Stabilizing Frustrated Phase Transitions in Selective Oxidation Reactions
Using multimodal operando spectromicroscopy, the frustrated phase transition responsible for selective oxidation over cobalt oxide spinel catalysts is identified, corresponding to combined surface reaction and Mars‐van Krevelen (MvK) dynamics. This regime is disrupted by the formation of mobile vacancies and the depletion of active oxygen at high ...
Luis Sandoval‐Diaz +11 more
wiley +1 more source
This work presents highly consistent GaN‐based thin‐film gas sensors prepared by MOCVD for non‐invasive breath analysis. The sensors exhibit tunable selectivity from oxidizing to reducing gases by incorporating In composition, ultra‐low detection limits and humidity resistance.
Yuxuan Wang +9 more
wiley +1 more source
Effective adsorption of methylene blue using natural Saudi zeolite as a low-cost sustainable adsorbent. [PDF]
Alsuhybani M +5 more
europepmc +1 more source
ABSTRACT Microalgal biomass has emerged as a valuable resource in recirculating aquaculture systems (RAS), due to its natural capacity to recover nutrients. In addition, microalgae are potential source of fish‐feed in the aquaculture industry. However, its application in RAS needs careful consideration, as microalgae can interact with geosmin, a common
Asmit Baral +3 more
wiley +1 more source
ANOVA and design expert model for discoloring of azo benzene derivative dye used mesoporous aluminum silicon oxide nanoparticles. [PDF]
Adly YM +5 more
europepmc +1 more source
This study shows that guanidinium cations weakly attract one another in water and form like‐charge contact ion pairs. From NMR, we determine the free energy of ion‐pair formation to be ≈${\approx }$ –0.5 kJ mol−1${\rm mol}^{-1}$, consistent with all‐atom MD simulations and DFT calculations.
Denys Biriukov +8 more
wiley +1 more source
Sustainable xanthan-based superabsorbent hydrogel with enhanced durability for repeated nitrate remediation in drinking water. [PDF]
Mahinroosta M +2 more
europepmc +1 more source
Low Parsons–Zobel slope of metal–solution interfaces: A theoretical comparison of three causes
Abstract Rational design of electrochemical energy conversion and storage devices hinges on a fundamental understanding of the electrical double layer (EDL) at the electrode–electrolyte interface. The classical Gouy–Chapman–Stern model of EDL predicts a unity Parsons–Zobel (PZ) slope, which is derived from the relation between inverse measured ...
Weiqiang Tang +3 more
wiley +1 more source
Magnetic Fe<sub>1-<i>x</i></sub> Zn <sub><i>x</i></sub> Fe<sub>2</sub>O<sub>4</sub> nanoparticles as dual adsorbents for Cr(vi) and Direct Red 79: kinetics, isotherms, and mechanistic insights. [PDF]
Thi Hau V +6 more
europepmc +1 more source
Molecular Cages Based Materials for CO2 Capture, Separation, and Conversion
Molecular cages (MCs), boasting soluble, regenerable traits and precisely tunable structures, exhibit substantial potential for efficient CO2 capture, separation, and conversion. This review thoroughly explores MCs' recent advancements, analyzes current unresolved challenges, and provides forward‐looking perspectives to tackle pressing carbon‐related ...
Ding Zou +4 more
wiley +1 more source

