Results 51 to 60 of about 120,968 (266)

Toward Fast Proton Shuttling in Acidic Oxygen Evolution Reaction

Advanced Functional Materials, EarlyView.
This review establishes proton transfer dynamics as a descriptor governing acidic OER activity, moving beyond the kinetic constraints derived from the proton coupled electron transfer. We discuss how deprotonation governs classical mechanisms, including adsorbate evolution mechanism (AEM), lattice oxygen mechanism (LOM) and oxide path mechanism (OPM ...
Ashish Gaur, Jaeyeong Kim, Sungwook Mhin, HyukSu Han   +3 more
wiley   +1 more source

Enthalpy/Entropy Contributions to Conformational KIEs: Theoretical Predictions and Comparison with Experiment

Molecules, 2013
Previous theoretical studies of Mislow’s doubly-bridged biphenyl ketone 1 and dihydrodimethylphenanthrene 2 have determined significant entropic contributions to their normal (1) and inverse (2) conformational kinetic isotope effects (CKIEs).
Aaron Fong, Matthew P. Meyer, Daniel J. O'Leary   +2 more
doaj   +1 more source

Microscopic Origin of Temperature‐Dependent Anisotropic Heat Transport in Ultrawide‐Bandgap Rutile GeO2

Advanced Functional Materials, EarlyView.
Rutile GeO2${\rm GeO}_{2}$ exhibits orientation‐dependent heat transport with temperature‐dependent anisotropy, showing higher cross‐plane thermal conductivity along [001] than along the equivalent in‐plane [100] and [010] directions. Temperature‐dependent TDTR measurements and first‐principles phonon calculations identify the microscopic phonon ...
Pouria Emtenani, Marta Loletti, Felix Nippert, Eduardo Bedê Barros, Zbigniew Galazka, Hans Tornatzky, Christian Thomsen, Juan Sebastián Reparaz, Riccardo Rurali, Markus R. Wagner   +9 more
wiley   +1 more source

Non-linear dependence of ion heat flux on plasma density at the L–H transition of JET NBI-heated deuterium–tritium plasmas

Nuclear Fusion
Recent JET D–T campaigns opened the possibility of unique isotope studies to investigate the L–H transition physics in view of reactor plasmas and to study the origin of the observed power threshold minimum.
P. Vincenzi, E.R. Solano, E. Delabie, C. Angioni, G. Birkenmeier, C. Maggi, R.B. Morales, H.J. Sun, E. Tholerus, JET Contributors   +9 more
doaj   +1 more source

Ion Beam Analysis of Hydrogen Isotope Effect at Ti-Mo Interdiffusion Interface

Yuanzineng kexue jishu, 2022
In order to explore the effect of Ti-Mo interdiffusion on metal hydrogen absorption, hydrogen absorption isotope effects at the TiMo alloy due to the interdiffusion at interface were investigated by using ion beam analysis (IBA) which is a non ...
DUAN Yiming;LI Cong;ZHANG Weiguang;WANG Meng;SHI Liqun
doaj  

Isotope effects observed in diluted D2O/H2O mixtures identify HOD-induced low-density structures in D2O but not H2O

Scientific Reports, 2022
Normal and heavy water are solvents most commonly used to study the isotope effect. The isotope effect of a solvent significantly influences the behavior of a single molecule in a solution, especially when there are interactions between the solvent and ...
Anna Stefaniuk, Sylwester Gawinkowski, Barbara Golec, Aleksander Gorski, Kosma Szutkowski, Jacek Waluk, Jarosław Poznański   +6 more
doaj   +1 more source

General Synthesis of Amorphous Pd‐Based Nanoparticles Towards Highly Efficient Nitrate‐to‐Ammonia Electrocatalysis

Advanced Functional Materials, EarlyView.
A family of amorphous palladium‐based multi‐component phosphides nanoparticles, synthesized via a robust one‐step wet‐chemical method, overcoming the immiscibility of different elements and the difficulty in forming a stable, disordered structure. When applied in the electrochemical nitrate reduction reaction, these nanocatalysts effectively suppress ...
Lei Xu, Chuhao Luan, Mingzi Sun, Weiwei Chen, Xiaozhi Liu, Chen Ma, Long Zheng, Gang Wang, Peng Han, Ping Gu, Xiao Wang, Chenhao Shu, Cheng Lyu, Zhenyu Zhang, Nailiang Yang, Hongyan He, Xiaohong Li, Dong Su, Bolong Huang, Wenjun Zhang, Ye Chen   +20 more
wiley   +1 more source

Chlorine Isotope Effects from Isotope Ratio Mass Spectrometry Suggest Intramolecular C-Cl Bond Competition in Trichloroethene (TCE) Reductive Dehalogenation

Molecules, 2014
Chlorinated ethenes are prevalent groundwater contaminants. To better constrain (bio)chemical reaction mechanisms of reductive dechlorination, the position-specificity of reductive trichloroethene (TCE) dehalogenation was investigated.
Stefan Cretnik, Anat Bernstein, Orfan Shouakar-Stash, Frank Löffler, Martin Elsner   +4 more
doaj   +1 more source

Affinity‐Tuned Albumin Hitchhiking Extends the Bioorthogonal Capture Window in Pretargeting Radiotheranostics

Advanced Healthcare Materials, EarlyView.
Pharmacokinetic engineering of clickable radioligands was achieved via albumin hitchhiking approach within a pretargeted radiotheranostics delivery platform. This approach reduced rapid renal elimination, expanded bioorthogonal capture window, boosted tumor uptake by ∼3.5‐fold, and improved the tumor‐to‐liver ratio by ∼6‐fold.
Xie He, Nicholas L. Fletcher, Gayathri R. Ediriweera, Yifei Zhu, James Humphries, Christopher B. Howard, Jiazheng Wang, Craig A. Bell, Kristian Kempe, Kristofer J. Thurecht   +9 more
wiley   +1 more source

Germanium isotope effect induced guest rattling and cage distortion in clathrates

Journal of Materiomics, 2018
Intermetallic clathrates are materials characterized by a large cage structure where guest atoms can move anharmonically, providing these materials exotic thermoelectric properties.
Ran Ang, Zhengshang Wang, Shang-Fei Wu, Pierre Richard, Zhenzhong Yang, Lin Gu, Gang Mu, Jingtao Xu, Ning Liu, Jun Tang   +9 more
doaj   +1 more source