Results 101 to 110 of about 17,233 (279)

Catalysis of 3-Pyrrolidinecarboxylic Acid and Related Pyrrolidine Derivatives in Enantioselective anti-Mannich-Type Reactions:  Importance of the 3-Acid Group on Pyrrolidine for Stereocontrol

open access: yes, 2008
The development of enantioselective anti-selective Mannich-type reactions of aldehydes and ketones with imines catalyzed by 3-pyrrolidinecarboxylic acid and related pyrrolidine derivatives is reported in detail.
Fujie Tanaka (2329276)   +10 more
core   +1 more source

State‐of‐the‐Art and Synthetic Challenges for Hydrosilane Production

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of hydrosilanes is currently energy intensive and their recycling is not considered. However, these compounds are important in many industrial fields but also for the valorization of oxygenated waste, towards a circular economy. This review compares the available synthetic routes and highlights the remaining challenges for the production ...
Gabriel Durin   +3 more
wiley   +1 more source

A Deep Analytical Investigation of the Aroma Chemistry of Incrocio Bruni 54 and Its Differentiation from Italian White Varieties

open access: yesFermentation
Incrocio Bruni 54 is a little-known white grape variety developed in the Marche region (Italy) from a cross between Verdicchio and Sauvignon Blanc to combine aromatic freshness with structure.
Maurizio Piergiovanni   +3 more
doaj   +1 more source

Nova metodologia de bromação dos adutos de morita-baylishillman E sua utilização como intermediários sintéticos na Preparação de heterociclos [PDF]

open access: yes, 2008
TCC (graduação) - Universidade Federal de Santa Catarina. Centro de Ciências Físicas e Matemáticas. Curso de Química.Neste trabalho será apresentada uma nova metodologia sintética simples e eficiente para a preparação de (Z)-2-(bromometil)-2-alcenoatos a
FERREIRA, Misael
core  

Strain Release of 1‐Azabicyclo[1.1.0]butanes as a Gateway to Highly Functionalized Azetidines: New Strategies and Structural Motifs

open access: yesChemistry – A European Journal, EarlyView.
Over the past decade, the interest in azetidines has continuously risen, by virtue of their highly appealing pharmaceutical properties. Monocyclic, spirocyclic, and bridged azetidines can be accessed by leveraging 1‐azabicyclo[1.1.0]butanes as precursors.
Yuri Gelato   +3 more
wiley   +1 more source

Structure Elucidation and Total Synthesis of Granolides A–C: Ethyl‐branched Sesquiterpenes From the Tropical Frog Gephyromantis granulatus

open access: yesChemistry – A European Journal, EarlyView.
Males of the tropical frog Gephyromantis granulatus carry unique ethyl‐branched sesquiterpenoid macrolactones in their scent glands. Their structure elucidation was performed by GC/MS, leading to the proposed structures of the granolides. A flexible enantioselective synthesis confirmed the structures and allowed determination of their absolute ...
Johanna Kuhn   +2 more
wiley   +1 more source

Impact of selenium-enriched Ligilactobacillus salivarius DACN818 on Zhacai: Insights from metabolomics and microbiomics

open access: yesFood Chemistry: X
Selenium enrichment can modulate the metabolic activities of microorganisms, yet how such changes influence the quality characteristics of fermented foods remains poorly understood.
Qingxu Guo   +5 more
doaj   +1 more source

O uso de 2,2,2-tricloro-1-ariletanonas como agentes benzoilantes [PDF]

open access: yes, 1987
Dissertação (mestrado) - Universidade Federal de Santa Catarina. Centro de Ciencias Fisicas e MatematicasA preparação de diversas amidas e hidrazidas pela reação de 2,2,2-tricloro-1-ariletanona com diferentes nucleófilos demostrou ser um processo ...
Rebelo, Ricardo Andrade
core  

N‐Aryl Acridone Derivatives as Effective Catalysts for Energy Transfer Reactions

open access: yesChemistry – A European Journal, EarlyView.
Acridones derivatives have high triplet energy, are simple accessible, and could be used in challenging [2+2] ENT reactions. ABSTRACT Organic photocatalysts capable of promoting high‐energy triplet energy transfer (EnT) remain limited, particularly for demanding [2+2] photocycloaddition reactions.
Francesco Calogero   +8 more
wiley   +1 more source

Ampliação do índice semi-empírico topológico para Alquilbenzenos e sua aplicação em estudos de Qspr / qsrr [PDF]

open access: yes, 2004
TCC (graduação) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas, Curso de Química.Neste estudo o Índice Semi-Empírico Topológico (IET) foi desenvolvido e otimizado com o objetivo de predizer a retenção cromatográfica de
PORTO, Ledilege Cucco
core  

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