Results 111 to 120 of about 9,679,616 (302)

Probing stratospheric transport and chemistry with new balloon and aircraft observations of the meridional and vertical N2O isotope distribution [PDF]

open access: yes, 2006
A comprehensive set of stratospheric balloon and aircraft samples was analyzed for the position-dependent isotopic composition of nitrous oxide (N2O). Results for a total of 220 samples from between 1987 and 2003 are presented, nearly tripling the number
Kaiser, Jan   +11 more
core   +2 more sources

Active Phase of Nickel Electrocatalysts Driving Alkaline Hydrogen Evolution

open access: yesAdvanced Materials, EarlyView.
Using depth‐resolved and operando spectroscopic measurements coupled with electrochemical mass spectrometry, the authors uncover the critical role of sub‐surface oxidised species in increasing the activity and durability of Ni‐based cathodes for hydrogen evolution.
Yifeng Wang   +17 more
wiley   +1 more source

Efficient Hydroxyl Diffusion Triggers Surface Hydronium Enrichment and Bulk Proton Participation to Boost Alkaline Hydrogen‐Evolving Reaction

open access: yesAdvanced Materials, EarlyView.
For the first time, we shed light on the surface‐to‐bulk diffusion, induction, and reaction behaviors of OH−, H+, and H2O species on model oxides for alkaline hydrogen‐evolving reaction (HER). We first demonstrate that bulk OH− diffusion significantly affects the generation of proton sources and the diffusion/reaction behaviors of protons, thus ...
Daqin Guan   +12 more
wiley   +1 more source

Side‐Chain‐Induced Interlayer Slipping in Metalloporphyrin COFs Enables Microenvironment and Spin‐State Regulation for Photocatalytic CO2 Reduction

open access: yesAdvanced Materials, EarlyView.
Alkoxy chain length drives a continuous transition from eclipsed AA to a serrated, slipped AA* configuration over Co‐porphyrin COFs. A moderate slip both contracts the pore channel to enrich CO2 and suppress hydrogen evolution, and enhances collective high‐spin of Co sites, which delivers a record CO production rate with high selectivity.
Jie He   +8 more
wiley   +1 more source

Combined stable isotope and gut contents analysis of food webs in plant-dominated, shallow lakes [PDF]

open access: yes, 2003
1. To determine feeding links between primary producers, invertebrates and fish, stable isotope analyses and gut content analyses of fish were conducted on the components of four shallow, eutrophic to hypertrophic, plant-dominated lakes. 2.
Susan Waldron   +3 more
core   +1 more source

Decoding Synergistic Pathways in Bimetallic MOFs for Advanced Oxidation Processes

open access: yesAdvanced Materials, EarlyView.
This review presents a unified framework linking metal pairing and framework design with electronic structure, redox cycling, oxidant activation, reactive‐species generation, and catalytic performance across photocatalytic and oxidant‐based BMOF‐AOPs. The resulting design principles guide the development of hydrolytically stable and efficient BMOFs for
Karim El‐Naggar   +2 more
wiley   +1 more source

Carbon stable isotope analysis of cereal remains as a way to reconstruct water availability: preliminary results [PDF]

open access: yes, 2011
Reconstructing past water availability, both as rainfall and irrigation, is important to answer questions about the way society reacts to climate and its changes and the role of irrigation in the development of social complexity.
Jenkins, Emma L.   +8 more
core   +1 more source

Spectrally Coordinated Plasmonic–Photothermal Photocatalysts for Mineralization of Mixed Indoor VOCs Under White LED Illumination

open access: yesAdvanced Materials, EarlyView.
A plasmonic–photothermal–photocatalytic hybrid comprising Cu(II)‐grafted TiO2, yolk–shell Au@SiO2, and reduced graphene oxide sheets (CuT/AuSi‐GS) harvests full‐spectrum white light‐emitting diode (LED) light via complementary photocatalytic oxidation, localized surface‐plasmon‐resonance‐induced electric‐field enhancement, and photothermal acceleration.
Minhyung Lee   +10 more
wiley   +1 more source

Sulfur isotope rations of sulfide minerals from the deposit of the Tsuchikura mine, Shiga Prafecture, Japan [PDF]

open access: yes, 1998
Sulfur isotope rations of sulfide minerals in the ore specimens from the deposit of the Tsuchikura mine are distrib-uted in a range from -0.8 to 5.4%, mostly from +0.5 to 3.0%, close to the previous data (from +1 to +3%) by Miyake and Sasaki (1980).
Harada, Kaori   +2 more
core   +1 more source

Atom–Cluster Synergy in Scalable Fe–Ru Dual‐Site Architectures Accelerates Alkaline Hydrogen Evolution

open access: yesAdvanced Materials, EarlyView.
A mechanochemically synthesized dual‐site electrocatalyst (RuNC@Fe1NC) accelerates alkaline hydrogen evolution via atomic‐level spatial decoupling. Oxophilic Fe single atoms effectively dissociate water, while adjacent Ru nanoclusters rapidly recombine hydrogen.
Jae‐Hoon Baek   +9 more
wiley   +1 more source

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