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Binuclear dimethylaminoborole iron carbonyls: iron–iron multiple bonding versus nitrogen → iron dative bonding

Theoretical Chemistry Accounts, 2012
Theoretical studies show that pendant dimethylamino groups can play a significant role in the chemistry of unsaturated binuclear dimethylaminoborole iron carbonyls. For [C4H4BN(CH3)2]2Fe2(CO)5, the lowest energy structures have single CO bridges and Fe–Fe single bonds of lengths ~2.8 A. The lowest energy [C4H4BN(CH3)2]2Fe2(CO) n
Jianlin Chen   +6 more
openaire   +1 more source

Iron chelators and iron toxicity

Alcohol, 2003
Iron chelation may offer new approaches to the treatment and prevention of alcoholic liver disease. With chronic excess, either iron or alcohol alone may individually injure the liver and other organs. In combination, each exaggerates the adverse effects of the other.
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Iron-Refractory Iron Deficiency Anemia

Seminars in Hematology, 2009
Iron-refractory iron deficiency anemia (IRIDA) is an autosomal recessive disorder characterized by iron deficiency anemia unresponsive to oral iron treatment but partially responsive to parenteral iron therapy. IRIDA has recently been shown to be caused by mutations in the gene TMPRSS6, which encodes a transmembrane serine protease (also known as ...
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Iron–sulfur clusters: Why iron?

Journal of Inorganic Biochemistry, 2006
This communication addresses a simple question by means of density functional calculations: Why is iron used as the metal in iron-sulfur clusters? While there may be several answers to this question, it is shown here that one feature - the well-defined inner-sphere reorganization energy of self-exchange electron transfer - is very much favored in iron ...
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Marrow Iron

JAMA: The Journal of the American Medical Association, 1977
Marrow aspirates stained with the Prussian blue reaction give a variety of patterns. Characteristic pictures are shown for megaloblastic anemia, infection, and subjects after injection of iron dextran. The appearance of iron in histiocytes in marrows stained with Wright's stain is differentiated from noniron deposits.
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An evolving view on biogeochemical cycling of iron

Nature Reviews Microbiology, 2021
Andreas Kappler   +2 more
exaly  

Iron/iron-sucrose

Reactions Weekly, 2023
openaire   +1 more source

Matching the kinetics of natural enzymes with a single-atom iron nanozyme

Nature Catalysis, 2021
Yuanjun Chen, Juncai Dong, Rui Gao
exaly  

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