Results 111 to 120 of about 1,983 (261)

Regulating Copper Nuclearity in Metal–Organic Frameworks for the Hydrogenation of Carbon Dioxide

Small Methods, EarlyView.
CO2 hydrogenation on Cu‐metalated MOFs at gas–solid and liquid–solid interfaces depend strongly on the nuclearity of the Cu, which can be adjusted via the density of defects and the synthesis process. In both reaction regimes, methanol formation is favored on Cu clusters rather than on isolated Cu sites, highlighting the critical role of metal ...
Soufiane Bahou, Chanokporn Kosri, Ashour A. Ahmed, Hesham Mena, Riya Sehrawat, Sebastian Wohlrab, Thanapa Numpilai, Pongtanawat Khemthong, Thongthai Witoon, Kajornsak Faungnawakij, Bunyarat Rungtaweevoranit, Ali Abdel‐Mageed   +11 more
wiley   +1 more source

High‐Density Iron Nanostructures Grown on Electrospun PVA/Pectin Fibers via Seed‐Mediated Strategy for As(V) Remediation

Small Methods, EarlyView.
A seed‐assisted anisotropic growth strategy enabling unprecedented iron loading and controlled anisotropic nanostructure formation on electrospun PVA/pectin nanofibers is presented. By decoupling nucleation and growth through sequential Fe2+ then Fe3+ doping, it achieves a 12‐fold increase in accessible iron content, producing rice‐grain‐like ...
Ayelen C. Santos, Silvina Cerveny, Carolina Iacovone, Cinthia P. Ramos, Angel J. Marzocca, Silvia Goyanes   +5 more
wiley   +1 more source

Organic and Inorganic Pollutants, Oxidative Stress Biomarkers, and Electrophoretic Protein Profiles in an Endangered Thresher Shark (Alopias vulpinus) From Southeastern Brazil: A Case Study

Environmental Toxicology, EarlyView.
ABSTRACT A comprehensive screening of different environmental contaminants (total metals, thermostable metal fractions associated with detoxification, and persistent organic pollutants) was conducted in an endangered common thresher shark (Alopias vulpinus ) individual incidentally captured in southeastern Brazil.
Sidney Fernandes Sales Junior, Amanda Pontes Lopes, Heloíse Martins de Souza, Regina Fonseca, Enrico Mendes Saggioro, Francielli Monteiro Casanova, Kamila Cezar Gramlich, Tatiana Dillenburg Saint'Pierre, Carlos German Massone, Renato Carreira, Rachel Ann Hauser‐Davis   +10 more
wiley   +1 more source

Environmental Contaminant Accumulation in Freshwater Turtles Inhabiting Three Rivers of the Permian Basin, New Mexico, USA

Environmental Toxicology, EarlyView.
ABSTRACT Freshwater turtles are valuable sentinels of aquatic systems due to their long lifespans and resilience in environments impacted by contaminants. The Permian Basin, dominated by the oil and gas sector, spans western Texas and southeastern New Mexico, USA, including the Pecos River and its tributaries, the Delaware and Black Rivers.
Ana G. G. Sapp, W. Gregory Cope, Christopher E. Moorman, Frank X. Weber, Ivana Mali   +4 more
wiley   +1 more source

Morphology and Photoelectrochemical Properties of Sputtered WO3:Mo Anodes

Zeitschrift für anorganische und allgemeine Chemie, EarlyView.
WO3:Mo thin films for photoelectrochemical water splitting were deposited by sputtering from a W:Mo target. Substrate temperature, pressure, oxygen partial pressure, deposition rate, and film thickness were systematically varied. The results show that the substrate temperature is the dominant parameter governing both the film morphology and the ...
David Adner, Michael Arnold, Julia Hilbig, Ralf Bandorf, Arno Görne, A. Wouter Maijenburg, Marko Turek, Christian Hagendorf, Stephan Ulrich   +8 more
wiley   +1 more source

A Multi‐Analytical Approach for the Compositional Characterization and Chronological Discrimination of Benin (Nigeria) Metal Sculptures

Archaeometry, EarlyView.
ABSTRACT This study presents a multi‐analytical archaeometric approach for the compositional characterization and chronological discrimination of Benin metal sculptures in relation to the 1897 Punitive Expedition. The methodology integrates elemental composition (XRF and ICP), stable lead isotope ratios (MC‐ICP‐MS) for alloy system characterization ...
I. Torraba, D. A. Ahumada, H. Bagán, A. Tarancón, S. Eisenhofer, J. F. García   +5 more
wiley   +1 more source

Early Bronze Age Copper Circulation in the Guadalentín and Segura Valleys (SE Spain)

Archaeometry, EarlyView.
ABSTRACT Identifying the sources of copper used in Early Bronze Age metalwork from south‐east Spain is key to resolving a long‐running debate concerning centralized control, or lack thereof, over El Argar society's economic organisation. This study provides the first substantial integrated programme of EDXRF and MC‐ICP‐MS analyses for copper‐base ...
Dirk Brandherm, Ignacio Montero‐Ruiz
wiley   +1 more source

Tracing Identity in a Fragmented Past: Multi‐Proxy Analysis of Human Skeletal Remains From Dungowan Creek, New South Wales, Australia

Archaeometry, EarlyView.
ABSTRACT Human skeletal remains constitute critical archaeological evidence for reconstructing past societies, yet their investigation requires careful ethical, cultural, and legislative consideration. This paper reports on the discovery, recovery and analysis of a set of skeletal remains encountered during a cultural heritage management (CHM ...
Antonella Skepasianos, Cameron Neal, Sarah Croker, Anthony Dosseto, Michelle Fermor, Steve Talbott, Warren Mayers, Joel Mason, Florian Dux, Luke Kirkwood, Pamela Kottaras, Alan N. Williams   +11 more
wiley   +1 more source

Late Iron Age and Early Roman Brooches From the Lower Rhine Area: Provenance of the Metal Supply Traced Through Lead Isotopes

Archaeometry, EarlyView.
ABSTRACT Geochemical analysis of five brooch types from the Lower Rhine area dated to the last century bc and first century ad is used to constrain resource use, exchange and mobility. Lead isotope ratios demonstrate an Iberian provenance for copper in bronze Late Iron Age brooches.
A. A. T. Ruiter, B. J. H. van Os, J. B. V. Hermsen, G. R. Davies, S. W. Merkel   +4 more
wiley   +1 more source

Influence of Laser Repetition Rate, Fluence and Spot Size on LA‐Q‐ICP‐MS/MS 87Sr/86Sr Precision: Insights from Apatites and Silicate Glasses

Geostandards and Geoanalytical Research, EarlyView.
Key Points Higher laser repetition rate, fluence and larger spot size increase signal intensity. Higher laser repetition rate produces overlaps in aerosolised particles, improving signal stability and precision. For Sr‐rich materials, moderate spot diameter (≤ 60 μm), 3 J cm‐2 fluence and ≥ 12 Hz repetition rate are recommended.
Edafe O. Ominigbo, David T. Murphy, Kate E. Jenkins, Mitchell de Bruyn, Karine H. Moromizato   +4 more
wiley   +1 more source