Results 61 to 70 of about 386,226 (302)

Impact of the isotope effect on divertor detachment and pedestal structure in DIII-D

open access: yesNuclear Fusion
Dedicated H-mode hydrogen experiments has been conducted at DIII-D and are compared to a similar deuterium dataset under a range of divertor conditions, revealing significant effects of the isotope mass on divertor conditions and pedestal behavior.
R. Mattes   +8 more
doaj   +1 more source

Can Adsorption on Graphene be Used for Isotopic Enrichment? A DFT Perspective

open access: yesMolecules, 2018
We have explored the theoretical applicability of adsorption on graphene for the isotopic enrichment of aromatic compounds. Our results indicate that for nonpolar molecules, like benzene, the model compound used in these studies shows a reasonable ...
Mateusz Pokora, Piotr Paneth
doaj   +1 more source

SI‐bioATRP in Mesoporous Silica for Size‐Exclusion Driven Local Polymer Placement

open access: yesAdvanced Functional Materials, EarlyView.
An enzyme‐catalyzed surface‐initiated atom transfer radical polymerization (SI‐bioATRP) of an anionic monomer within mesoporous silica particles, using hemoglobin as a catalyst, allows for controlling the location of the formed polymer via size‐exclusion effects between the nanopores and the biomacromolecules, thereby opening routes to functional ...
Oleksandr Wondra   +8 more
wiley   +1 more source

Pressure and isotope effect on the anisotropy of MgB$_{2}$

open access: yes, 2005
We analyze the data for the pressure and boron isotope effect on the temperature dependence of the magnetization near $T_{c}$. Invoking the universal scaling relation for the magnetization at fixed magnetic field it is shown that the relative shift of ...
D. G. Hinks   +10 more
core   +1 more source

Oxygen isotope fractionation during N2O production by soil denitrification [PDF]

open access: yes, 2016
The isotopic composition of soil-derived N2O can help differentiate between N2O production pathways and estimate the fraction of N2O reduced to N2. Until now, δ18O of N2O has been rarely used in the interpretation of N2O isotopic signatures because of ...
Augustin, Jürgen   +5 more
core   +2 more sources

Toward Scalable Solutions for Silver‐Based Gas Diffusion Electrode Fabrication for the Electrochemical Conversion of CO2 – A Perspective

open access: yesAdvanced Functional Materials, EarlyView.
In this study, the preparation techniques for silver‐based gas diffusion electrodes used for the electrochemical reduction of carbon dioxide (eCO2R) are systematically reviewed and compared with respect to their scalability. In addition, physics‐based and data‐driven modeling approaches are discussed, and a perspective is given on how modeling can aid ...
Simon Emken   +6 more
wiley   +1 more source

Mobile Bipolaron

open access: yes, 2000
We explore the properties of the bipolaron in a 1D Holstein-Hubbard model with dynamical quantum phonons. Using a recently developed variational method combined with analytical strong coupling calculations, we compute correlation functions, effective ...
Bonca, J., Katrasnik, T., Trugman, S. A.
core   +1 more source

Enhanced Nitric Oxide Electroreduction to Ammonia via Modulating Spin‐Polarization of Fe Single‐Atom Catalysts

open access: yesAdvanced Functional Materials, EarlyView.
A strategic spin‐polarization suppression in Fe single‐atom catalysts is proposed to enhance electrocatalytic reduction of NO to NH3. Employing a top‐down electrospinning strategy, self‐supported FeSAC with Fe‐N3S1 coordination structure and spin‐state transition is engineered from high‐spin to low‐spin.
Jialing Song   +13 more
wiley   +1 more source

The effects of isotopic separation on closed nuclear fuel cycles [PDF]

open access: yes, 2016
This paper investigates the potential benefits to the fuel cycle outcomes of removing a single isotope during separation processes. Two strategies for managing the removed isotope are considered.
Flanagan, Robert Ryan
core   +1 more source

Enthalpy/Entropy Contributions to Conformational KIEs: Theoretical Predictions and Comparison with Experiment

open access: yesMolecules, 2013
Previous theoretical studies of Mislow’s doubly-bridged biphenyl ketone 1 and dihydrodimethylphenanthrene 2 have determined significant entropic contributions to their normal (1) and inverse (2) conformational kinetic isotope effects (CKIEs).
Aaron Fong   +2 more
doaj   +1 more source

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