Results 231 to 240 of about 45,379 (303)

Synthesis and Characterization of Anhydrous Cerium(III) Acetate, [Ce(CH3COO)3], and its Interconversions to Hydrated Phases

Zeitschrift für anorganische und allgemeine Chemie, EarlyView.
The crystal structure of anhydrous cerium(III) acetate [Ce(CH3COO)3] is reported. Additionally, the interconversions in the cerium(III) acetate hydrate system were studied by in situ and ex situ PXRD. We report the synthesis and crystal structure of anhydrous cerium(III) acetate [Ce(CH3COO)3] (1) as well as the interconversions to different hydrated ...
Niklas Ruser, Vanessa Behrens, Christoph Meier, Jennifer Theissen, Felix Steinke, Christian Näther, Jonas Gosch, Norbert Stock   +7 more
wiley   +1 more source

From mononuclear to pyrazine-bridged dinuclear samarium(iii) complexes: role of fluxidentate coordination in luminescent and thermal behavior. [PDF]

RSC Adv
Aggarwal V, Singh D, Dalal S, Bhagwan S, Kumar S, Malik RS, Kumar P, Sindhu J.   +7 more
europepmc   +1 more source

Organotitanyl “TiCp” Fragment Capping the Bowl‐Shaped Unit in the Ternary Anion [(Cp)Ti(Sn3Bi3)]2−

Zeitschrift für anorganische und allgemeine Chemie, EarlyView.
A novel ternary anion, [(η5‐Cp)Ti(Sn3Bi3‐κ3)]2− composed of a cyclopentadienyl titanium fragment coordinated by a Sn3Bi3 bowl‐shaped cluster unit, is reproted. Unlike homoatomic nine‐atom clusters of heavier tetrel elements, which retain their identity upon dissolution, intermetalloid clusters are not formed directly from ternary alkali‐metal alloys in
C. E. Fajman, M. Botta, V. Hlukhyy, T. F. Fässler   +3 more
wiley   +1 more source

Crystal Structure and Eu2+ Luminescence of the Lithium Alkaline‐Earth Silicate Fluoride LiBa2SiO4F

Zeitschrift für anorganische und allgemeine Chemie, EarlyView.
With Li2BaSiO4F, a new lithium alkaline‐earth silicate fluoride could be synthesized via high‐temperature solid‐state reaction. Crystal structure and luminescence properties upon Eu2+ activation were investigated. A high‐temperature solid‐state synthesis in weld‐shut tantalum ampoules yielded a new alkaline‐earth silicate fluoride, LiBa2SiO4F.
Kilian M. Rießbeck, Hannah Holzer, Markus Seibald, Christiane Stoll, Frauke Philipp, Hubert Huppertz   +5 more
wiley   +1 more source

Contrasting single-molecule magnet behaviour in dysprosium and terbium bis(stannolediide) complexes. [PDF]

Nat Chem
Sun X, Hinz A, Maier S, Gillhuber S, Jin D, Saito M, Weigend F, Schlittenhardt S, Moreno-Pineda E, Wernsdorfer W, Ruben M, Roesky PW.   +11 more
europepmc   +1 more source

Synthesis and Characterization of the Molybdenum Carbonyl‐Functionalized Zintl Ions [(η4‐Pb4)Mo(CO)3]4− and [Pb4{Mo(CO)3}3]6−

Zeitschrift für anorganische und allgemeine Chemie, EarlyView.
The reaction of the tetrahedral [Pb4]4− with Mo(CO)4(tmeda) yields two different Mo(CO)3‐functionalized clusters which can both be related to known clusters by the same substitution pattern following the isolobal principle. The crystal structures of [Na([2.2.2]crypt)]2Na2[(η4‐Pb4)Mo(CO)3] · 8.7NH3 and Na6[Pb4{Mo(CO)3}3] · 22NH3 are reported.
Michael Witzmann, Nikolaus Korber
wiley   +1 more source

Chemoselective and stereoselective charge transfer dynamic quenching with triazacyclononane europium and terbium tetra-azatriphenylene complexes.

Dalton Trans
Wen X, Black DJ, Pal R, Parker D.
europepmc   +1 more source

Synchrotron beamline setup enabling quasi‐simultaneous PXRD and XANES measurements: case study of Fischer–Tropsch catalyst reduction at 60 bar

Journal of Synchrotron Radiation, EarlyView.
This paper presents a beamline setup that allows the combination of in situ powder X‐ray diffraction (PXRD) and X‐ray absorption near‐edge structure (XANES) measurements within a single experimental cycle to investigate cobalt catalyst structures and properties under real conditions.Powder X‐ray diffraction (PXRD) and X‐ray absorption near‐edge ...
Lipeng Yao, G. Leendert Bezemer, Irene. M. N. Groot, Oleg Konovalov, Maciej Jankowski   +4 more
wiley   +1 more source

Yb₂-Tb Upconversion in a Hetero-Trimetallic Molecular Lanthanide Complex. [PDF]

Angew Chem Int Ed Engl
Kofod N, Thornton ME, Richardson A, Smith C, Gurung S, Parkinson P, Faulkner S, Hay S, Natrajan LS.   +8 more
europepmc   +1 more source

Gepta‐EX: a multi‐channel germanium detector for X‐ray absorption fine structure

Journal of Synchrotron Radiation, EarlyView.
Gepta‐EX is a compact seven‐channel high‐purity germanium detector designed to deliver high‐resolution fluorescence X‐ray absorption fine‐structure measurements at photon energies where silicon detectors become effectively transparent. It provides excellent energy resolution across a broad energy range, avoids silicon escape‐peak artifacts, and offers ...
Abdul K. Rumaiz, Francesca Capocasa, Anthony J. Kuczewski, Giovanni Pinaroli, Thomas Krings, Bruce Ravel, D. Peter Siddons   +6 more
wiley   +1 more source