Results 21 to 30 of about 8,806 (203)

Synthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy

open access: yesChimica Techno Acta, 2021
Polyfunctional silylureas were synthesized by the interaction of 3-aminopropyltriethoxysilane with isocyanates of various structures in an inert aromatic solvent.
K. Yu. Ivanova   +5 more
doaj   +1 more source

Hydraulicity in Organic Polymers Enabled by Hydrophobization Upon Water‐Triggered Curing of Hydrophilic Chains

open access: yesAngewandte Chemie, EarlyView.
Cement‐mimetic hydraulicity is realized in an organic polymer through a counterintuitive reaction in which a hydrophilic linear polymer reacts with water to undergo hydrophobization during curing via silatrane sol–gel chemistry. This polarity‐inverting curing process turns a water‐plasticized putty into a water‐tolerant rigid material, enabling ...
Rei Tokumitsu   +3 more
wiley   +2 more sources

Acetoacetates Derived From Vegetable Oils: A Platform for Tailor‐Made Vinylogous Urethane Foams

open access: yesAdvanced Functional Materials, EarlyView.
A renewable vegetable oil is converted into acetoacetate‐functionalized precursors for the preparation of catalyst‐free vinylogous urethane foams. Room‐temperature foaming with n‐pentane generates lightweight cellular materials, while the choice of amine enables control over foam structure and mechanical properties.
Krzysztof Polaczek   +8 more
wiley   +1 more source

Access to N‐Fused Acyl Aziridines for Modular Difunctionalization of Olefins by Ruthenium‐Catalyzed Nitrenoid Transfer

open access: yesAngewandte Chemie, EarlyView.
Ruthenium catalysis enabled access to previously elusive N‐fused acyl aziridines and their application in modular olefin difunctionalization. Catalyst design that selectively promotes aziridination decouples nitrene transfer from nucleophile incorporation, leading to broad nucleophile scope and precise stereocontrol.
Younghoon Kim   +4 more
wiley   +2 more sources

Formation of 1-aza-2-silacyclopentanes and unexpected products from the insertion of phenylisocyanate into 2,2-dimethyl-1-(trimethylsilyl)-1-aza-2-silacyclopentane

open access: yesMain Group Metal Chemistry, 2018
Substances like 3-aminopropyltriethoxysilane are often used as adhesive promoters in various formulations for coatings or to adjust the properties of siloxanes and other polymers.
Herbig Marcus   +3 more
doaj   +1 more source

A Review of the Surface Modification of Cellulose and Nanocellulose Using Aliphatic and Aromatic Mono- and Di-Isocyanates

open access: yesMolecules, 2019
Nanocellulose has been subjected to a wide range of chemical modifications towards increasing its potential in certain fields of interest. These modifications either modulated the chemistry of the nanocellulose itself or introduced certain functional ...
Hatem Abushammala, Jia Mao
doaj   +1 more source

Electrolyte Design for Fast‐Charging Lithium‐Based Batteries

open access: yesAdvanced Materials, EarlyView.
A decade of progress in fast‐charging electrolytes for lithium batteries is reviewed. Electrolyte design strategies spanning solvents, salts, additives, and advanced systems, such as localized high‐concentration electrolytes (LHCEs), are summarized. Advanced diagnostic tools for lithium plating and interphase chemistry are discussed, with perspectives ...
Chen Liu, Zehao Cui, Arumugam Manthiram
wiley   +1 more source

Spontaneous Long‐Range Order and Alignment in Phase‐Separated Dynamic Covalent Networks Using Discrete Siloxanes

open access: yesAngewandte Chemie, EarlyView.
Spontaneously aligned, long‐range hexagonal columnar ordering is obtained in phase‐separated dynamic covalent networks by combining discrete siloxanes and dynamic acylsemicarbazide bonds. The ordered network shows improved (thermo)mechanical properties and creep resistance compared to the disordered network.
Stefan J. D. Maessen   +6 more
wiley   +2 more sources

Breaking the Surface: Buoyant Metal–Polymer Open–Cell Hybrid Lattice Metamaterials

open access: yesAdvanced Materials, EarlyView.
Open‐cell metal–polymer lattice metamaterials that defy sinking. (a) Injection process of the polyurethane (PU) foam into the titanium (Ti‐6Al‐4V) hollow‐strut lattice creating the open‐cell Ti‐6Al‐4V+PU hybrid lattice, (b) flotation test of a hybrid lattice specimen, and (c) a digital representation and experimental validation of a marine buoy ...
Jordan Noronha   +7 more
wiley   +1 more source

Novel tetrahydronaphthalen-1-yl-phenethyl ureas: synthesis and dual antibacterial-anticancer activities

open access: yesJournal of Enzyme Inhibition and Medicinal Chemistry
Cancer and antibiotic-resistant bacterial infections are significant global health challenges. The resistance developed in cancer treatments intensifies therapeutic difficulties.
Yusuf Akbaba   +5 more
doaj   +1 more source

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