Results 31 to 40 of about 420 (124)
It is a challenge to improve the selectivity of high‐denticity ligands for Mg2+ over Ca2+. We show that in aryl‐alkynyl derivatives of APTRA, electron‐withdrawing substituents lower the binding affinity for Ca2+ more than Mg2+, making the ligand more selective for Mg2+.
Laura L. Duncan +2 more
wiley +1 more source
The multi‐component doping strategy, involving self‐assembly, host‐guest systems, and crystal engineering, has gained attention for its simplicity, cost‐effectiveness, structural diversity, and adjustable room‐temperature phosphorescence (RTP). This review summarizes and evaluates the progress in creating RTP materials using this strategy, highlighting
Zhenjie Zhou +10 more
wiley +1 more source
Cu‐Catalyzed Tetrafluoroethylation of Aryl Iodides Using “Safe Supply” Tetrafluoroethylene
Reaction of [CuH(PPh3)]6 with PMePh2 and readily obtained 1:1 CO2: tetrafluoroethylene affords Cu complex 1 that ffects the CuCl(NHC)‐catalysed tetrafluoroethylation of aryl iodides. ABSTRACT The success of Cu‐mediated, late‐stage fluoroalkylation, originally developed for CF3 transfer, has expanded to additional RF groups including C2F5, CF2H, OCF3 ...
Nicholas O. Andrella +4 more
wiley +1 more source
UV photodissociation dynamics of iodobenzene: Effects of fluorination
The UV photochemistry of various fluorinated iodobenzenes (4-fluoro-, 2,4-difluoro-, 3,5-difluoro-, and perfluoro-iodobenzene) has been investigated at many wavelengths by velocity map imaging, time-resolved near infrared absorption spectroscopy and (spin-orbit resolved) ab initio calculations of the ground and excited state potentials along the C–I ...
Murdock, Daniel +3 more
openaire +3 more sources
5-Bromo-1,3-dichloro-2-iodobenzene
The title compound, C6H2BrCl2I, crystallizes in space group P21/c with two molecules in the asymmetric unit. The molecules stack in two different directions, with their plane normals approximately parallel to [110] and [1\overline 10]. The molecules of the asymmetric unit are held together by π–π interactions.
M. Arun Prasad +2 more
openaire +1 more source
2,2'-Bipyridine Derivatives as Halogen Bond Acceptors in Multicomponent Crystals. [PDF]
Kučas F +4 more
europepmc +1 more source
Alkyl Levulinates and 2-Methyltetrahydrofuran: Possible Biomass-Based Solvents in Palladium-Catalyzed Aminocarbonylation. [PDF]
Uzunlu N +3 more
europepmc +1 more source
Palladium-Catalyzed Carbonylative Difunctionalization of Unactivated Alkenes Initiated by Unstabilized Enolates. [PDF]
Zhang P, Newhouse TR.
europepmc +1 more source
A Cascade Sonogashira Cross-Coupling-Substitution-Elimination Reaction for the Synthesis of Linear Conjugated Dienynes. [PDF]
Lumbreras-Teijeiro A +3 more
europepmc +1 more source
The Sulfonation of Iodobenzene. [PDF]
N. Hesselbjerg Christensen +5 more
openaire +1 more source

