The first example of a simple alkylated phosphinidene‐adduct (“phospha‐Wittig”) is reported. The synthesis of Me3PPC2F5 was enabled through reaction of the cyclotetraphosphane (PC2F5)4 with PMe3. The phosphanyl‐functionalized Wittig reagent Me3PC(CF3)P(C2F5)F was prepared by treating the diphosphane P2(C2F5)4 with PMe3.
Lukas Hartmann +7 more
wiley +1 more source
A Breed-Specific SNP Panel With Higher Theoretical Exclusion Power and Practical Equivalence to International Standards for Parentage Testing in Pura Raza Española Horses. [PDF]
Laseca N +5 more
europepmc +1 more source
Germylium Catalyzed Dehydrofluorination Reactions of Fluorinated Alkanes
Dehydrofluorination reactions of fluorinated alkanes catalyzed by germylium ions are reported. Computational studies of the mechanism revealed an E2 type mechanism involving a germane as a base to facilitate olefin formation in competition with an SN2 mechanism for hydrodefluorination.
Julie Borel +3 more
wiley +1 more source
Long-term clinical progression of Sneddon syndrome associated with antiphospholipid syndrome. [PDF]
Paes BP +3 more
europepmc +1 more source
Relay Approach: A Convergent Synthesis of Key Fragments en route to (+)‐Neosorangicin A
A selective synthesis of three key fragments of the antibiotically active (+)‐neosorangicin A is reported, providing a foundation for its convergent total synthesis and proof of strategy via a relay approach. ABSTRACT Herein, we report the synthesis of the three key fragments of the macrolide antibiotic (+)‐neosorangicin A, a compound exhibiting potent
Marvin Wenninger +6 more
wiley +1 more source
Predictive divergence in machine learning models for clinical mortality risk: A multicohort study of covid-19 patients. [PDF]
Magalhães JCN, Chiavegatto Filho ADP.
europepmc +1 more source
Syntheses and Properties of Pentafluoroethylplumbanes in the Oxidation States +II, +III, and +IV
Syntheses of pentafluoroethyl substituted plumbanes in the formal oxidation states +II, +III, and +IV are reported. The compounds were characterized by multinuclear NMR spectroscopy, including 207Pb NMR spectroscopy, mass spectrometry and single‐crystal x‐ray diffraction experiments. ABSTRACT Mono‐, bis‐, and tris(pentafluoroethyl)plumbanes of the type
Michael Grasse +4 more
wiley +1 more source
EVApeCognition: An 18-Year Dataset of Great Ape Cognition. [PDF]
Sánchez-Amaro A +107 more
europepmc +1 more source
Ultrasonic sensors are evaluated for their applicability in dynamic gas–liquid systems. By comparing sensor data with two independent optical reference methods, their robustness and reliability are demonstrated under varying flow conditions and tray geometries in column systems.
Niklas Breuer +2 more
wiley +1 more source
Going from Pt to PGM‐free Catalysts: Effects of Ink Compositions on PEM Water Electrolysis
Optimisation of cathode ink formulations regarding the ratio between catalyst, carbon and binder results in a boost in PEM water electrolysis performance. The optimisation can be transferred from pentlandites to platinum and selenide catalysts, wherein the metal chalcogenides show a stronger performance enhancement.
Janna Wierper +7 more
wiley +1 more source

