Results 81 to 90 of about 16,640 (300)

Lanthanides — Phthalocyanines complexes : from a diphthalocyanine Pc

open access: yes, 2017
Lanthanide-phthalocyanine adducts PcyLnx have been synthetized for Ln = La, Nd, Eu, Gd, Dy, Yb and Lu. The analysis of their spectroscopic properties and of their behavior under chemical oxidation and reduction suggests that whereas a diphthalocyanine ...
J. Roncali, M. M'Sadak, F. Garnier
core   +1 more source

Hydration counteracts the separation of lanthanides by solvent extraction

open access: yes, 2020
The extraction of lanthanides from aqueous nitrate solutions by quaternary ammonium nitrate ionic liquids (e.g., [A336][NO3]) shows a negative sequence (i.e., light lanthanides are more efficiently extracted than heavy lanthanides), which conflicts with ...
Li, Zheng, Binnemans, Koen
core   +1 more source

Luminescence and Photochromism in Lanthanide‐Doped Hackmanites

open access: yesAdvanced Optical Materials, EarlyView.
Lanthanide‐doped lithium hackmanite derivatives are prepared utilizing a doped LiAlSiO4 precursor to modify luminescent and photochromic properties. Upon UV excitation, europium doping results in green Eu2+ persistent luminescence from shallow traps. Contrarily, samarium doping induces unusual near‐infrared photochromism.
Joshua Baggott   +7 more
wiley   +1 more source

Antenna Effect in Halogen‐Containing ZnSm Coordination Compounds: Utilizing Colorimetry for a Room‐Temperature Tunable Ratiometric Molecular Thermometer

open access: yesAdvanced Science, EarlyView.
The ZnSm‐Cl dinuclear molecular complex was synthesized through a simple one‐pot method. ZnL and Sm3+ exhibit complementary temperature‐dependent emission As the temperature increases, a noticeable color difference of ZnSm‐Cl can be observed within the room temperature range of 253‐333 K.
Ye Xia   +7 more
wiley   +1 more source

Lattice dynamics of lanthanides

open access: yes, 1979
Les fréquences de phonons des deux lanthanides Tb et Ho ont été calculées à partir du modèle de potentiel non local des métaux de terres rares d'upadhyaya et Animalu, qui prend en compte les termes linéaires en E et k.q dans le développement de Taylor du
J.C. Upadhyaya
core   +1 more source

A New Customizable Surfactant LLPS Strategy for Sustainable and Highly Efficient Radioactive Metal Ion Separation

open access: yesAdvanced Science, EarlyView.
A diluent‐free, customizable liquid–liquid phase separation (LLPS) platform enables highly efficient radioactive metal ion extraction and stripping. By encapsulating hydrophobic extractants into an ionic surfactant‐rich condensed phase, this LLPS system leverages synergistic electrostatic and coordination interactions.
Ruihan Yan   +7 more
wiley   +1 more source

Enrichment of lanthanides in aragonite

open access: yes, 2009
Using the constant addition technique, the coprecipitation of lanthanum, gadolinium, and lutetium with aragonite in seawater was experimentally investigated at 25 degrees C.
Lu Bo, Liu Gang, Qu Chengli
core  

Light‐Switched Mesenchymal Stem Cells for In Situ Exosome Amplification in Craniofacial Bone Defect Reconstruction

open access: yesAdvanced Science, EarlyView.
Light‐switchable MSCs (MSC‐UCNPs) were constructed by intracellular incorporation of UCNPs. Upon 980 nm irradiation, UCNPs emitted localized ultraviolet light (365 nm), activating the ROS/HEXB/LAMP1 signaling pathway to suppress lysosome–multivesicular body fusion and thereby enhance exosome biogenesis. Embedded within an injectable hydrogel, MSC‐UCNPs
Tingting Wu   +7 more
wiley   +1 more source

Temperature‐Driven Emission Redistribution of Yb2+ in SrB4O7 Enables Highly Sensitive Optical Thermometry Supported by Multiple Linear Regression

open access: yesAdvanced Science, EarlyView.
A novel optical thermometer exploits the rare UV emission of Yb2+ ions in a SrB4O7 host, enabling highly sensitive, non‐contact temperature measurements from 80 to 420 K. The applied multiple linear regression (MLR) analysis results in a multiple increase in the resulting temperature sensitivity.
Fang Zhao   +6 more
wiley   +1 more source

Reverse Weak Polarity‐Induced Ordered Layer Control for Enhanced Second‐Harmonic Generation in Ultraviolet Nonlinear Optical Crystals

open access: yesAdvanced Science, EarlyView.
Reverse Weak Polarity‐Induced Ordered Layer Control strategy, optimizing the design of layered structures, has been successfully designed. By leveraging inhomogeneous field of units to replace isotropic fields of metal cations, polar layers realize controllable layer stacking via a “layer→linker→layer” polarity transfer.
Lingli Wu   +7 more
wiley   +1 more source

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