Results 61 to 70 of about 2,054 (165)

Morphological Control of Aurophilic Chains of Gold(I) Dithiolate Dimers With Alkali and Alkali Earth Cations

open access: yesChemistry – A European Journal, EarlyView.
Luminescent coordination polymers of Group 1 (Li, K, Cs) and 2 (Mg─Ba) cations with gold(I) iso‐maleonitriledithiolate ({Au2[S2C = C(CN)2]}2−) units were prepared; 1‐D aurophilic chains are present in all cases. The structures strongly depend on cation charge and size, with N‐cyano coordination observed in the Gp 1 and larger Gp 2 cations. Increasingly
Jefferson A. Pells   +2 more
wiley   +1 more source

Influence of Carboxylate Ligand Variation on Structure, Magnetic Exchange, and Magnetocaloric Performance in Hexanuclear Gd(III) Complexes

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT Hexanuclear cyclic Gd(III) coordination compounds are promising candidates for magnetic and magnetocaloric applications, yet systematic series remain rare due to synthetic challenges. We report the synthesis and characterization of five new complexes with the general formula [Gd(H3bt)(carboxylate)]6, employing four different carboxylate ...
Ondřej František Fellner   +7 more
wiley   +1 more source

Urothermal Synthesis of Luminescent Alkaline Earth MOFs

open access: yesChemistry – A European Journal, EarlyView.
The e‐murea derivative (1,3‐dimethylimidazolidin‐2‐one) was employed as solvent for the urothermal synthesis of a series of nine AE MOFs featuring luminescence in the crystalline state with remarkable quantum yields ranging from 0.45 to 0.84. ABSTRACT The urothermal approach in 1,3‐dimethylimidazolidin‐2‐one (e‐murea) was employed for the successful ...
Michaël Teixeira, Stéphane A. Baudron
wiley   +1 more source

Thermodynamic Assessment of the La-Fe-O System [PDF]

open access: yes, 2018
The La-Fe and the La-Fe-O systems are assessed using the Calphad approach, and the Gibbs energy functions of ternary oxides are presented. Oxygen and mutual La and Fe solubilities in body-centered cubic (bcc) and face-centered cubic (fcc) structured ...
Chen, M.   +4 more
core   +1 more source

Heterogeneous Single/Dual‐Atom Electrocatalysts in Lithium–Sulfur Batteries

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This review summarizes recent advances in single‐atom and dual‐atom electrocatalysts for high‐performance lithium–sulfur batteries. The text systematically covers the classification of catalysts by active metal centers, key synthesis methods, in situ characterization for mechanistic insights, and electrocatalytic mechanisms.
Wenbin Li   +3 more
wiley   +1 more source

Depolymerization and Reuse of Polycarbonates: Emerging Classes, Mechanisms and Challenges

open access: yesAngewandte Chemie, Volume 138, Issue 19, 4 May 2026.
This review collects the latest developments in the area of chemical and catalytic polycarbonate recycling strategies and includes the controlled degradation of similar types of macromolecules. Apart from the main strategies for deconstruction, the key mechanistic features of these depolymerization processes are also discussed together with the ...
Davide Rigo   +4 more
wiley   +2 more sources

Fractionation of Milligram Quantities of Gadolinium and Terbium Ions by Annular Free‐Flow Isotachophoresis

open access: yesELECTROPHORESIS, EarlyView.
ABSTRACT The fractionation of milligram quantities of gadolinium (Gd) and terbium (Tb) ions is demonstrated using annular free‐flow isotachophoresis (ITP) with ammonium as the leading ion and hydronium as the terminating ion, and α‐hydroxyisobutyric acid (HIBA) and acetate as lanthanide complexing ligands.
Hannah Hallikainen   +2 more
wiley   +1 more source

Chiral supramolecular electronics for high‐efficiency circularly polarized organic light‐emitting diodes

open access: yesFlexMat, EarlyView.
This perspective highlights supramolecular strategy for achieving band‐level chirality in vacuum‐deposited triazatruxene thin films, enabling circularly polarized organic light‐emitting diodes (OLEDs) with both high dissymmetry factor and external quantum efficiency, thereby overcoming the longstanding efficiency‐dissymmetry trade‐off in circularly ...
Xiang‐Chun Li   +3 more
wiley   +1 more source

Enhanced CO2 reduction to multi‐carbon products on CuLa bimetallic catalyst

open access: yesInfoMat, EarlyView.
Electrochemical CO2 reduction offers a promising approach for carbon utilization while is limited by selectivity toward multi‐carbon products. In this work, we developed CuLa catalysts, which significantly improved C2+ selectivity towards around 75% under 200 mA cm−2.
Di Wang   +7 more
wiley   +1 more source

Critical evaluation of stability constants of metal complexes of complexones for biomedical and environmental applications* (IUPAC Technical Report) [PDF]

open access: yes, 2017
Available experimental data on stability constants of proton (hydron) and metal complexes for seven complexones of particular biomedical and environmental interest: iminodiacetic acid [2,2'-azanediyldiacetic acid, IDA], (methylimino)diacetic acid [2,2 ...
Anderegg, Giorgio   +4 more
core  

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