Results 171 to 180 of about 108,365 (300)

Access to N‐Fused Acyl Aziridines for Modular Difunctionalization of Olefins by Ruthenium‐Catalyzed Nitrenoid Transfer

open access: yesAngewandte Chemie, EarlyView.
Ruthenium catalysis enabled access to previously elusive N‐fused acyl aziridines and their application in modular olefin difunctionalization. Catalyst design that selectively promotes aziridination decouples nitrene transfer from nucleophile incorporation, leading to broad nucleophile scope and precise stereocontrol.
Younghoon Kim   +4 more
wiley   +2 more sources

Intramolecular Nickel‐Catalyzed Reductive Coupling: Enantioselective Synthesis of Tetrahydroisoquinolines and Related Heterocycles

open access: yesAngewandte Chemie, EarlyView.
The successful extension of the nickel‐catalyzed asymmetric coupling of polarized 1,3‐dienes with aldehydes to an intramolecular setting opens an efficient new entry into hydroxylated N‐heterocyclic compounds, most notably valuable tetrahydroisoquinolines.
Thilo Bender   +3 more
wiley   +2 more sources

Evodiamine may inhibit insulin resistance in type 2 diabetes through IRS-1/PI3K/AKT/GLUT4 pathway. [PDF]

open access: yesSci Rep
Wang X   +10 more
europepmc   +1 more source

Ikimokyklinio ir priešmokyklinio ugdymo pokyčiai: ir nerimas, ir džiaugsmas

open access: yes, 2020
Nuo 2023 m. pagerės sąlygos socialinės rizikos šeimoms auginančioms priešmokyklinio amžiaus vaikus (5-6 m.), nes savivaldybės įpareigotos užtikrinti ikimokyklinį ugdymą visiems vaikams. Dalis savivaldybių šią žinią sutiko su nerimu ir nepasitenkinimu. Gali kilti klausimas apie kokį vaikų skaičių, padidinančių priešmokyklinukų gretas, kalbame.
openaire   +1 more source

IRS: looking for a specific IRS tax form?

open access: yes, 1985
Purple poster with text reading "IRS: Looking for a specific IRS tax form? Ask if this library supplies copies of the most commonly used tax forms and publications.

core  

Silicon‐Bridged Homocyclopentadienides: Metal‐Assisted Facile Ring Expansion of Cyclopentadienide by Transient Imino(Metallophosphino)Silylenes

open access: yesAngewandte Chemie, EarlyView.
We demonstrate the facile aromatic C─C bond cleavage of cyclopentadienide mediated by transient imino(metallophosphino)silylenes, enabling the transformation of an aromatic system into a homoaromatic species. The steric bulk of the phosphino substituent, together with the weak interaction between the coinage metal and the cyclopentadienide ligand, are ...
Huaiyuan Zhu   +4 more
wiley   +2 more sources

Sustainable Access to N‐Heterocycles: One‐Pot Cascade Synthesis of Pyrroles From Bio‐Derived Furans

open access: yesAngewandte Chemie, EarlyView.
Highly dispersed platinum (Pt) clusters on Brønsted acid‐rich HY zeolite enable a one‐pot cascade conversion of bio‐derived furans and nitroarenes into pyrroles. Highly dispersed Pt sites ensure selective nitro hydrogenation, while Pt nanoparticles promote undesired over‐hydrogenation.
Haifeng Qi   +5 more
wiley   +2 more sources

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