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Sorption isotherms, GAB parameters and isosteric heat of sorption

Journal of the Science of Food and Agriculture, 2005
AbstractThe diffusion–sorption drying model has been developed as a physics‐based way to model the decreasing drying rate at low moisture contents. This new model is founded on the existence of different classes of water: free and bound water. The transition between these classes and the corresponding thermodynamics form distinct components of the ...
Quirijns, E.J.   +3 more
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Desorption isotherms and isosteric heat of anaerobic fermentation residues

Chinese Journal of Chemical Engineering, 2019
Abstract This paper presents the equilibrium desorption isotherms and the isosteric heat of sorption of a mixture containing mechanically dewatered fermentation residue (obtained from a blend of chicken, swine and cattle manure) used in biogas plants and corn spoiled silage in a ratio of 2:1.
Tibor Poós, Viktor Szabó
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Equilibrium isotherms and isosteric heats of morel (Morchella esculenta)

Journal of Food Engineering, 2002
Abstract Moisture desorption isotherms of Morchella esculenta mushrooms were determined at 5, 15, 25 and 35 °C and within the range of 0.11–0.92 water activity using a standardized conductivity hygrometer. Five models were considered to describe isotherms (GAB, Oswin modified, Henderson modified, Halsey modified and Ratti) being fitted to the ...
A Mulet   +3 more
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Net isosteric heat of sorption in dried fruits

Journal of Food Engineering, 1991
Abstract In this work, the net isosteric heats of sorption (q st,n ) of five dried fruits (sultana raisins, currants, figs, prunes and apricots) were determined for adsorption and desorption, using the relevant thermodynamic relation, (i.e. Clausius-Clapeyron equation) in the temperature range 15–60°C, based on experimental sorption data. From the
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Isosteric Heat of Potential Confinement in the Hydrogen Storage Material

Nano, 2015
In the hydrogen storage problem, if an attractive potential well is formed inside the void space of porous materials, the storage gas density is expected to increase significantly compared to the H2 gas density outside the material. Actually, the overall H2 density inside the material is enhanced basically by a Boltzmann factor of exp[[Formula: see ...
Jaehyun Bae   +6 more
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Lattice spacing and isosteric heat of argon monolayers below 50K

Surface Science Letters, 1980
Abstract The lattice constants of 2D solid Ar adsorbed on graphite are reported for many combinations of T and vapor pressure P, where ...
Christopher G. Shaw, S.C. Fain
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Lattice gas with multiple interactions: isosteric heat and thermal desorption

Surface Science, 1992
Abstract Using the transfer matrix method we calculate the isosteric heat and thermal desorption kinetics for particles adsorbed on a triangular lattice with repulsive nearest neighbor, attractive and repulsive next-nearest neighbor and trio interactions. As an example we study the adsorption of CO on a Ru(0001) surface.
S.H. Payne, Jun Zhang, H.J. Kreuzer
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Isosteric heats of adsorption for nitrogen adsorbed on microporous silica

Journal of the Chemical Society A: Inorganic, Physical, Theoretical, 1971
Nitrogen adsorption isotherms at three different but similar temperatures were determined on samples of microporous silicas prepared by a freeze–thaw technique. A maximum in the plot of the isosteric heat of adsorption against coverage was observed on all the samples investigated.
D. Dollimore, T. Shingles
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Derivation of isosteric heat of adsorption for non-ideal gases

International Journal of Heat and Mass Transfer, 2015
Abstract This paper presented a theoretical framework for precise determination of the isosteric heat of adsorption for non-ideal gases. The derived equation had been applied for various adsorbent–refrigerant pairs. Highly porous activated carbon powder, namely Maxsorb III and activated carbon fiber of type (A-20) were used as adsorbents with HFC ...
Ahmed A. Askalany, Bidyut B. Saha
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Isosteric heat of sorption of dihydrogen on alumina-supported palladium

Journal of the Chemical Society, Faraday Transactions, 1995
Pd/Al2O3 samples of different palladium loadings were prepared by an incipient wetness technique. The palladium dispersion (D) of each sample was estimated from its isotherm of hydrogen uptake measured volumetrically at 298 K. The isosteric heat of hydrogen sorption (q, including absorption and adsorption) on palladium was determined from a series of ...
Shu-Chin Chou   +2 more
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