Results 61 to 70 of about 3,886 (250)

SO2 Transfer Enabled by an Easy‐to‐Handle Ionic Liquid

open access: yesChemistry – A European Journal, EarlyView.
Best of both worlds: The ionic liquid [NEt3Me][Cl(SO2)n] unites the atom economy and low cost of sulfur dioxide with the safety and applicability of common surrogates, streamlining SO2 transfer to access to 3‐sulfolenes, sulfonamides, and SuFEx reagents.
Johanna S. Sturm   +11 more
wiley   +1 more source

Fluorogenic Sydnones for Bioorthogonal Labeling of DNA

open access: yesChemistry – A European Journal, EarlyView.
Conjugates of sydnones with cyanine‐styryl dyes combine bioorthogonal reactivity with fluorogenicity. The reactivity with bicyclo[6.1.0]non‐4‐yne (BCN)‐modified DNA showed second‐order rate constants of up to k2 = 2,300 M−1s−1 and fluorescence turn‐on by one magnitude of order.
Kerstin Müller   +1 more
wiley   +1 more source

Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
The development of sustainable synthetic methods for cyclic carbonates draws inspiration from nature, focusing on eco‐friendly processes and renewable resources like CO2 and biomass. This review explore various CO2 activation mechanisms, green chemistry principles, and green catalysts.
Erika Saccullo   +4 more
wiley   +1 more source

Associations Between Microbial Depletion and Autonomic Dysregulation in Binge‐Eating Disorder

open access: yesInternational Journal of Eating Disorders, EarlyView.
ABSTRACT Objective The interplay between the gut microbiome and autonomic nervous system remains unexplored in binge‐eating disorder (BED). We aimed to explore specific microbial alterations in BED and examine their potential association with cardiac vagal tone as a distinct bio‐behavioral phenotype.
Shuang Liang   +4 more
wiley   +1 more source

Metal‐Free Halogen‐Engineered Carbon Nanotubes for Highly Efficient Oxygen Reduction Reaction

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
In work employs density functional theory screening to guide the halogen engineering of metal‐free, Cl‐mediated carbon nanotubes for a highly efficient oxygen reduction reaction (ORR). Cl‐mediation optimally tunes the electronic structure and binding energies of oxygen intermediates, delivering an ORR activity rivaling that of commercial Pt/C, high 4e−
Kai Zhao   +11 more
wiley   +1 more source

Sustainable Iron Catalysis for Chemodivergent Oxidation of Lignin‐Based Vanillyl Alcohol: Selective Access to Vanillin and Vanillic Acid

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Green reaction media enable chemodivergent oxidation of vanillyl alcohol, selectively affording vanillin or its fully oxidized counterpart, vanillic acid. The use of an earth‐abundant, inexpensive, and nontoxic iron catalyst for the transformation of lignin‐derived alcohol to fine chemicals underscores the sustainability of the process. A low E‐factor (
Rasmiranjan Hota   +2 more
wiley   +1 more source

Assessment of the effects of microwave‐produced biodiesel blends on electric generator performance and emissions

open access: yesEnvironmental Progress &Sustainable Energy, EarlyView.
Abstract Biodiesels are emerging as alternatives to diesel fuel. However, to be a feasible solution, biodiesels must meet strict criteria including high efficiency and minimal environmental impact. The current study focuses on evaluating ethyl ester biodiesel and its blends with diesel fuel to assess their potential.
Ilham Yahya   +6 more
wiley   +1 more source

Unique deficits in place coding across subfields of the hippocampus in a mouse model of temporal lobe epilepsy

open access: yesEpilepsia, EarlyView.
Abstract Objective Memory problems are comorbid with temporal lobe epilepsy (TLE). Animal models of TLE reveal impairments in spatial firing fields of hippocampal place cells, providing a potential neural substrate for memory problems. Each subfield of the hippocampus carries out unique aspects of spatial memory, yet little is known about how ...
Brittney L. Boublil   +4 more
wiley   +1 more source

Household Coverage of Fortified Staple Food Commodities in Rajasthan, India.

open access: yesPLoS ONE, 2016
A spatially representative statewide survey was conducted in Rajasthan, India to assess household coverage of atta wheat flour, edible oil, and salt. An even distribution of primary sampling units were selected based on their proximity to centroids on a ...
Grant J Aaron   +7 more
doaj   +1 more source

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