Results 151 to 160 of about 561,896 (299)

Photoswitchable Conductive Metal–Organic Frameworks

Advanced Functional Materials, EarlyView.
A conductive material where the conductivity can be modulated remotely by irradiation with light is presented. It is based on films of conductive metal–organic framework type Cu3(HHTP)2 with embedded photochromic molecules such as azobenzene, diarylethene, spiropyran, and hexaarylbiimidazole in the pores.
Yidong Liu, Mersad Mostaghimi, Abhinav Chandresh, Saibal Jana, Wolfgang Wenzel, Lars Heinke   +5 more
wiley   +1 more source

Orthogonal cation and anion template-directed synthesis of a heteroditopic [3]catenane for ion-pair recognition. [PDF]

Chem Sci
Tay HM, Docker A, Martínez-Martínez AJ, Beer PD.   +3 more
europepmc   +1 more source

The Thermodynamics of Formation of Metal Complexes and Ion-Pairs in Solution

Croatica Chemica Acta, 1970
The problem of characterisation of species present at equilibrium in an electrolyte solution is discussed. Shortcomings of the free energy approach are shown due to inadmissible neglect of entropy changes in complex formation. It is shown that complexes formed with hard ligands are stabilised entirely by entropy changes.
openaire   +2 more sources

Advancing Electronic Application of Coordination Solids: Enhancing Electron Transport and Device Integration via Surface‐Mounted MOFs (SURMOFs)

Advanced Functional Materials, EarlyView.
The layer‐by‐layer (LbL) assembly of coordination solids, enabled by the surface‐mounted metal‐organic framework (SURMOF) platform, is on the cusp of generating the organic counterpart of the epitaxy of inorganics. The programmable and sequential SURMOF protocol, optimized by machine learning (ML), is suited for accessing high‐quality thin films of ...
Zhengtao Xu, Christof Wöll, Stefan Bräse   +2 more
wiley   +1 more source

Ion-Pair Mediated Valence Isomerization of Selected Cyclic C₇H₈ Molecules Trapped in Insertion Complexes. [PDF]

Int J Mol Sci
Liang C, Naumkin FY.
europepmc   +1 more source

NanoMOF‐Based Multilevel Anti‐Counterfeiting by a Combination of Visible and Invisible Photoluminescence and Conductivity

Advanced Functional Materials, EarlyView.
This study presents novel anti‐counterfeiting tags with multilevel security features that utilize additional disguise features. They combine luminescent nanosized Ln‐MOFs with conductive polymers to multifunctional mixed‐matrix membranes and powder composites. The materials exhibit visible/NIR emission and matrix‐based conductivity even as black bodies.
Moritz Maxeiner, Ruben Maile, Murat Cuvalli, Andreas Wolf, Ayisha Komal, Robert Oestreich, Christoph Janiak, Karl Mandel, Alexander Knebel, Klaus Müller‐Buschbaum   +9 more
wiley   +1 more source

Ion-Pair Speciation in Aqueous Alkali Fluorides from Nuclear Magnetic Resonance of ¹⁹F. [PDF]

J Phys Chem B
Musiał M, Miller S, Suiter CL, Klem H, Paulechka E, Schwarz KA, Widegren J, Riccardi D.   +7 more
europepmc   +1 more source

Enhancing Low‐Temperature Performance of Sodium‐Ion Batteries via Anion‐Solvent Interactions

Advanced Functional Materials, EarlyView.
DOL is introduced into electrolytes as a co‐solvent, increasing slat solubility, ion conductivity, and the de‐solvent process, and forming an anion‐rich solvent shell due to its high interaction with anion. With the above virtues, the batteries using this electrolyte exhibit excellent cycling stability at low temperatures. Abstract Sodium‐ion batteries
Cheng Zheng, Qian Yao, Yanan Sun, Hongyu Lv, Zhongchao Bai, Guoliang Zhang, Nana Wang, Jian Yang   +7 more
wiley   +1 more source

MnI‐Functionalized Covalent Organic Framework as Efficient Electrocatalyst for CO2 Reduction in a Catholyte‐Free Zero‐Gap Electrolyzer

Advanced Functional Materials, EarlyView.
This work demonstrates the successful integration of a phenanthroline‐based 2D COF with MnI catalytic sites into a catholyte‐free membrane‐electrode‐assembly cell for CO2 electroreduction. The crystalline COF actively suppresses Mn⁰–Mn⁰ dimerization, achieving a turnover frequency of 617 h⁻¹ at 2.8 V (full‐cell potential), and enabling stable operation.
Laura Spies, Marcos Eduardo G. Carmo, Gonçalves J. Marrenjo, Stephan Reuther, Patrick Ganswindt, Antonio Otavio T. Patrocinio, Thomas Bein, Osmando F. Lopes, Jenny Schneider   +8 more
wiley   +1 more source

La³⁺ Networks and Speciation in the Molten State: Impact of Spacer Salt Selection on Structural Heterogeneity. [PDF]

J Am Chem Soc
Borah B, Emerson MS, Roy S, Ferrari JJ, Chapman KW, Gallington LC, Dhakal D, Kim EM, Halstenberg PW, Dai S, Gill SK, Wishart JF, Margulis CJ.   +12 more
europepmc   +1 more source