Results 191 to 200 of about 57,276 (400)

Stabilities and Limitations in the Reactivity of Phosphorus Ylide‐Based Aluminum‐ and Gallium‐Carbon Ambiphiles − A Combined Experimental and Computational Approach

open access: yesEuropean Journal of Inorganic Chemistry, Accepted Article.
The unexpected reactivity and stability limits of phosphorus ylide‐based aluminum‐ and gallium‐carbon ambiphiles are described. While the previously published t‐butyl‐substituted compound (2‐{AltBu2}‐C6H4)Ph2PCMe2 (1tBu) reactsreversibly with NH3 at room temperature with cleavage of a N–H bond, the reaction with MeNH2 is much less favourable and ...
Felix Krämer   +3 more
wiley   +1 more source

Reactivity of an Ortho‐Phenylene‐Bridged Al/P Frustrated Lewis Pair toward Small Molecules

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
The first mono ortho‐phenylene‐bridged Al/P frustrated Lewis pair (FLP) is synthesized and characterized. Its reactivity is probed against several small molecules. Furthermore, a suitable entry point for generating other Al/C‐based FLPs starting from the Al/P‐based title compound is identified.
Melina E. A. Dilanas, Frank Breher
wiley   +1 more source

Study of the reactivity of Kraft and organosolv lignins with 4, 4’–diphenylmethane diisocyanate and characterization of the obtained products [PDF]

open access: yes, 2011
The interaction of two types of lignins: Kraft lignin (KL), isolated according to the LignoBoost process (Sweden), and Alcell organosolv (OL) lignin (Canada), with 4,4’-diphenylmethane diisocyanate (MDI) in the dry dioxane media at 25 degrees of Celsius,
Arshanitsa, Alexandr   +3 more
core  

High Molar Mass Non‐Isocyanate Polyurethanes by Transurethanization of Diols with Isophorone‐Based Bismethylcarbamate

open access: yesMacromolecular Chemistry and Physics, EarlyView.
High molar mass polyurethanes are achieved using potassium carbonate (K2CO3) as a catalyst, confirming that the polytransurethanization route is a good alternative to the isocyanate one. Abstract The synthesis of thermoplastic polyurethanes (TPU) has been associated with sustainability issues, prompting the development of alternative synthesis routes ...
Nichollas G. Jaques   +5 more
wiley   +1 more source

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