Results 221 to 230 of about 15,117 (303)

Single‐Atom Iron‐Catalyzed Oxidative Esterification: From Methylarenes to the Upcycling of Polystyrene and Lignin‐Derived Feedstocks

Angewandte Chemie, EarlyView.
Heterogeneous iron‐catalyzed environmentally benign and sustainable CH‐oxidative esterification methodology has been developed for the synthesis of esters. This challenging reaction has been achieved by the rational design of specific single atom iron‐based catalyst with Fe‐N4 active centers, which empowered the oxidative esterification of methyl and ...
Zhuang Ma, Binyu Zhang, Hui Yang, Yue Hu, Junzheng Yu, Yanbin Cui, Jun Zhao, Matthias Beller, Rajenahally V. Jagadeesh   +8 more
wiley   +1 more source

Synthesis of sulfanyl derivatives of 1,2,4-triazoles <i>via</i> an acid catalyzed intramolecular cyclization of isothiosemicarbazones: structural characterization, <i>E</i>/<i>Z</i> isomerism, mechanistic insights and <i>in vitro</i> cytotoxicity. [PDF]

RSC Adv
Snisha K, Karthikeyan MC, Bhuvanesh N, Arockiam AJV, Karvembu R.   +4 more
europepmc   +1 more source

Potassium‐Ligand Cooperation Facilitated Chemical Bond Activation and Catalytic Hydrogenation

Angewandte Chemie, EarlyView.
A new strategy for alkali metal‐mediated catalysis based on metal–ligand cooperation (MLC) is presented. Potassium pincer complexes exhibit remarkable reactivity toward a range of molecules via an unprecedented potassium–ligand cooperative mechanism. This reactivity enables potassium‐catalyzed hydrogenation, providing efficient reduction of ketones and
Yaoyu Liang, Irena Efremenko, Thiyagarajan Subramanian, Amit Kumar, Liat Avram, Yael Diskin‐Posner, David Milstein   +6 more
wiley   +1 more source

Unilateral Lung Agenesis and Left Isomerism in a Neonate: A Case Report of Multi-system Anomalies. [PDF]

Cureus
Mukherjee TG, Thurmann KE, Richardson R.
europepmc   +1 more source

Vapor‐Phase Grain‐Boundary Anchoring Enables Molecular Toughening and Record Bending Endurance in Pilot‐Scale Roll‐to‐Roll‐Printed Flexible Perovskite Modules

Angewandte Chemie, EarlyView.
A vapor‐phase molecular toughening strategy is developed for pilot‐scale roll‐to‐roll (R2R) ‐compatible fabrication of flexible perovskite solar modules. Thiol vapor selectively regulates crystallization and anchors at grain boundaries, reducing defects while enhancing mechanical resilience.
Lirong Dong, Viktor Rehm, Shudi Qiu, Zexian Han, Naveen Harindu Hemasiri, Michael Wurmshuber, Michael Wagner, Cindy‐Ly Tavera‐Méndez, Dorothea Wisser, Chaohui Li, Robin Basu, Leopold Lahn, Olga Kasian, Sarmad Feroze, Wolfgang Heiss, Andreas Distler, Hans‐Joachim Egelhaaf, Fu Yang, Christoph J. Brabec   +18 more
wiley   +1 more source

Outcomes of Cardiac Repair in Heterotaxy Syndrome Patients-Tertiary Center Experience. [PDF]

CJC Pediatr Congenit Heart Dis
Ebrahim MA, Alzayed NT, Alsahhaf SM, Almulla MA, Yassin KM, Shabaan LA, Elsayed MA, Lyubomudrov VG.   +7 more
europepmc   +1 more source

Redirecting Excited‐State Proton Transfer Through Supramolecular Polymerization in Nanoconfinement

Angewandte Chemie, EarlyView.
Supramolecular confinement redirects the excited‐state proton transfer pathway of an amphoteric emitter. In water, the molecule undergoes ESPD, whereas co‐assembly with γ‐cyclodextrin forms nanotubes that template slip‐stacked emitter pairs and enable ESIMPT. Structural and photophysical characterization of the assemblies shows that the preorganization
Luis C. Pantaleone, Robert Hutchings, Bente Reus, Jacopo Martinelli, Alessia Lasorsa, Patrick C. A. van der Wel, Marc C. A. Stuart, Wesley R. Browne, Tibor Kudernac   +8 more
wiley   +1 more source

Mining extreme properties from a large metamaterial database. [PDF]

Nat Commun
Chen J, Wei Z, Xiao X, Wei K, Yang X, Qu Z, Fang D.   +6 more
europepmc   +1 more source

Coordination‐Driven Direct C─H Metalation of N‐Heterocycles With a Superbasic Co(II) Amide Co(TMP)2

Angewandte Chemie, EarlyView.
By enabling regioselectivities that are inaccessible with conventional bases, this study introduces a Co(II) amide platform for the deprotonative C─H metalation of sensitive N‐heterocycles. Subsequent interception of the resulting Co(II) intermediates with external oxidants affords a family of sterically congested, TMP‐substituted heterocycles via C─N ...
Na Jin, Manting Mu, Max García‐Melchor, Eva Hevia   +3 more
wiley   +1 more source