Results 71 to 80 of about 8,806 (203)

Rh(III)-catalyzed directed C–H bond amidation of ferrocenes with isocyanates

open access: yesBeilstein Journal of Organic Chemistry, 2012
[RhCp*(OAc)2(H2O)] [Cp* = pentamethylcyclopentadienyl] catalyzed the C–H bond amidation of ferrocenes possessing directing groups with isocyanates in the presence of 2 equiv/Rh of HBF4·OEt2.
Satoshi Takebayashi   +3 more
doaj   +1 more source

Nonthermal Plasma–Enabled Cascade N2 Activation and Electroreduction

open access: yesEcoEnergy, EarlyView.
Integrating plasma‐assisted NOx synthesis with subsequent electrochemical reduction enables the sustainable synthesis of high‐value N‐containing chemicals under ambient conditions. ABSTRACT The development of sustainable nitrogen fixation technologies operating under ambient conditions is critical for reducing the energy intensity and carbon footprint ...
Shijia Li, Wei Gao, Ziyun Wang
wiley   +1 more source

Occupational allergic and irritant contact dermatitis in workers exposed to polyurethane foam

open access: yesInternational Journal of Occupational Medicine and Environmental Health, 2014
Objectives: To evaluate sensitization to chemicals present in work environment after an outbreak of contact dermatitis in workers of vehicle equipment factory, exposed to polyurethane foam, based on 4,4'-diphenylmethane diisocyanate (MDI).
Marta Kieć-Świerczyńska   +4 more
doaj  

A Sustainable Path for Composite Tooling: Novel Materials, Design, and Technologies Through FEM and LCA

open access: yesProceedings
Intro: Production of composite parts requires proper tools, often made of polyurethane boards, implying the use of harmful substances, such as isocyanates [...]
Gloria Anna Carallo   +6 more
doaj   +1 more source

A Biosourced and Self‐Healable Polymer Electrolyte for Potassium Batteries

open access: yesEcoEnergy, EarlyView.
A biosourced lignin‐filled gel polymer electrolyte combines suppressed crystallinity, high ionic conductivity, and UPy‐driven self‐healing for potassium batteries. The optimized formulation sustains long‐term cycling with 97.5% capacity retention after 1000 cycles and preserves electrochemical operation after intentional membrane damage.
Sabrina Trano   +6 more
wiley   +1 more source

Flexible Phase Change Bandage Incorporated With Zeolite for Temperature‐Controlled Wound Hemostasis

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A novel flexible hemostatic phase change bandage (HPB) was designed and constructed through chemical cross‐linking and electrospinning to mitigate thermal injury and broaden the application of PCMs in the medical field. Furthermore, the flexible HPB shows thermal stability, strong mechanical strength, excellent infiltration, and reliable thermal ...
Xinyu Zhang   +8 more
wiley   +1 more source

Synergistic Modulation of Conductivity and Oxidation Stability in SiHfBCN Ceramics via UV‐Assisted Structural Evolution

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A quinary UV‐curable SiHfBCN ceramic photoresist with high ceramic yield enhanced is developed through sequential molecular design for high‐temperature sensing coatings. The elevated interconnected conductive network induced by chemically bonded carboxylated MWCNTs enables the pyrolyzed ceramics' enhanced conductivity and excellent oxidation stability.
Xiyue Zhu   +8 more
wiley   +1 more source

Thermoresponsive Gel Polymer Electrolytes Enabled by Retained Double Bonds for Thermal Shutdown in Lithium‐Ion Batteries

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A smart gel electrolyte with thermal shutdown capability has been proposed enabled by a two‐step cross‐linking strategy, which preserves a high density of unreacted double bonds at room temperature. This strategy brings negligible degradation to room temperature electrochemical performance, while under thermal abuse conditions above 115 °C, the gel ...
Yihan Wu   +6 more
wiley   +1 more source

Harnessing Thin‐Film Solid‐State Electrolytes: Enabling Breakthroughs in All‐Solid‐State Batteries

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Schematic illustration highlighting the advantages of transitioning from traditional thick solid‐state electrolytes (SSEs) to thin‐film SSEs. Thinning the electrolyte enables higher ionic conductivity, reduced interfacial polarization, improved flexibility, compact electrode contact, and enhanced energy density, offering a promising pathway toward high‐
Yitao He   +3 more
wiley   +1 more source

Lignocellulosic Triboelectric Materials for Energy Harvesting and Emerging Applications: A Review on Lignin‐Molecular Engineering toward Improved Performance

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Contrasting sustainable biomass with depleting petroleum resources, this review charts the evolutionary timeline of lignin‐based TENGs. We systematically evaluate their fundamental mechanisms, enhancement strategies, and applications in green self‐powered electronics.
Yuxin Yang   +9 more
wiley   +1 more source

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