Results 51 to 60 of about 8,806 (203)
CHIMIA, 1992 Adducts obtained by 1,3-dipolar cycloadditions to 2,3-dihydroisothiazol-3-one 1,1-dioxides are inclined to undergo a cheletropic process, by which the newly formed heterocyclic part undergoes aromatization, while SO2 is extruded and an ...
Kaspar F. Burri
doaj +2 more sources
Solid-state Synthesis of 1-Ethoxycarbonyl-4-substituted-semicarbazides
Molecules, 2003 A rapid and simple method for the preparation of 1-ethoxycarbonyl-4-substituted-semicarbazides has been developed. As examples the reaction of six different isocyanates with ethyl carbazate under solvent-free conditions are reported.
Hedayat A. Taghizadeh +2 more
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Carbon Energy, EarlyView.Replacing the oxygen evolution reaction with the electro‐oxidation of pollutants and waste streams offers an energy‐efficient route for simultaneous hydrogen production and pollutant remediation. This review summarizes the reaction mechanisms, catalyst design principles, and emerging paired‐electrolysis strategies that govern activity, selectivity ...
Safa Al‐Yahyaey +4 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.Covalent linkage of a highly crystalline PHBV with a ductile P3HB4HB is shown to produce block copolymers with markedly enhanced extensibility and toughness, outperforming equivalent blends. The results demonstrate that polymer architecture, not composition alone, governs mechanical response, offering a route to biodegradable materials that combine ...
Katrin Blandine Kockler +3 more
wiley +1 more source
Catalytic Annulation of Epoxides with Heterocumulenes by the Indium-Tin System
Molecules, 2018 In the synthesis of five-membered heterocycles by the annulation of epoxides with heterocumulenes such as carbon dioxide and isocyanates, we developed the indium-tin catalytic system and synthesized various cyclic adducts including novel types products ...
Itaru Suzuki +3 more
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Chemistry – A European Journal, EarlyView.Proton‑transfer catalysis controls acylsemicarbazide dissociation, linking proton affinity to exchange kinetics and enabling predictive design of robust, tunable dynamic covalent networks. ABSTRACT We provide design principles for predicting bond exchange kinetics in acylsemicarbazide (ASC)‐based systems that can be applied to tuning the properties of ...
Siebe Lekanne Deprez +6 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.A molecular design strategy combines lignin‐derived aromatic units, sugar‐derived furan groups, and flexible glycol segments to create wet‐spinnable polyurethanes. Thermally reversible Diels–Alder crosslinking chemistry enables formation of crosslinked thermosetting fibers, repeated de‐crosslinking/re‐crosslinking cycles, and tunable fiber properties ...
Rafael N. L. Menezes +7 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.Two families of bTurea‐derived biradicals, bcTmols and bcTCOOKs, were prepared as polarizing agents for dynamic nuclear polarization (DNP)‐enhanced NMR through short and efficient synthetic routes. The best‐performing biradical, bcTCOOK‐M2, containing two methyl groups on the urea bridge, provided signal enhancements of up to ∼220 at 14.1 T and 100 K ...
Ancy T. Wilson +3 more
wiley +1 more source
A class of carbonic anhydrase I – selective activators
Journal of Enzyme Inhibition and Medicinal Chemistry, 2017 A series of ureido and bis-ureido derivatives were prepared by reacting histamine with alkyl/aryl-isocyanates or di-isocyanates. The obtained derivatives were assayed as activators of the enzyme carbonic anhydrase (CA, EC 4.2.1.1), due to the fact that ...
Erol Licsandru +4 more
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