Results 201 to 210 of about 120,968 (266)

Gut–Brain Axis Modulation by Short‐Chain Fatty Acids Exerts Disease‐Modifying Effects in a Murine Model of Drug‐Resistant Epilepsy

Annals of Neurology, EarlyView.
Objective Drug‐resistant epilepsy (DRE) remains a clinical challenge, as therapies modifying disease trajectory are lacking. Increasing evidence implicates gut microbiota dysbiosis in epilepsy pathophysiology, with short‐chain fatty acids (SCFAs) emerging as key microbial metabolites with neuroprotective and anti‐inflammatory properties.
Akash A. Bera, Rossella Di Sapia, Greta Volpedo, Sneha Anand, Eray Sahin, Pasquale Baldassarre, Francesca Buffelli, Andrea Petretto, Chiara Lavarello, James D. Mills, Gabriele Cattaneo, Ilaria Craparotta, Eleonora Aronica, Antonella Riva, Pasquale Striano, Annamaria Vezzani, Teresa Ravizza   +16 more
wiley   +1 more source

Palladacarboxamide Capping Reagents for Carbon Isotope Labeling and Pharmaceutical Diversification

Angewandte Chemie, EarlyView.
Herein, we present a method for carbon isotope labeling of arylamides via the coupling of air‐stable palladium carboxamide complexes and boronic ester/acids. A wide variety of functionalized boronic esters and acids have been coupled with simple palladium carboxamides complexes.
Daniel V. Hoffmann, Anika Schick, Lasse Kjær, Vitus J. Enemærke, Clemens Kaussler, Jens Torp, Pablo Martínez‐Pardo, Charles S. Elmore, Troels Skrydstrup   +8 more
wiley   +1 more source

Stable Isotope Composition of Skin Layers Confirms Trophic Differentiation of Baird's and Sato's Beaked Whales (Berardius spp.) in the Western North Pacific. [PDF]

Rapid Commun Mass Spectrom
Filatova OA, Fedutin ID, Bobyr IG, Titova OV, Ragimov MO, Hoyt E, Tsurikov SM, Tiunov AV.   +7 more
europepmc   +1 more source

Formation of Gallium Monofluoride in the Coordination Sphere of Nickel

Angewandte Chemie, EarlyView.
The elusive gas‐phase species gallium monofluoride forms selectively in the coordination sphere of a nickel(II) centre as a product of C(sp3)–F bond activation, with a weakly coordinating anion as the fluorine source. The herein reported gallium monofluoride ligand acts as a very strong σ‐donor ligand at nickel and serves as a fluorine donor towards ...
Johannes Stephan, Samia Kahlal, Jean‐Yves Saillard, Marvin Mühlau, Lisa Gremmel, Christian Gemel, Roland A. Fischer   +6 more
wiley   +1 more source

Toward Multi(radio)metalated DNA: Enzymatic Polymerization of Metal‐Chelate‐Modified Deoxyribonucleoside Triphosphates

Angewandte Chemie, EarlyView.
This work presents the first enzymatic polymerization of defined metal‐chelator‐modified nucleotides that leverage polymerase fidelity for uniform (radio)metal loading with successful incorporation of five different metals: Ga, In, Tb, Lu, and Y.
Antonio A. W. L. Wong, François Bénard, David M. Perrin   +2 more
wiley   +1 more source

Isotopic Fractionation and Masking Effects during Biotransformation of Chlorinated Ethanes. [PDF]

Environ Sci Technol
Phillips E, De Vera J, Kümmel S, Bulka O, Chen W, Edwards E, Nijenhuis I, Gehre M, Sherwood Lollar B.   +8 more
europepmc   +1 more source

Nickel Wall-coated Microreactors for Enhanced Sensitivity and Peak Resolution in Compound-specific Carbon and Nitrogen Isotope Analysis. [PDF]

Anal Chem
Al-Ghoul H, Elsner M.
europepmc   +1 more source

Nitrogen Isotope Effects in Urea Metabolism: From Biochemistry to ¹⁵N Natural Abundance in Cancer. [PDF]

Int J Mol Sci
Tea I, Tcherkez G.
europepmc   +1 more source

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Binding Isotope Effects

Chemical Reviews, 2013
Katarzyna Swiderek, Piotr Paneth
exaly   +3 more sources

Diffusion Isotope Effects in Isotope Mixtures

Berichte der Bunsengesellschaft für physikalische Chemie, 1972
AbstractThe tracer diffusion of deuterium and tritium in the β‐phase of PdHn has been measured by means of special techniques, the time lag method with mass spectrometer or counter tube as detector, and the decay function of isotope exchange. It has been found that D atoms as tracer in β‐PdHn, i.e.
B. Bonn, E. Gans, G. Sicking, E. Wicke
openaire   +1 more source