Results 1 to 10 of about 401 (106)
Studies of Halogen Bonding Induced by Pentafluorosulfanyl Aryl Iodides: A Potential Group of Halogen Bond Donors in a Rational Drug Design [PDF]
Molecules, 2019 The activation of halogen bonding by the substitution of the pentafluoro-λ6-sulfanyl (SF5) group was studied using a series of SF5-substituted iodobenzenes.
Yuji Sumii +3 more
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Research on Synthesis, Structure, and Catalytic Performance of Tetranuclear Copper(I) Clusters Supported by 2-Mercaptobenz-zole-Type Ligands [PDF]
MoleculesTetrahedral copper(I) clusters [Cu4(MBIZ)4(PPh3)2] (2), [Cu4(MBOZ)4(PPh3)4] (6) (MBIZ = 2-mercaptobenzimidazole, MBOZ = 2-mercaptobenzoxazole) were prepared by regulation of the copper-thiolate clusters [Cu6(MBIZ)6] (1) and [Cu8(MBOZ)8I]− (5) with PPh3 ...
Tingyu Zhu +3 more
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Structural Features of Dihenzoyldioxy-Iodobenzenes
CHIMIA, 1972 Covalent (I) rather than ionic (II) structure has been assigned to dihenzoyldioxy-iodobenzenes.
Božo Plesničar
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Crystals, 2021 In order to study the effect of halogen bond on tautomerism in β-diketones in the solid-state, we have prepared a series of cocrystals derived from an asymmetric β-diketone, benzoyl-4-pyridoylmethane (b4pm), as halogen bond acceptor and perfluorinated ...
Valentina Martinez +3 more
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Crystals, 2021 In order to study the proclivity of primary amine groups to act as halogen bond acceptors, three aromatic diamines (p-phenylenediamine (pphda), benzidine (bnzd) and o-tolidine (otol)) were cocrystallised with three perfluorinated iodobenzenes (1,4 ...
Erik Uran +4 more
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Beilstein Journal of Organic Chemistry, 2015 Pyridine promotes dediazoniation of aryldiazonium tetrafluoroborates. The formed aryl radicals were trapped with B2pin2, iodine, or tetrahydrofuran to afford boronic esters, iodobenzenes and benzenes, respectively.
George Iakobson +3 more
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Polymer-supported Pd(0) catalyst for copper- and ligand-free Sonogashira reactions in aqueous media
Green Processing and Synthesis, 2012 The treatment of commercially available polymethyl methacrylate (PMMA) microspheres with palladium (Pd)Cl2 and formaldehyde, generated supported Pd(0)-PMMA with 0.79 (wt)% catalyst loading.
Yi Wen-Bin +3 more
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One-Pot Synthesis of Hypervalent Diaryl(iodo)bismuthanes from o-Carbonyl Iodoarenes by Zincation
Heteroatom Chemistry, 2019 Diaryl(iodo)bismuthanes possessing a hypervalent C=O•••Bi–I bond were conveniently synthesized in a one-pot reaction by using arylzinc reagents generated from o-carbonyl iodobenzenes and zinc powder under ultrasonication.
Toshihiro Murafuji +6 more
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Photopolymerization of Methyl Methacrylate Initiated by Iodobenzene– Triethylamine and Iodobenzene–Sodium Thiosulfate Systems [PDF]
Polymer Journal, 1972 The photopolymerization of methyl methacrylate was investigated in both iodobenzene–triethylamine and iodobenzene–Sodium thiosulfate systems. The polymerization reactions proceeded according to a radical mechanism, and were initiated by the phenyl radical which was generated by photolysis of iodobenzene.
Sumihiro Sakai +2 more
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3,5-Bis(trifluoromethyl)iodobenzene [PDF]
, 2009 InChI = 1S/C8H3F6I/c9-7(10,11)4-1-5(8(12,13)14)3-6(15)2-4/h1-3H InChIKey = VDPIZIZDKPFXLI-UHFFFAOYSA-N (reagent used as a versatile allylation or arylation component) Physical Data: bp 59–61 °C (10 mmHg); fp 74 °C; d 1.919 g cm^(−3). Solubility: sol DMF, acetonitrile, toluene, and most organic solvents.
Chang, Shuh-Kuen, Oh, Young In
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