Polymorph‐Specific Electronic Transduction in WO3 during Molecular Sensing
Metal‐oxide polymorphs with similar surface chemistry can nevertheless exhibit distinct sensing properties. In γ‐ and ε‐WO3, analyte adsorption appears comparable; yet, only ε‐WO3 induces a pronounced lattice electronic perturbation that accommodates charge in sub‐conduction band minimum states.
Matteo D'Andria +6 more
wiley +1 more source
High Charge Carrier Mobility in Non‐Conjugated 3D Covalent Organic Frameworks
A non‐conjugated 3D COF constructed via boronate ester linkages from tetraphenylene and pyrene‐based monomers is reported, which exhibits a high charge carrier mobility of 14 ± 1 cm2 V−1 s−1. ABSTRACT π‐Conjugation, π–π stacking, and long‐range order play a central role in determining charge transport efficiency in organic materials.
Joaquín Almarza +11 more
wiley +1 more source
Iridium-Schiff base complex-based fluorimetric turn-off sensor and HPLC-DAD analytical approaches for quantitation of 8-hydroxy-2'-deoxyguanosine as an oxidative DNA damage biomarker in biofluids of healthy and diabetic subjects. [PDF]
Ali HM +6 more
europepmc +1 more source
Lattice‐Matched 2D Template Enables Efficient Cesium Tin Halide Perovskite Solar Cells
Lattice‐matched 2D perovskite PEA2CsSn2I7 templates the out‐of‐plane growth of inorganic 3D γ‐CsSnI3 along the (110) plane, forming highly oriented 2D/3D tin halide perovskite heterostructures. With reduced trap states and mitigated δ‐phase impurities, the CsSnI3‐based solar cells achieve a power conversion efficiency of 15.27% and maintain stable ...
Hongzhe Anna Xu +15 more
wiley +1 more source
Enantioselective Pyrazole Alkylation via Iridium and Squaramide Catalyzed N-H Insertion. [PDF]
Ruud KJ +4 more
europepmc +1 more source
2D MOF with Intrinsic Porosity for Colorimetric Volatile Organic Compounds (VOCs) Detection
An uncommon 2D MOF with intrinsic in‐plane porosity that can be mechanically exfoliated undergoes a distinct and reversible colour change upon exposure to various volatile organic compounds. ABSTRACT In this work, we report an uncommon 2D metal–organic framework (MOF) with intrinsic in‐plane porosity that undergoes a distinct and reversible colour ...
Sergio R. Gamarra +4 more
wiley +1 more source
Exploring the Boundaries of Cyclometalated Iridium(III) Sensitizers in Photoelectrochemical Organic Transformations. [PDF]
Mantovani A +4 more
europepmc +1 more source
Origins of the selectivity of late transition metals of Group 9 and Group 10 for oxidative addition of C-H <i>vs.</i> C-Cl bonds. [PDF]
Qiu Y +7 more
europepmc +1 more source
Novel 2-(2'-Benzothiazolyl)-benzimidazole-Based Iridium(III) Photocatalysts Exhibit Antiproliferative Effects in 2D and 3D Cancer Cells to Bypass Hypoxia-Induced Resistance. [PDF]
Linero-Artiaga A +8 more
europepmc +1 more source
Support-Intensified Ir─P/O─Mo Cooperative Linkages for Robust Acidic Water Dissociation. [PDF]
Mei J +7 more
europepmc +1 more source

