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Acneiform dermatoses are follicular eruptions. The initial lesion is inflammatory, usually a papule or pustule. Comedones are later secondary lesions, a sequel to encapsulation and healing of the primary abscess.
Jansen, Thomas, Plewig, G.
core +1 more source
In the title compound, C(7)H(7)N(2) (+)·I(-), the cation is located on a site of 4mm symmetry and is thus disordered about the fourfold axis so that there are two perpendicular orientations of the six-membered ring and four rotational orientations of the {-NH(3) (+)} group.
Joel T. Mague +3 more
openaire +3 more sources
Dinuclear platinum(II) sulfide–thiolate complexes [Pt₂(μ-S)(μ-SR)(PPh₃)₄]⁺ containing fluorinated substituents and the identification of a SC₆F₅ π interaction in the crystal structure of [Pt₂(μ-S)(μ-SCH₂C₆F₅)(PPh₃)₄]BPh₄•2C₆H₆ [PDF]
Reactions of the platinum(II) sulfido complex [Pt₂(μ-S)₂(PPh₃)₄] with the alkyl iodides ICH₂CH₂(CF₂)nCF₃ (n = 3, 7) gives good yields of the monoalkylated products [Pt₂(μ-S){μ-SCH₂CH₂(CF₂)nCF₃}(PPh₃)₄]⁺, which were isolated as PF₆⁺or BPH₄⁻ salts, and ...
Henderson, William +2 more
core +2 more sources
Introduction: Iodine is an important compound in the kelp thallus; it should be determined to control the quality of crude herbal drugs of Laminaria sp.
Alexander V Nikulin +5 more
doaj +1 more source
High throughput synthesis of 2,5-substituted indoles using a titanium carbenoid bearing boronate functionality [PDF]
A titanium benzylidene complex bearing a boronate group converted resin-bound esters into enol ethers. Suzuki cross-coupling with aryl iodides followed by cleavage with acid completed the solid-phase synthesis of 2,5-disubstituted N-Boc-indoles.
Hartley, R.C. +3 more
core +1 more source
Metal‐Free Radical Borylation of Alkyl and Aryl Iodides
A metal‐free radical borylation of alkyl and aryl iodides with bis(catecholato)diboron (B2cat2) as the boron source under mild conditions is introduced.
Ying Cheng +2 more
semanticscholar +1 more source
The solid-state structure of the title salt, C7H7N2 (+.)I(-), consists of cation-anion sheets lying parallel to (110), with the components linked by N-H⋯I hydrogen bonds.
Joel T. Mague +3 more
openaire +3 more sources
Glycerol as a cheap, safe and sustainable solvent for the catalytic and regioselective β,β-diarylation of acrylates over palladium nanoparticles [PDF]
Herein we show that glycerol can be considered as a promising cheap and green solvent for the regioselective β,β-diarylation of alkenes. Whereas this reaction is generally catalyzed under an inert atmosphere by expensive phosphine or carbene-palladium ...
Barrault, Joel +7 more
core +2 more sources
Visible-light promoted atom transfer radical addition-elimination (ATRE) reaction for the synthesis of fluoroalkylated alkenes using DMA as electron-donor [PDF]
Here, we describe a mild, catalyst-free and operationally-simple strategy for the direct fluoroalkylation of olefins driven by the photochemical activity of an electron donor-acceptor (EDA) complex between DMA and fluoroalkyl iodides.
Gu, Jiwei +5 more
core +2 more sources
To show the synthetic utility of palladium/norbornene (Pd/NBE) cooperative catalysis, here we report concise syntheses of indenone-based natural products, pauciflorol F and acredinone A, which are enabled by direct annulation between aryl iodides and ...
Feipeng Liu +3 more
semanticscholar +1 more source

