Results 261 to 270 of about 403,555 (400)

Biogenesis and downstream effects of 3',5' and 2',3' cAMP isomers in plants. [PDF]

Sci Adv
Li M, Chodasiewicz M, Muraleedharan M, Lopez IM, Gorka M, Kerber O, Alotaibi SS, Nelson ADL, Lenobel R, Friedecká J, Skirycz A, Friml J.   +11 more
europepmc   +1 more source

Reactive extraction of 3-HP acid using tertiary and quaternary amines in decanol and comparison with its isomer 2-HP acid

, 2014
Marwen Moussa, Grégoire Burgé, Claire Saulou‐Bérion, Florent Allais, Violaine Athès-Dutour, Henry-Éric Spinnler   +5 more
openalex   +1 more source

Enantioselective Synthesis of a New Class of Stable and Functionalized Cyclopentadienes via CuH‐Catalysis

Angewandte Chemie, EarlyView.
Cyclopentadienes (CpHs) are fundamental building blocks with widespread applications in chemistry. However, their inherent acidity and isomeric instability have long limited access to chiral variants in an asymmetric fashion. Here, we introduce a CuH‐catalyzed asymmetric transformation that provides an unprecedented entry into a new class of ...
Piero Soppelsa, Riccardo Bellin, Besma Boulila, Francesco Vaghi, Manuel Orlandi   +4 more
wiley   +1 more source

A practical guide to RRKM theory, its simplified multi-well version AWATAR and master equation modelling of radiative processes.

Phys Chem Chem Phys
Salzburger M, Reimann M, Hartmann JC, Ončák M, Beyer MK.   +4 more
europepmc   +1 more source

Discrimination of Hexane Isomers by Temperature Swing Adsorption in a Rigid Aluminum Metal-Organic Framework. [PDF]

ACS Mater Lett
Xie F, Yu L, Jenkins T, Guo FA, Li S, Thonhauser T, Wang H, Li J.   +7 more
europepmc   +1 more source

1,7‐Digallatetracarborane: Between Nucleophilic closo‐Cluster and “Inverse Sandwich” Digallylene

Angewandte Chemie, EarlyView.
A dianionic π‐ligand is used to make a Janus‐type twofold complex with low‐valent gallium Ga(+I). The resulting compound can be seen as and reveals the reactivity of both: a Wade‐type closo‐carborane cluster with nucleophilic Ga‐sites, as well as π‐ligand stabilized Ga(I) atoms in an inverse sandwich compound.
Julijan Sarcevic, Tobias Heitkemper, Niklas Mehner, Maximilian Kubis, Christian P. Sindlinger   +4 more
wiley   +1 more source

Dual engineering of thermodynamics and kinetics in covalent organic frameworks for separation. [PDF]

Nat Commun
Rao ZR, Ran XQ, Li ZQ, Chen Y, Yan XP, Qian HL.   +5 more
europepmc   +1 more source

The Regularity of Vibration Dynamics and Electronic States of Fluorine Carotenoids Isomers Modulated by Polarization Environment

Zhiwei Men, Lü Xing, Qin Dai, Yi Shi, Rina Wu, Wei Zhang, Yeqiu Li   +6 more
openalex   +1 more source

Excited‐State Antiaromaticity in Nonbenzenoid Aromatics: Examining the Dynamics of Intramolecular Proton Transfer With a Small Driving Force

Angewandte Chemie, EarlyView.
The excited‐state antiaromaticity of hydroxybenzotropyliums (HBTs) can be tuned through substituent effects to bring the aromatic ‘enol’ (E) and keto (K) tautomers close in energy. This leads to abnormally slow excited‐state proton transfer (on the ns timescale), giving rise to dual fluorescence emission and weak photoacidity.
Promeet K. Saha, Charlotte A. Bardsley, Hector G. Miranda‐Salinas, Daniel Crane, Rabia Ayub, Andrew P. Monkman, Paul R. McGonigal   +6 more
wiley   +1 more source

Unwrapping the Dodecaborane Core: Structure, Electronic Properties, and Chemical Reactivity Across the Complete [B₁₂I_<i>n</i>]^- Series (<i>n</i> = 11-1). [PDF]

J Am Chem Soc
Shao Q, Cao W, Knorke H, Behrend KA, Kaur J, Rohdenburg M, Volke D, Kenttämaa HI, Hu Z, Sun Z, Warneke J, Sun H, Wang XB.   +12 more
europepmc   +1 more source