Results 91 to 100 of about 657,613 (309)

Einfluss des Ligandendesigns und nicht‐kovalenter Wechselwirkungen auf die isotaktische Ringöffnungspolymerisation von rac‐β‐Butyrolacton unter Verwendung von Salan‐ und Salalen‐Seltenen Erden Metallkatalysatoren

open access: yesAngewandte Chemie, EarlyView.
Polyhydroxybutyrate sind wichtige Vertreter von nachhaltigen Polyestern, bei denen jedoch die Kontrolle der Stereoregularität entscheidend ist, um vielversprechende thermische und mechanische Eigenschaften zu erzielen. Hochaktive Seltenerdmetall‐Salan/Salalen‐Komplexe erzielen isotaktisches (Pm bis zu 0.96 bei 0 °C) oder syndiotaktisches (Pr bis zu 0 ...
Stefanie Hörl   +4 more
wiley   +1 more source

Zwitterionic Dipeptide Surface Functionalization of Detonation Nanodiamond for Enhanced Control in Biological Environments

open access: yesAngewandte Chemie International Edition, EarlyView.
Here, we report a systematic investigation of novel zwitterionic dipeptide functionalized nanodiamonds to ensure colloidal stability over a broad pH range and in biological media. In vitro experiments in 2D and 3D cell cultures revealed a dipeptide‐dependent biocompatibility and cellular uptake.
Elisabeth Mayerhoefer   +5 more
wiley   +1 more source

Coordinative Ring‐Opening Polymerization of Limonene Carbamate towards Phosgene‐ and Isocyanate‐Free Polyurethane

open access: yesAngewandte Chemie International Edition, Accepted Article.
This study presents a phosgene‐ and isocyanate‐free route for the synthesis of polyurethanes using (R)‐limonene as a bio‐based starting material. The synthesis of the cyclic limonene‐based carbamate monomer LU is achieved in high yields using dimethyl carbonate as a sustainable, less hazardous phosgene surrogate and is verified by NMR, SC‐XRD, ESI‐MS ...
Jonas Futter   +4 more
wiley   +1 more source

Superconducting microresonators for detection and multiplexing [PDF]

open access: yes, 2008
Superconducting microresonators are drawing increasing attention for use in sensitive THz detection, especially for astronomical applications. These are relatively simple thin-film lithographically produced devices that are amenable to large-scale ...
Zmuidzinas, Jonas
core  

Ocrelizumab quantitation by liquid chromatography-tandem mass spectrometry

open access: yesJournal of Mass Spectrometry and Advances in the Clinical Lab, 2022
Introduction: Ocrelizumab is a monoclonal anti-CD20 antibody approved for the treatment of multiple sclerosis (MS). The clinical value of therapeutic drug monitoring (TDM) for this antibody in treatment of MS is unknown, and an adequately specific and ...
Erik I. Hallin   +4 more
doaj  

Thiotemplated Polyketide Chain Fusion and Reductive Cyclization Build the Reactive Butenolide Core of Malleicyprol

open access: yesAngewandte Chemie International Edition, Accepted Article.
Malleicyprol, a virulence factor of notorious animal and human pathogens of the Burkholderia pseudomallei (BP) group, features a molecular cyclopropanol warhead linked to a reactive butenolide core. Biosynthetic considerations suggested that this heterocycle was formed by the merger of two individual polyketide chains, but the precise mechanism has ...
Jonas Fiedler   +5 more
wiley   +1 more source

O gnosticismo antigo e o existencialismo contemporâneo

open access: yesCadernos Cajuína, 2017
Este trabalho pretende apresentar algumas das ideias de Hans Jonas presentes em sua análise sobre a relação entre os movimentos gnósticos da Antiguidade Tardia e do existencialismo heideggeriano a partir da tese de que ambos compartilham um caráter ...
Thiago Vasconcelos
doaj  

Influence of Ligand Design and Non‐Covalent Interactions on the Isoselective Ring‐Opening Polymerization of rac‐β‐Butyrolactone Using Salan and Salalen Rare‐Earth Metal Catalysts

open access: yesAngewandte Chemie International Edition, EarlyView.
Polyhydroxybutyrates are key sustainable polyesters, but controlling the stereoregularity is crucial for exhibiting the most promising thermal and mechanical properties. Highly active rare‐earth metal salan/salalen complexes yield isotactic (Pm up to 0.96 at 0 °C) or syndioenriched (Pr up to 0.91) PHB, depending on the steric demand of the ligand and ...
Stefanie Hörl   +4 more
wiley   +1 more source

O ético da condição humana na era da civilização tecnológica

open access: yesINTERthesis, 2009
http://dx.doi.org/10.5007/1807-1384.2009v6n1p48   A dimensão ética da condição humana em nossa época ocupa cada vez mais os espaços das discussões filosóficas. Neste cenário, o princípio da responsabilidade vem sendo amplamente pesquisado, sobretudo, por
Angela Luzia Miranda
doaj   +1 more source

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