Results 121 to 130 of about 85,178 (371)

Computational Studies of Ruthenium and Iridium Complexes for Energy Sciences and Progress on Greener Alternatives [PDF]

open access: yesarXiv, 2020
The energy sciences attempt to meet the increasing world-wide need for energy, as well as sustainability goals, by cleaner sources of energy, by new alternative sources of energy, and by more efficient uses of available energy. These goals are entirely consistent with the principles of green chemistry.
arxiv  

A General Cyanine‐Based Platform for Designing Robust Dual‐Channel Near‐Infrared Fluorescent and Photoacoustic Probes

open access: yesAdvanced Functional Materials, EarlyView.
The study presents a general cyanine‐based platform CySN for designing robust dual‐channel near‐infrared fluorescent (NIRF) and photoacoustic (PA) probes with high ratiometric signals change. CySN enables the construction of highly sensitive and selective dual‐channel NIRF/PA probes for both small molecule and enzyme biomarkers (H2O2, esterase ...
Pingzhou Wu   +14 more
wiley   +1 more source

Unexpected Molecular Structure of a Putative Rhenium‐Dioxo‐Benzocarbaporphyrin Complex. Implications for the Highest Transition Metal Valence in a Porphyrin‐Type Ligand Environment

open access: yesChemistryOpen, 2019
A combination of quantum chemical calculations and synthetic studies was used to address the possibility of very high (>6) valence states of transition metals in porphyrin‐type complexes. With corrole as a supporting ligand, DFT calculations ruled out Re(
Dr. Abraham B. Alemayehu   +3 more
doaj   +1 more source

Selective formation of γ-lactams via C–H amidation enabled by tailored iridium catalysts

open access: yesScience, 2018
Guiding nitrenes away from a migration Nitrogen conventionally shares its electrons in three bonds with one or more partners. A singly bonded nitrogen, or nitrene, is exceptionally reactive and can insert itself into normally inert C–H bonds.
S. Hong   +5 more
semanticscholar   +1 more source

Active Hydrogen for Electrochemical Ammonia Synthesis

open access: yesAdvanced Functional Materials, EarlyView.
This review provides a comprehensive overview of the active hydrogen (H*) for electrochemical ammonia synthesis with particular attention given to the regulation of H* generation and consumption to suppress the competition of hydrogen evolution reaction and enhance the yield, selectivity, and Faradaic efficiency of ammonia.
Guoqiang Gan, Guo Hong, Wenjun Zhang
wiley   +1 more source

[(η5-pentamethylcyclopentadienyl)(3-fluoro-N-methylbenzylamine-к1,N)dichlorido]iridium(III)

open access: yesMolbank, 2018
A half-sandwich iridium(III) complex containing 3-fluoro-N-methylbenzylamine ligands has been obtained by reaction of one equivalent of [(η5-Cp*)IrCl2]2 (Cp* = pentamethylcyclopentadienyl) with two equivalent of 3-fluoro-N-methylbenzylamine in very ...
Deliang Kong   +4 more
doaj   +1 more source

Iridium(I), Iridium(III), and Iridium(V) Complexes Containing the (2-Methoxyethyl)cyclopentadienyl Ligand

open access: yesOrganometallics, 2006
Peer ...
Esteruelas, Miguel A.   +4 more
openaire   +3 more sources

The Common Intermediates of Oxygen Evolution and Dissolution Reactions during Water Electrolysis on Iridium

open access: yesAngewandte Chemie, 2018
Understanding the pathways of catalyst degradation during the oxygen evolution reaction is a cornerstone in the development of efficient and stable electrolyzers, since even for the most promising Ir based anodes the harsh reaction conditions are ...
O. Kasian   +4 more
semanticscholar   +1 more source

Highly‐Entangled Hydrogel Electrolyte for Fast Charging/Discharging Properties in Aqueous Zinc Ion Batteries

open access: yesAdvanced Functional Materials, EarlyView.
A highly‐entangled polyacrylamide (HE‐PAM) hydrogel is designed as an aqueous electrolyte for the fast charging/discharging properties in Zn/MnO2 batteries. Such hydrogel electrolyte possessed excellent mechanical characters, stable cycling capability, and superb rate performance under high current densities. These characters can also be applied in the
Zhaoxi Shen   +11 more
wiley   +1 more source

Facet‐Junction Induced Strong Metal Support Interaction for Enhanced Alkaline Hydrogen Evolution Reaction

open access: yesAdvanced Functional Materials, EarlyView.
In this study, a novel facet‐junction strategy is proposed to enhance the strong metal‐support interaction (SMSI) between the loaded Ru atoms and the Co3O4 support. The synthesized structure with the incorporation of Ru doping and the (100)/(111) crystal plane junction has a particular influence on the catalyst's hydrogen evolution reaction (HER ...
Wenqian Shen   +6 more
wiley   +1 more source

Home - About - Disclaimer - Privacy