Results 201 to 210 of about 414,701 (274)

Advances in Parahydrogen‐Induced Polarization for Nuclear Magnetic Resonance of Peptides, Proteins, and Biopolymers

open access: yesChemistryEurope, EarlyView.
Hyperpolarization by parahydrogen‐induced polarization enhances the sensitivity of nuclear magnetic resonance spectroscopy of amino acids, peptides, mini‐proteins, and biopolymers using nonnatural amino acids with unsaturated side chains up to three orders of magnitude.
Gerd Buntkowsky
wiley   +1 more source

Organophotoredox/Cobalt‐Catalyzed Retro‐Hydroformylation of Aldehydes

open access: yesChemistryEurope, EarlyView.
A new photoredox/cobalt retro‐hydroformylation is developed. This one‐pot two‐step process involves the in situ formation of the corresponding 1,4‐dihydropyridine as key intermediate. Under mild reaction conditions, alkenes are efficiently produced from a wide range of aliphatic α‐monosubstituted aldehydes, with high functional‐group tolerance.
Augustin Nouaille   +3 more
wiley   +1 more source

The Newly Discovered Pathway for Oxygen Evolution Reaction: In‐Situ/Operando Characterization Techniques for Catalyst Development

open access: yesCarbon Energy, EarlyView.
This study introduces a newly discovered oxide path mechanism (OPM) for the oxygen evolution reaction (OER), emphasizing the role of in‐situ and operando characterization techniques in unraveling catalyst behavior under realistic conditions. The integration of advanced spectroscopic methods provides new mechanistic insights for the design of highly ...
Rabia Khalid   +4 more
wiley   +1 more source

Fe‐Facilitated Deep Reconstruction of Ni3S2 Toward Superior Oxygen Evolution

open access: yesCarbon Energy, EarlyView.
In situ Raman spectroscopy combined with density functional theory (DFT) reveals that Fe substitution is able to facilitate the deep reconstruction of Ni3S2 into oxyhydroxides (DR‐(Ni,Fe)OOH), inducing a downshift in the energy band structure, optimizing oxygen‐containing intermediates adsorption, and thereby improving the performance of the oxygen ...
Zhihang Liu   +9 more
wiley   +1 more source

6-Phosphogluconate dehydrogenase promotes mitochondrial fusion and immune suppression in tumor-associated monocytic suppressor cells. [PDF]

open access: yesNat Commun
Daneshmandi S   +13 more
europepmc   +1 more source

Interfacial Ru–O–W Orbital Coupling Enables Lattice Oxygen Stabilization for Enhanced Acidic OER

open access: yesCarbon Energy, EarlyView.
A RuO2/WO3 electrocatalyst with strong interfacial Ru–O–W bonds exhibits optimized Ru–O interactions, enhancing intrinsic activity and stability for acidic OER. The WO3 support modulates the electronic structure of RuO2 and promotes oxo‐intermediate deprotonation, delivering a low overpotential of 203 mV at 10 mA cm−2 and sustained operation beyond 200 
Tongzhou Wang   +9 more
wiley   +1 more source

Electrocatalytic CO2 Reduction Coupled to Formate Fermentation: An Electro‐Bio Cascade Approach in Biocompatible Electrolytes

open access: yesChemistry – A European Journal, EarlyView.
CO2 utilization in industrial biotechnology: Rational design of a process cascade for electrochemical CO2 reduction linked with formate fermentation, supporting robust cell growth and high biomass yields. ABSTRACT Integration of electrochemical CO2 reduction with microbial fermentation enables conversion of CO2 into valuable chemicals but poses ...
Luciana Vieira   +8 more
wiley   +1 more source

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