Results 41 to 50 of about 71,662 (334)

Palladium-catalyzed difluoromethylation of heteroaryl chlorides, bromides and iodides. [PDF]

open access: yes, 2017
A palladium-catalyzed difluoromethylation of a series of heteroaryl chlorides, bromides and iodides under mild conditions is described. A wide range of heteroaryl halides such as pyridyl, pyrimidyl, pyrazyl, funanyl, thienyl, pyazolyl, imidazolyl ...
Gu, Yang   +4 more
core   +1 more source

Crystal structure and Hirshfeld surface analysis of chiral catena-poly[l-histidinediium [[diiodidocuprate(I)]-μ-iodido] monohydrate]

open access: yesActa Crystallographica Section E: Crystallographic Communications
The title compound, {(C6H11N3O2)[CuI3]·H2O}n or (L-HisH2)CuI3·H2O (1), is a chiral organic–inorganic compound that crystallizes in the monoclinic P21 space group.
Valerii Y. Sirenko   +4 more
doaj   +1 more source

A Simple and Effective Protocol for One-Pot Diazotization-Iodination of Aromatic Amines by Acidic Ionic Liquid [H-NMP]HSO4 at Room Temperature [PDF]

open access: yesIranian Journal of Chemistry & Chemical Engineering, 2011
A simple and efficient one-pot method for the preparation of aromatic iodides has been developed by sequential diazotization–iodination of aromatic amines employing sodium nitrite and sodium iodide in the presence of acidic ionic liquid N-methyl-2 ...
Abdolreza Hajipour   +1 more
doaj  

Effect of 2-Substitution on the Rearrangement of 1-Cyclopropylvinyl Cations [PDF]

open access: yes, 1973
2-Substitution in 1-cyclopropylvinyl cations produces a steric effect on cation generation and solvent trapping, but an electronic charge-stabilizing effect on cyclopropyl-to-cyclobutyl ...
Bergman, Robert G., Kelsey, Donald R.
core   +1 more source

Palladium(II)/Cationic 2,2’-Bipyridyl System as a Highly Efficient and Reusable Catalyst for the Mizoroki-Heck Reaction in Water

open access: yesMolecules, 2010
A water-soluble and air-stable Pd(NH3)2Cl2/cationic 2,2’-bipyridyl system was found to be a highly-efficient and reusable catalyst for the coupling of aryl iodides and alkenes in neat water using Bu3N as a base.
Fu-Yu Tsai   +2 more
doaj   +1 more source

Modeling the hydrolysis of perfluorinated compounds containing carboxylic and phosphoric acid ester functions, alkyl iodides, and sulfonamide groups [PDF]

open access: yes, 2009
Temperature dependent rate constants were estimated for the acid- and base-catalyzed and neutral hydrolysis reactions of perfluorinated telomer acrylates (FTAcrs) and phosphate esters (FTPEs), and the SN1 and SN2 hydrolysis reactions of fluorotelomer ...
Kaya Forest, Sierra Rayne
core   +1 more source

An intracellular transporter mitigates the CO2‐induced decline in iron content in Arabidopsis shoots

open access: yesFEBS Letters, EarlyView.
This study identifies a gene encoding a transmembrane protein, MIC, which contributes to the reduction of shoot Fe content observed in plants under elevated CO2. MIC is a putative Fe transporter localized to the Golgi and endosomal compartments. Its post‐translational regulation in roots may represent a potential target for improving plant nutrition ...
Timothy Mozzanino   +7 more
wiley   +1 more source

β‐TrCP overexpression enhances cisplatin sensitivity by depleting BRCA1

open access: yesMolecular Oncology, EarlyView.
Low levels of β‐TrCP (Panel A) allow the accumulation of BRCA1 and CtIP, which facilitate the repair of cisplatin‐induced DNA damage via homologous recombination (HR) and promote tumor cell survival. In contrast, high β‐TrCP expression (Panel B) leads to BRCA1 and CtIP degradation, impairing HR repair, resulting in persistent DNA damage and apoptosis ...
Rocío Jiménez‐Guerrero   +8 more
wiley   +1 more source

Highly stereocontrolled synthesis of trans-enediynes via carbocupration of fluoroalkylated diynes

open access: yesBeilstein Journal of Organic Chemistry, 2012
Treatment of readily prepared (Z)-6-benzyloxy-1,1,1,2-tetrafluoro-6-methyl-2-hepten-4-yne with 1.5 equiv of LHMDS in −78 °C for 1 h gave the corresponding trifluoromethylated diyne in an excellent yield.
Tsutomu Konno   +2 more
doaj   +1 more source

catena-Poly[3,3′-diethyl-1,1′-(propane-1,3-diyl)di(1H-imidazol-3-ium) [silver(I)-di-μ-iodido-silver(I)-di-μ-iodido]]

open access: yesActa Crystallographica Section E, 2012
The title compound, {(C13H22N4)[Ag2I4]}n, was prepared by reaction of 1,3-bis(N-ethylimidazolium-1-yl)propane iodide with silver (I) oxide. In the 3,3′-diethyl-1,1′-(propane-1,3-diyl)di(1H-imidazol-3-ium) cation, the dihedral angle ...
Jian-Zhong Huo   +4 more
doaj   +1 more source

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