Results 111 to 120 of about 104,171 (282)

Photocatalytic Aqueous Reforming of Methyl Formate

open access: yesAdvanced Materials, EarlyView.
A 3d‐metal Cu‐based atomically dispersed photocatalyst, supported on modified g‐C₃N₄, facilitates the photocatalytic selective hydrogen (7.5 mmol gcat−1 of hydrogen; nothing else than H2 and CO2) generation from methyl formate. This diverse system functions under mild conditions, providing high hydrogen yield, selectivity, and enduring stability ...
Dongxu Zuo   +13 more
wiley   +1 more source

Confining Quantum Dots Within Covalent Organic Framework Cages for Coupled CO2 Photoreduction and Value‐Added Chemical Synthesis

open access: yesAdvanced Materials, EarlyView.
A 3D/0D S‐scheme heterojunction photocatalyst is constructed by spatially confining ZnSe quantum dots within covalent organic framework (COF) porous cages, enabling coupled CO2 photoreduction and value‐added chemical synthesis. COF porous cages serve as nanoreactors, enriching reactant concentrations, and the S‐scheme heterojunction facilitates charge ...
Jingzhao Cheng   +9 more
wiley   +1 more source

Evaluation on Adsorption Separation of Low Concentration Xe and Kr by Activated Carbon Through Static and Dynamic Methods

open access: yesHe huaxue yu fangshe huaxue
Radioactive Xe isotopes are located at the heavy mass peaks of the fission mass distribution curves of 235U and 239Pu, with the characteristics of high fission yields and moderate half-life times, which have important application value in environmental ...
Bin CHEN   +6 more
doaj   +1 more source

Tailoring Advanced Metal‐Based Nanomedicines for Adaptable Nanodynamic Disease Therapies and Theranostics

open access: yesAdvanced Materials, EarlyView.
This review summarizes recent advances in metal‐based nanomaterials (MBNs) as multifunctional platforms for next‐generation diagnostics and nanodynamic therapies (NDTs), highlighting their structural tunability, diverse therapeutic modalities, and broad biomedical applications in oncology and infectious disease control.
Qihang Ding   +11 more
wiley   +1 more source

Using isotopic fingerprints in gastropod shells to validate commercial production pathway and geographic provenance

open access: yesRoyal Society Open Science
Growing demand for high-value seafood is fuelling provenance fraud, which threatens the sustainability of wild fisheries while posing biosecurity and human health risks.
Elise N. Boultby   +3 more
doaj   +1 more source

Tuning Active Hydrogen on Reconstructed RuO2/Co(OH)2 Catalysts for Selective Ammonia Synthesis

open access: yesAdvanced Materials, EarlyView.
A combined approach of precatalyst design and electrolyte engineering is employed to develop highly active, selective, and stable catalysts for electrochemical nitrate reduction. In alkaline media, the reconstructed RuO2/Co(OH)2 catalyst demonstrates impressive performance in ammonia synthesis, rechargeable Zn‐NO3− battery, and the remediation of ...
Anquan Zhu   +12 more
wiley   +1 more source

Unlocking Spin Dynamics: Spin‐Orbit Coupling Driven Spin State Interconversion in Carbazole‐Containing TADF Emitters

open access: yesAdvanced Optical Materials, EarlyView.
This study explores overlapping charge transport mechanisms in TADF materials and identifies spin‐orbit coupling as the dominant mechanism for triplet‐to‐singlet transition in carbazole‐based cyanoarene emitters. Computational investigations reveal a second spin‐orbit‐coupling‐mediated reverse intersystem crossing pathway, significantly enhancing the ...
Annika Morgenstern   +13 more
wiley   +1 more source

Visible‐Light‐Promoted Dearomatization for The Construction of Imidazole Scaffolds

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Lighting up flat aromatics: a visible‐light photocatalytic dearomative acylation of imidazo[1,2‐a]pyridines using α‐keto acids as sustainable acyl radical precursors is reported, leading to dual fluorescent imidazoles. Dearomatization is a powerful strategy for constructing complex carbocycles and heterocycles, though it typically relies on harsh ...
Silvia Roscales, Aurelio G. Csáky
wiley   +1 more source

One‐Pot Cascade Synthesis of Isoquinolinone‐Fused Quinoxalines Through Sequential Rh(III)/Pd(II) Catalysis

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A new one‐pot, dual catalytic strategy for the synthesis of polycyclic isoquinolinone‐fused quinoxalines from commercially available N‐(2‐acetamidophenyl)benzamides and 1,3‐diynes is reported. This transformation proceeds via Rh(III)/Pd(II)‐mediated sequential NH/CH activation/annulation. Detailed mechanistic studies elucidate the reaction pathway. A
Wei‐Jung Chiu   +3 more
wiley   +1 more source

Recent Advances in Ene Reactions with Carbon Enophiles

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Recent advances in the classical intra‐ and intermolecular ene nexus with carbon enophiles (alkenes, alkynes, arynes, and allenes) show a considerable increase in structural complexity and an enormous potential for functional applications in polymer science.
Thomas J. J. Müller
wiley   +1 more source

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