aryl Iodides [PDF]
The (hetero)aryl sulfoximines are important structures for developing bioactive molecules, whose synthesis relies on oxidation of (hetero)aryl sulfilimines. However, asymmetric approaches for assembling (hetero)aryl sulfilimines are still rare.
Mingchuang He +4 more
doaj +2 more sources
The title compound, 5-hydroxy-N,N,N-trimethyltryptammonium (5-HTQ) iodide {systematic name: [2-(5-hydroxy-1H-indol-3-yl)ethyl]trimethylazanium iodide}, C13H19N2O+·I−, has a single tryptammonium cation and one iodide anion in the asymmetric unit. The ions are held together by N—H...I and O—H...I hydrogen bonds in infinite chains along [100].
Duyen N. K. Pham +3 more
openaire +3 more sources
Facile Solvent-Free Mechanochemical Synthesis of UI3 and Lanthanoid Iodides
Lewis base-free lanthanoid (Ln) and actinoid (An) iodides are difficult to obtain, as standard protocols describe syntheses in solutions of donor solvents which are ultimately hard to remove. We have now established a mechanochemical approach towards the
Daniel Werner +6 more
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A simple and highly effective methodology for the cross-coupling of heteroaryl iodides with NN–AuPPh3 at room temperature is reported. The protocol is based on a novel catalytic system consisting of Pd2(dba)3·CHCl3 and the phosphine ligand MeCgPPh having
Igor Zayakin +5 more
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Solvent-Free Synthesis of Aryl Iodide Using Nano SiO2/HIO4 as a Reusable Acid Catalyst [PDF]
An efficient and environmentally benign method for the synthesis of aryl iodides have been developed by diazotization of aromatic amines with NaNO2 and nanosilica periodic acid (nano-SPIA) as a green catalyst via grinding followed by a sandmeyer ...
A. Bamoniri +2 more
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Luminescent materials in the form of glass ceramic
In this paper an original method for obtaining glass ceramic samples based on iodides of alkaline-earth elements activated by Eu2+ is proposed, their structural and spectral-luminescent properties are studied.
Tatsiana A. Salamakha +2 more
doaj +1 more source
Benzazole derivatives: V. The reactivity of some 2-p-tolyl-and 2-p-methylstyryl-benzimidazolium salts [PDF]
The reactivity of the p-substituted methyl group in 1-methyl-2-p-tolylbenzimidazolium and 1-methyl-2-p-methylstyrylbenzimidazolium iodides with p-nitroso-dimethylaniline (p-NDMA) and aromatic aldehydes was studied.
Cernatescu Corina, Comanita Eugenia
doaj +1 more source
Procedures are described for the preparation of alkyl iodides from fatty alcohols and glyceryl ethers. Alkyl iodides were separated directly by gas-liquid chromatography (GLC) on ethylene glycol succinate columns and do not require calibration factors in
Kenneth E. Guyer +3 more
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