Results 231 to 240 of about 14,370,095 (307)

Aktivierung von Metallkomplexen durch Ultraschallwellen für eine gezielte Krebstherapie

open access: yesAngewandte Chemie, EarlyView.
Ultrasound enables non‐invasive activation of metal‐based therapeutics deep within tumors. Acoustic cavitation can drive sonodynamic reactive oxygen species generation or mechanochemical metal–ligand bond dissociation, enabling controlled release of bioactive payloads.
Félix Grosjean   +3 more
wiley   +1 more source

Self-organized optofluidic locking enables stable single-frequency lasing in dynamic liquid media. [PDF]

open access: yesSci Adv
Duan R   +19 more
europepmc   +1 more source

Characterization of a Fungal Modular Polyketide Synthase System Reveals an Unusual Strategy for Polyketide Chain Initiation

open access: yesAngewandte Chemie, EarlyView.
Fungal modular polyketide synthases (PKSs) remain largely unexplored. Functional characterization of the LasC/LasD assembly line established its role in strasseriolide C biosynthesis and suggested an unexpected strategy for chain initiation, in which a malonyl unit is transferred from the module 2 acyl carrier protein (ACP) domains to the loading ACP ...
Qiaolin Ji   +5 more
wiley   +1 more source

Substrate‐Dependent Crosslinking by the Cytochrome P450 From Aminopyruvatide Biosynthesis

open access: yesAngewandte Chemie, EarlyView.
Substitutions in the aminopyruvatide precursor peptide altered the C─C linkage formed from a YLY motif by the P450 ApyO to a N─C linkage in a WLY motif. Moreover, constitutional isomers crosslinked by C─C and C─O linkages were formed from YYY or YWY motifs. ABSTRACT Cytochrome P450s catalyze an array of reactions including crosslinking of aromatic side
Chandrashekhar Padhi   +6 more
wiley   +1 more source

Suppression of Peierls Instability in a Metal−Halide Porous Framework

open access: yesAngewandte Chemie, EarlyView.
Peierls distortion in one‐dimensional Pt‐I chains is suppressed by confinement within the periodic electrostatic environment of a porous Cu–I framework. X‐ray crystallography shows equivalent Pt–I distances without bond alternation, and conductivity of the Pt‐I chains is greatly enhanced.
Ning Zhou   +3 more
wiley   +1 more source

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