Zwitterionic Mn(III)‐Tetraphenyl Porphyrins: Water‐Soluble MRI Contrast Agents with High Relaxivity
Mn(III)‐based contrast agents (MBCAs) are promising and potentially safer alternatives to the Gd(III)‐based contrast agents (GBCAs) currently used in MRI. This study reports the synthesis, physicochemical characterization and first in vivo application of novel Mn(III)‐tetraphenylporphyrin chelates, bearing zwitterionic sulfobetaine or N‐oxide groups ...
Darius Ludolfs +10 more
wiley +1 more source
High-Quantum-Yield [Eu(Phen)<sub>2</sub>(NO<sub>3</sub>)<sub>3</sub>] Phosphor Exhibiting Zero Thermal Quenching under Real Operating Conditions (30-150 °C). [PDF]
Raymundo Silva KS +5 more
europepmc +1 more source
The growing demand for lithium‐ion batteries in the European Union contributes to critical raw material scarcity. This challenge can be addressed by establishing a circular economy, making use of highly efficient and economical recycling processes. The efficiency of these processes depends on high‐purity material streams and thus on the availability of
Simon Ziegler +4 more
wiley +1 more source
This minireview highlights recent advances in catalyst development and mechanistic strategies that enable photochemical and photocatalytic reactivity under 700–1000 nm NIR light, emphasizing how long‐wavelength excitation expands opportunities in both synthetic chemistry and biology.
Santosh K. Pagire +3 more
wiley +2 more sources
From Electrolyte to Alloys: Electrodeposition of Rare Earth Element-Based Thin Films-State of the Art. [PDF]
Rudnik E.
europepmc +1 more source
In order to rationalise the magnetic properties of a newly synthesised Co2III$_{2}^{III}$Co6II$_{6}^{II}$ coordination cluster it was found essential to exploit the freedom to choose the local coordinate frames for describing the high‐spin CoII centres.
Joscha Nehrkorn +5 more
wiley +1 more source
Unraveling Thermal Interactions in Lanthanide-Doped Phosphors: A Frequency-Domain Analysis Approach. [PDF]
Romero M +4 more
europepmc +1 more source
Staggered, square, and heavily bent dimers occur in the five known solvatomorphs of paddlewheel (PW) complex [PtVO(SOCPh)4]. These and other structural motifs are well within energetic reach due to the shallow potential energy surface that guides dimerization and are included in a revised classification of available structural data on heterobimetallic ...
Olga Mironova +3 more
wiley +1 more source
Electronic energy levels and optical spectra of trivalent lanthanide ions in water - Ce(III), Pr(III), Nd(III), Sm(III), Eu(III), Gd(III), Tb(III), Dy(III), Ho(III), Er(III), Tm(III), and Yb(III). [PDF]
Nielsen VRM, Sørensen TJ.
europepmc +1 more source
Tailoring exciplex formation in metal-induced supramolecular organization.
Le-Hoang G, Guénée L, Piguet C.
europepmc +1 more source

