Results 171 to 180 of about 462,203 (338)

Photolyzable Polymer Brushes: Subtractive 3D Structuring of Surfaces Using Water and Light

Angewandte Chemie, EarlyView.
Facile structuring of polymer brushes is achieved by flipping the process from controlled growth to controlled brush photolysis. Using surface‐initiated radical ring‐opening polymerization of cyclic monomers with photocleavable cyclobutane rings, photodegradable targets are embedded into the polymer chains. The enabled continuous subtractive patterning
Henrik Kalmer, Federica Sbordone, Phuong T. Do, Kai Mundsinger, Hazal Kayas, Robert T. Jones, Jayanti Mendhi, Tim R. Dargaville, Damien G. Harkin, Lukas Michalek, Andrew Nelson, Hendrik Frisch   +11 more
wiley   +2 more sources

Advancements in Graphdiyne‐Based Multiscale Catalysts for Green Hydrogen Energy Conversion

Advanced Intelligent Discovery, EarlyView.
This review systematically explores the fundamental characteristics of graphdiyne (GDY), cutting‐edge field of GDY‐based multiscale catalysts within sustainable energy conversion systems.Special emphasis is placed on the structure‒property relationships in different reactions.
Qian Xiao, Lu Qi, Siao Chen, Yurui Xue
wiley   +1 more source

Convergent Total Synthesis of 16β‐Hydroxylpseudobufarenogin

Angewandte Chemie, EarlyView.
We present a novel convergent strategy that integrates Pd/Ag‐promoted Suzuki–Miyaura coupling with Ir‐catalyzed radical‐relay cyclization, enabling the first total synthesis of 16β‐hydroxylpseudobufarenogin. This approach is broadly applicable to the total synthesis of various oxygenated bufadienolides by simply modifying the fragment structures ...
Wataru Shigematsu, Yo Matsumoto, Koichi Hagiwara, Masayuki Inoue   +3 more
wiley   +2 more sources

FTIR vs. FT-IR vs. Mid-IR [PDF]

Applied Spectroscopy, 2010
Peter R. Griffiths, Rebecca Airmet
openaire   +2 more sources

FastCat: Autonomous Discovery of Multielement Layered Double Hydroxide Alloy Catalysts for Alkaline Oxygen Evolution Reaction

Advanced Intelligent Discovery, EarlyView.
A machine learning‐guided self‐driving laboratory screened over 500 nickel‐based layered double‐hydroxide catalysts for alkaline oxygen evolution. Out of the eight metals, the robot uncovered a quaternary Ni–Fe–Cr–Co catalysts requiring only 231 mV overpotential to reach 20 mA cm−2.
Nis Fisker‐Bødker, Enzo Raffaele Moretti, Jin Hyun Chang, Tejs Vegge   +3 more
wiley   +1 more source

Cobalt‐Catalyzed Intramolecular C─H Silylation of Arenes

Angewandte Chemie, EarlyView.
Direct C─Si bond formation via C─H silylation is an atom‐economical route to organosilanes but is largely limited to noble metals. We report the first cobalt‐catalyzed intramolecular arene C–H silylation enabled by HCo(PMe3)4, which activates Si–H and C–H bonds to form diverse silacycles and silafluorenes in high yields with broad functional‐group ...
Yongqiang Xu, Valentin Poirier, Gilles Lemière, Julie Oble, Marc Petit   +4 more
wiley   +2 more sources

Large Language Model‐Based Chatbots in Higher Education

Advanced Intelligent Systems, Volume 7, Issue 3, March 2025.
The use of large language models (LLMs) in higher education can facilitate personalized learning experiences, advance asynchronized learning, and support instructors, students, and researchers across diverse fields. The development of regulations and guidelines that address ethical and legal issues is essential to ensure safe and responsible adaptation
Defne Yigci, Merve Eryilmaz, Ail K. Yetisen, Savas Tasoglu, Aydogan Ozcan   +4 more
wiley   +1 more source

Bent N‐Heterocyclic Allenes From a Well‐Defined Titanium Vinylidene Complex

Angewandte Chemie, EarlyView.
The syntheses and the structures of N‐heterocyclic allenes are reported. Allenes bearing fluorenylidene capping groups show markedly bent C═C═C units, a carbene‐like reactivity, and they can act as potent C‐donor ligands for metal complexes. ABSTRACT Allenes typically display a linear geometry. A notable exception occurs in allenes bearing two electron‐
Bastiaan Kooij, Damien W. Chen, Rosario Scopelliti, Farzaneh Fadaei‐Tirani, Kay Severin   +4 more
wiley   +2 more sources

Site‐Selective B─H Activation via HAT Toward Xanthyl‐closo‐Carboranes as Bench‐Stable Precursors of Organosulfur Boron Clusters

Angewandte Chemie, EarlyView.
A light mediated direct regioselective B─H functionalization, via hydrogen atom transfer (HAT), is described. Unexplored xanthyl‐closo‐carboranes as novel bench‐stable and versatile platforms to access sulfur‐containing boron clusters are reported for the first time.
Marco Rusconi, Eugenia Magi, Polyssena Renzi, Emanuele Azzi, Valeria Lagostina, Enrico Salvadori, Mario Chiesa, Birgit Hischa, Giovanni Ghigo, Annamaria Deagostino   +9 more
wiley   +2 more sources

Ir kalviai, ir kryžiai : recenzija

, 2013
The publications heading has published Rimantas Sliužinskas', specialist of ethnic culture from Klaipėda, review of the 2012, released in Anykščiai, publication "Lithuanian blacksmith cross-making" by Jolanta Zabulytė. It contains material from the 2012 Horse Museum (Niūroniai village, Anykščiai district) exhibition of forged "suns" and the scientific ...
openaire   +1 more source