A dynamic isotope effect in the nucleophilic substitution reaction between F<sup>-</sup> and CD<sub>3</sub>I. [PDF]
Ayasli A +10 more
europepmc +1 more source
Strong inverse kinetic isotope effect observed in ammonia charge exchange reactions. [PDF]
Petralia LS +4 more
europepmc +1 more source
Integrating Spatial Proteogenomics in Cancer Research
Xx xx. ABSTRACT Background: Spatial proteogenomics marks a paradigm shift in oncology by integrating molecular analysis with spatial information from both spatial proteomics and other data modalities (e.g., spatial transcriptomics), thereby unveiling tumor heterogeneity and dynamic changes in the microenvironment.
Yida Wang +13 more
wiley +1 more source
Configurational entropy of ice XIX and its isotope effect. [PDF]
Gasser TM +3 more
europepmc +1 more source
Oil‐Coated Nanoplastics Induce Rapid Membrane Disruption and Severe Intestinal Injury
ABSTRACT Plastic food containers used in food delivery may pose underrecognized health risks by releasing micro‐ and nanoplastics (MNPs), especially when in contact with oil‐rich foods. Here, we show that cooking oil dramatically increased MNP release from polypropylene (PP) and polyethylene (PE)‐coated containers within 3 min of microwave heating ...
Ruwen Xie +17 more
wiley +1 more source
Chromosome segregation in Streptococcus pneumoniae depends on RocS, a bitopic protein whose membrane‐anchoring mechanisms were unclear. Using NMR and AFM, this study reveals that the widely conserved RocS anchor binds to membranes via a conserved kink‐helix motif which inserts into lipid nanodomains.
Ana Álvarez‐Mena +11 more
wiley +1 more source
Observation of the solvent enantio-isotope effect in asymmetric ring-opening of cyclic diaryliodoniums with selenocyanate. [PDF]
Li Y, Tao C, Duan L, Gu Z.
europepmc +1 more source
Liquid Bismuth Catalyst Enables High‐CO‐Selectivity in CO2 Hydrogenation
This work introduces a dynamic liquid bismuth catalyst for efficient CO2‐to‐syngas conversion. Stabilized molten Bi nanodroplets on a defective VOx support enable a reversible Bi3+/Bi0 redox cycle at moderate temperatures. Mechanistic insights reveal that Ni‐Bi dual sites synergistically activate H2 and cleave CO2, leading to high CO selectivity ...
Xinxin Lu +6 more
wiley +1 more source
Kinetic isotope effect reveals rate-limiting step in green-to-red photoconvertible fluorescent proteins. [PDF]
Breen B, Whitelegge JP, Wachter RM.
europepmc +1 more source
Therapeutic Gases in Biomedicine: Updates on Nitric Oxide and Beyond
Therapeutic gases, including NO, CO, H2S, H2, CO2, O2, and Xe, play vital roles in cellular signaling and repair. This review highlights the emerging carriers and delivery systems that enable controlled, localized gas release for diagnostic and therapeutic applications.
Syed Muntazir Andrabi +4 more
wiley +1 more source

