Systems silver iodide-sodium iodide and silver iodide-potassium iodide
The phase relations for the systems AgI-NaI and AgI-KI have been determined for the temperature range from room temperature to 685° C, using differential thermal analysis techniques. The AgI-NaI system has a eutectic at 50 mole percent NaI and 384° C. The AgI-KI system has eutectics at 20.8 and 28.5 mole percent KI and 254° C and 244° C, respectively ...
Burley, G., Kissinger, H. E.
openaire +2 more sources
Nickel-Catalyzed Carbonylative Synthesis of Functionalized Alkyl Iodides
Summary: Functionalized alkyl iodides are important compounds in organic chemistry and biology. In this communication, we developed an interesting nickel-catalyzed carbonylative synthesis of functionalized alkyl iodides from aryl iodides and ethers. With
Jin-Bao Peng +5 more
doaj +1 more source
Copper-Catalyzed Arylation of 1\u3cem\u3eH\u3c/em\u3e-Perfluoroalkanes [PDF]
A general method has been developed for arylation of readily available 1H-perfluoroalkanes. The method employs aryl iodide and 1H-perfluoroalkane reagents, DMPU solvent, TMP2Zn base, and a copper chloride/phenanthroline catalyst.
Daugulis, Olafs +2 more
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Long-Term Antithyroid Drug Therapy in Smoldering or Fluctuating-Type Graves’ Hyperthyroidism with Potassium Iodide [PDF]
Graves’ hyperthyroidism is characterized by stimulation of the thyroid gland by thyroid-stimulating hormone receptor antibodies (TRAbs). Antithyroid drug (ATD) continuation is recommended as long as the thyroid gland is stimulated. Goiter size, thyroidal
Ken Okamura
doaj +1 more source
Development of covalent triazine frameworks as heterogeneous catalytic supports [PDF]
Covalent triazine frameworks (CTFs) are established as an emerging class of porous organic polymers with remarkable features such as large surface area and permanent porosity, high thermal and chemical stability, and convenient functionalization that ...
Krishnaraj, Chidharth +3 more
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Regioselective zincation of indazoles using TMP2Zn and Negishi cross-coupling with aryl and heteroaryl iodides. [PDF]
The metalation of various SEM-protected functionalized indazoles with TMP2Zn provides 3-zincated indazoles which undergo palladium-catalyzed Negishi cross-couplings in good ...
Andreas Unsinn +40 more
core +1 more source
Five protocols were first compared for the copper-catalyzed C-N bond formation between 7-azaindole and aryl/heteroaryl iodides/bromides. The 1-arylated 7-azaindoles thus obtained were subjected to deprotometalation-iodolysis sequences using lithium 2,2,6,
Mohamed Yacine Ameur Messaoud +9 more
doaj +1 more source
Acneiform dermatoses are follicular eruptions. The initial lesion is inflammatory, usually a papule or pustule. Comedones are later secondary lesions, a sequel to encapsulation and healing of the primary abscess.
Jansen, Thomas, Plewig, G.
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Facile synthesis of α-alkoxymethyltriphenylphosphonium iodides: new application of PPh3/I2
An efficient one pot method for the synthesis of α-alkoxymethylphosphonium iodides is developed by using PPh3/I2 combination at room temperature.
Humaira Yasmeen Gondal +4 more
doaj +1 more source
Dinuclear platinum(II) sulfide–thiolate complexes [Pt₂(μ-S)(μ-SR)(PPh₃)₄]⁺ containing fluorinated substituents and the identification of a SC₆F₅ π interaction in the crystal structure of [Pt₂(μ-S)(μ-SCH₂C₆F₅)(PPh₃)₄]BPh₄•2C₆H₆ [PDF]
Reactions of the platinum(II) sulfido complex [Pt₂(μ-S)₂(PPh₃)₄] with the alkyl iodides ICH₂CH₂(CF₂)nCF₃ (n = 3, 7) gives good yields of the monoalkylated products [Pt₂(μ-S){μ-SCH₂CH₂(CF₂)nCF₃}(PPh₃)₄]⁺, which were isolated as PF₆⁺or BPH₄⁻ salts, and ...
Henderson, William +2 more
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