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Smart Bioinspired Material‐Based Actuators: Current Challenges and Prospects
Advanced Intelligent Systems, Volume 7, Issue 3, March 2025.This work gathers, in a review style, an extensive and comprehensive literature overview on the development of autonomous actuators based on synthetic materials, bringing together valuable knowledge from several studies. Furthermore, the article identifies the fundamental principles of actuation mechanisms and defines key parameters to address the size
Alejandro Palacios +4 more
wiley +1 more source
Angewandte Chemie, EarlyView.Single‐atom growth from [Zr@Sb12]2− to [Zr@Sb13]3− disrupts the closed‐shell S2P6 superatomic configuration and markedly attenuates three‐dimensional (3D) aromaticity. Ultrafast spectroscopy further links stronger spherical aromaticity to slower excited‐state relaxation, establishing an atom‐resolved structure‐aromaticity‐dynamics relationship ...
Yun Zhang +7 more
wiley +2 more sources
Separation of Minor Actinides from Lanthanides by Dithiophosphinic Acid Extractants [PDF]
, 2008 The selective extraction of the minor actinides (Am(III) and Cm(III)) from the lanthanides is an important part of advanced reprocessing of spent nuclear fuel.
Klaehn, J. R. +7 more
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Valencies of the lanthanides [PDF]
, 2017 The valencies of the lanthanides vary more than was once thought. In addition to valencies associated with a half-full shell, there are valencies associated with a quarter- and three-quarter-full shell.
David A. Johnson +3 more
core +1 more source
Angewandte Chemie, EarlyView.Spatial organization of Eu/Tb centers in EuTb‐FDA MOFs is employed to regulate Tb‐to‐Eu energy transfer configuration for ratiometric PFAS sensing. Directional energy transfer amplifies PFAS‐induced optical perturbations into opposite lanthanide emission responses, with enhanced Tb emission and quenched Eu emission, thereby amplifying the sensing ...
Jiatong Huo +5 more
wiley +2 more sources
NHC‐Copper(I)‐Mediated Functionalization of White Phosphorus
Angewandte Chemie, EarlyView.White phosphorus is functionalized by N‐heterocyclic carbene supported copper(I) complexes through redox‐neutral steps. Treatment of the resulting complexes with electrophiles releases the ligands from the metal center as asymmetrically substituted organophosphorus butterfly compounds.
Thomas M. Horsley Downie +4 more
wiley +2 more sources
The Astrophysical JournalIn kilonovae, freshly synthesized r -process elements imprint features on optical spectra, as observed in AT2017gfo, the counterpart to the GW170817 binary neutron star merger.
Nicholas Vieira +5 more
doaj +1 more source
Tunable Oxygen Connectivity in Carbaporphyrinoid Polymers on Metal Surfaces
Angewandte Chemie, EarlyView.Hydroxyl‐functionalized dicarbaporphyrinoid polymers synthesized on Au(111) enable tunable oxygen‐mediated connectivity under UHV conditions. Thermal activation yields one‐dimensional hydroxyl‐terminated polymers that can selectively evolve into either covalently‐linked dibenzo‐p‐dioxane architectures through intermolecular C–O–C coupling or two‐fold ...
Alberto Martínez‐Bajo +14 more
wiley +2 more sources
Leaching of Some Lanthanides from Phosphogypsum Fertilizers by Mineral Acids
, 2015 The phosphate rock contains trace amounts of uranium and lanthanides. When treating this rock with H2SO4 produces phosphoric acid together with 5 times of its quantity of phosphogypsum (PG) precipitate as a by-product.
F Abdel Hai +4 more
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InorganicsApplications of lanthanide chemistry have been successful in metallics and the petroleum industry. In the medical realm, lanthanides have shown utility in radiotherapy agents, photodynamic therapy agents, and magnetic resonance imaging (MRI) contrast ...
David C. Platt +5 more
doaj +1 more source