Results 41 to 50 of about 1,253 (148)

Preparation of a Reactive Phosphorus/nitrogen-Based Intumescent Flame Retardant Coating for Cotton Fabrics

open access: yesJournal of Natural Fibers, 2023
This study focuses on the synthesis of a reactive phosphorus-/nitrogen-based intumescent flame retardant (IFR) agent using diethyl phosphite, urea, and glutaraldehyde through Kabachnik-Fields reaction. We further studied the potential applications in IFR
Ying-Jun Gao   +4 more
doaj   +1 more source

NEW PHOSPHORUS COMPOUNDS K[PCL3(X)] (X= SCN, CN): PREPARATION AND DFT AND SPECTROSCOPIC STUDIES [PDF]

open access: yes, 2016
Indexación: Web of Science. Scielo.Two new phosphorus complexes, potassium trichlorothiocyanophosphate (III) (PTCTCP; K[PCl3(SCN)]) and potassium trichlorocyanophosphate (III) (PTCCP; K[PCl3(CN)]) were synthesized from the reaction of KSCN and KCN ...
GERLI–CANDIA, LORENA   +4 more
core   +3 more sources

Microwave-assisted synthesis of N,N-bis(phosphinoylmethyl)amines and N,N,N-tris(phosphinoylmethyl)amines bearing different substituents on the phosphorus atoms

open access: yesBeilstein Journal of Organic Chemistry, 2019
A family of N,N-bis(phosphinoylmethyl)amines bearing different substituents on the phosphorus atoms was synthesized by the microwave-assisted and catalyst-free Kabachnik–Fields reaction of (aminomethyl)phosphine oxides with paraformaldehyde and ...
Erika Bálint   +3 more
doaj   +1 more source

Generation of rectangular optical waves by relativistic clipping

open access: yes, 2013
Theoretical results are reported, concerning the reflection and transmission of few-cycle laser pulses on a very thin conducting layer, which may represent the surface current density of the massless charges of graphene.
Varro, Sandor
core   +1 more source

Switching the N‐Alkylation of Arylamines with Benzyl Alcohols to Imine Formation Enables the One‐Pot Synthesis of Enantioenriched α‐N‐Alkylaminophosphonates

open access: yesEuropean Journal of Organic Chemistry, Volume 2019, Issue 20, Page 3105-3111, June 2, 2019., 2019
The base‐free N‐alkylation of anilines with benzylic alcohols can be switched in favor of imine formation simply by switching between a closed and an open reaction system. Further functionalization of the in situ synthesized imine leads to α‐N‐alkylaminophosphonates via a one‐pot procedure in an atom‐economic fashion.
Natalie Hofmann, Kai C. Hultzsch
wiley   +1 more source

The Kabachnik–Fields Reaction: A Key Transformation in Organophosphorus Chemistry

open access: yesReactions
The Kabachnik–Fields (KF) reaction is a versatile three-component method for the condensation of amines, carbonyl compounds, and P–H reagents, enabling efficient synthesis of α-aminophosphonates—key bioactive and functional molecules.
Giovanni Ghigo   +2 more
doaj   +1 more source

A Review of Solvate Ionic Liquids: Physical Parameters and Synthetic Applications

open access: yesFrontiers in Chemistry, 2019
Solvate Ionic Liquids (SILs) are a relatively new class of ionic liquids consisting of a coordinating solvent and salt, that give rise to a chelate complex with very similar properties to ionic liquids.
Daniel J. Eyckens, Luke C. Henderson
doaj   +1 more source

On the Synthesis of [1,3]Azaphospholo[4,5‐f]quino(xa)lines and 2,3‐Dihydro‐[1,3]azaphospholo[4,5‐f]quino(xa)line 1‐oxides

open access: yesEuropean Journal of Organic Chemistry, Volume 28, Issue 17, May 21, 2025.
Syntheses of quinoline and quinoxaline derivatives fused with phosphacycles were developed from commercially available quinolin‐6‐amine and quinoxalin‐6‐amine. Abstract Despite their potential in areas such as medicinal chemistry and organic materials, scaffolds in which quinoline and quinoxaline are fused to phosphacycles such as 1,3‐oxaphosphole, 1,3‐
Mohamed Ali Dridi   +9 more
wiley   +1 more source

New Cytotoxic Derivatives by the Phosphorylation and Phosphinoylation of Diethyl α‐Amino‐α‐Aryl‐Methylphosphonates

open access: yesChemistry – A European Journal, Volume 31, Issue 21, April 9, 2025.
In order to make available potentionally bioactive new α‐aminophosphonic derivatives, diethyl α‐amino‐α‐aryl‐methylphosphonates were phosphorylated, phosphinoylated and thiophosphinoylated with the corresponding P‐chloride. The effect of a P=O to P=S modification was evaluated by single crystal X‐ray cristallography.
Márton Bircher   +6 more
wiley   +1 more source

Copper(II) Complexes of Organophoshonic Acids‐A Comparative Study

open access: yesJournal of Chemistry, Volume 8, Issue S1, Page S271-S281, 2011., 2011
Polynuclear copper(II) derivatives of 1‐hydroxyethylidenediphosphonic acid (HEDP), 1‐aminoethylidenediphosphonic acid (AEDP, H4L), α‐aminobenzylidene diphosphonic acid (ABDP, H4L), 1‐amino‐2‐carboxyethane‐ 1,1‐diphosphonic acid (ACEDP, H5L), 1,3 diaminopropane‐1,1,3,3‐tetra‐phosphonic acid (DAPTP, H8L), Ethylenediamine‐N,N′‐bis (dimethyl ...
B. Venkateswara Rao, D. M. Puri
wiley   +1 more source

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