Results 131 to 140 of about 338 (152)

Clathrate hydrate crystallization

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Clathrate hydrate crystallization has been an area of interest to chemical engineers from the point of view of crystal structure, thermophysical properties, phase equilibria, kinetics, industrial applications, and environmental (climate change) implications.
Peter Englezos
wiley   +1 more source

First SOLPS‐ITER Simulation Study of Japanese DEMO on Leakage of Seeded Ar Impurity

open access: yesContributions to Plasma Physics, EarlyView.
ABSTRACT For JA DEMO, one of the grand challenges is efficiently handling the extreme power loads onto plasma‐facing components, particularly the divertor targets. Impurity seeding is an essential strategy for increasing the radiation losses and thereby reducing the heat load on the targets.
Hang Si   +6 more
wiley   +1 more source

Caving‐enhanced geothermal system overwhelms fracturing‐ and pipe‐enhanced geothermal system in heat extraction

open access: yesDeep Underground Science and Engineering, EarlyView.
Our study reveals that caving‐enhanced geothermal systems (C‐EGS) with adequately fractured reservoirs achieve optimal heat extraction by minimizing preferential flow paths, while conventional fracturing (F‐EGS) and pipe‐based (P‐EGS) systems suffer accelerated thermal drawdown.
Fangchao Kang   +4 more
wiley   +1 more source

Transition Metal Compounds as Thermochromic Materials: Classification, Properties, Limitations, and Applications

open access: yesEcoEnergy, EarlyView.
This review systematically examines how different transition metal compounds—such as binary and multinary metal oxides, halides, sulfides, and salts—exhibit thermochromism based on the d‐electron configurations of their transition metal cations. It focuses on three main mechanisms of thermochromism: phase transition, charge transfer, and bandgap change.
Jie Wang   +5 more
wiley   +1 more source

Light‐Induced Structural Reorganization of Fe Centers Unlocks High Efficiency of Visible‐Light Photo‐Fenton Water Cleaning Catalyst

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Bimetallic Cu and Fe oxide species supported on porous silica with interparticle mesoporosity act as efficient photo‐Fenton‐like catalysts under visible light. Photogenerated electrons drive the Cu2+/Cu1+ redox cycle. Part of Cu1+ is responsible for the regeneration of the Fe3+/Fe2+ cycle at neutral pH. Light irradiation additionally induces structural
Andraž Šuligoj   +6 more
wiley   +1 more source

Doped Ta3N5 Semi‐Transparent Photoanode Enabling Stable Solar Redox Flow Cell Operation

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Synergistic Al:TiO2 underlayer and La doping stabilize semitransparent Ta3N5 photoelectrodes for over 90 h of continuous operation in alkaline solution. The solar redox flow cell demonstrated 12 photocharge–discharge cycles at ∼55% coulombic efficiency using a K4Fe(CN)6|1,5‐DHAQ chemistry. Solar redox flow cells (SRFCs) are photoelectrochemical devices
Filipe Moisés M. Francisco   +4 more
wiley   +1 more source

Diphenyl Disulfide‐Promoted Racemization of 1‐Arylethanols for Photobiocatalytic Dynamic Kinetic Resolution

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Purple‐light activation of aggregated diphenyl disulfide unlocks the photocatalyst‐free racemization of 1‐arylethanols. The resulting sulfur radical process operates under mild conditions and couples with the enzymatic acylation by Candida antarctica lipase B in a photobiocatalytic dynamic kinetic resolution, revealing new opportunities for sulfur ...
Cristina Guolo   +2 more
wiley   +1 more source

Bridging computational and clinical strategies for presurgical identification of epileptogenic networks

open access: yesEpilepsia Open, EarlyView.
Abstract Objective About one third of epilepsy patients are drug‐resistant. Resective epilepsy surgery remains a key treatment option but depends critically on accurate identification of the seizure onset zone (SOZ), which is still guided mainly by subjective visual inspection of electrophysiological signals.
Tena Dubcek   +5 more
wiley   +1 more source

Thermally activated delayed fluorescence exciplex sensitizers with fast reverse intersystem crossing for improving efficiency stability of organic light‐emitting diodes based on multi‐resonance emitters

open access: yesFlexMat, EarlyView.
Two exciplex emitters are constructed based on a host‐guest doping strategy, and their exciton dynamics processes are investigated in depth. High‐performance OLEDs are fabricated by employing these exciplexes as emitters or sensitizers, providing excellent electroluminescence efficiencies and low efficiency roll‐offs.
Jingwen Xu   +4 more
wiley   +1 more source

Spirobifluorene fusion in multiple resonance frameworks enables efficient pure‐red OLEDs with narrowband emission and suppressed efficiency roll‐off

open access: yesFlexMat, EarlyView.
An orthogonal spirobifluorene‐fusion strategy is introduced for B/N/O‐alternated MR frameworks, enabling improved kRISC (5.46 × 103 s−1), high ΦPL (97%), and narrow‐band pure‐red emission. Vacuum‐evaporated OLEDs incorporating this emitter achieve an EQEmax >40% (FWHM = 36 nm) and exhibit exceptionally low efficiency roll‐off at high luminance ...
Yan‐Yun Jing   +7 more
wiley   +1 more source

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