Results 81 to 90 of about 2,054 (165)

Eu(II) Complexes as Model Systems for Spin‐Only Metal Polarizing Agents for Solid Effect DNP

open access: yesAnalysis &Sensing, Volume 6, Issue 3, May 2026.
This study introduces Eu(II)‐[2.2.2]cryptand as a model polarizing agent for solid effect dynamic nuclear polarization (DNP). By analyzing the roles of nuclear spin (I = 5/2) and zero‐field splitting in an S = 7/2 system, the authors reproduce electron paramagnetic resonance (EPR) and DNP behavior across various field strengths.
Florian Taube   +3 more
wiley   +1 more source

Lanthanide Monoporphyrinates and Complexes With a Schiff Base Derivative: Thermodynamic Stability and Bioimaging Capabilities

open access: yesChemistry–Methods, Volume 6, Issue 5, May 2026.
This study provides new data for the stability constants of lanthanide complexes using spectrometric methods with different approaches, considering the stability differences. Clinical applications ranging from magnetic resonance imaging to cancer therapy are more relying on the use of lanthanide coordination compounds.
Wanqi Zhou   +5 more
wiley   +1 more source

Quantitative Real‐Time MRI for the Assessment of Gastric Motility

open access: yesJournal of Magnetic Resonance Imaging, Volume 63, Issue 5, Page 1482-1495, May 2026.
ABSTRACT Background Current reference standards for measuring gastric emptying and motility are not considered optimal due to the time required, ionizing radiation, invasiveness, and spatial resolution. Purpose To assess gastric motility using novel real‐time dynamic magnetic resonance imaging in combination with static measurements for gastric ...
Lydia Neubauer   +14 more
wiley   +1 more source

Hybrid Modification Strategies of Metal–Organic Frameworks: A Review on Structural Design and Environmental Applications

open access: yesChemistryOpen, Volume 15, Issue 5, May 2026.
This review examines how hybrid modification strategies enhance the structural design and environmental performance of metal–organic frameworks (MOFs). It outlines key synthesis routes, functionalization approaches, and integration with complementary materials, highlighting advances in pollutant removal, sensing, and sustainable remediation.
Samar H. Elagamy   +3 more
wiley   +1 more source

Synergistic Photophysical and Mechanical Enhancement in Europium Supramolecular Hydrogel by Incorporating Gd(DPA)3 Complex (DPA = Dipicolinate)

open access: yesChemistryOpen, Volume 15, Issue 5, May 2026.
Lanthanide‐based hydrogels incorporating Ln(DPA)3 complexes are synthesized and exhibit enhanced mechanical and luminescent properties. Increased complex concentration improves stiffness and emission intensity without altering coordination symmetry. Computational insights reveal preserved structural features, while lifetime changes highlight hydrogel ...
Caroliny O. Cavalcante   +7 more
wiley   +1 more source

Membrane Vesicle Formation Removes Iron Sulfide Mineral Crusts From the Cell Surface of Growing Sulfate‐Reducing Bacteria

open access: yesGeobiology, Volume 24, Issue 3, May/June 2026.
ABSTRACT Sulfate‐reducing bacteria (SRB) drive the process of sulfate reduction in low‐temperature sedimentary environments. Through the production of sulfide, they promote the formation of iron‐sulfide (Fe‐S) minerals when Fe(II) is available. The negative charge of the cell surface of bacteria can promote the binding of Fe(II), leading to the ...
Cheyenne Brokaw   +2 more
wiley   +1 more source

Zwitterionic Mn(III)‐Tetraphenyl Porphyrins: Water‐Soluble MRI Contrast Agents with High Relaxivity

open access: yesChemMedChem, Volume 21, Issue 8, 28 April 2026.
Mn(III)‐based contrast agents (MBCAs) are promising and potentially safer alternatives to the Gd(III)‐based contrast agents (GBCAs) currently used in MRI. This study reports the synthesis, physicochemical characterization and first in vivo application of novel Mn(III)‐tetraphenylporphyrin chelates, bearing zwitterionic sulfobetaine or N‐oxide groups ...
Darius Ludolfs   +10 more
wiley   +1 more source

Pheophytinisation of eight chlorophyll derivatives in aqueous acetone [PDF]

open access: yes, 1992
Mazaki, Hitoshi   +4 more
core   +1 more source

Inorganic Photoluminescent Microparticles as Identifiers for the Sorting of Lithium‐Ion Battery Cathodes

open access: yesChemSusChem, Volume 19, Issue 8, 28 April 2026.
The growing demand for lithium‐ion batteries in the European Union contributes to critical raw material scarcity. This challenge can be addressed by establishing a circular economy, making use of highly efficient and economical recycling processes. The efficiency of these processes depends on high‐purity material streams and thus on the availability of
Simon Ziegler   +4 more
wiley   +1 more source

Multiple Dimerization Modes in Thiocarboxylate Paddlewheel Complexes: A Comprehensive View of Energy Landscapes from DFT Calculations and Statistics

open access: yesChemistry – A European Journal, Volume 32, Issue 15, 22 April 2026.
Staggered, square, and heavily bent dimers occur in the five known solvatomorphs of paddlewheel (PW) complex [PtVO(SOCPh)4]. These and other structural motifs are well within energetic reach due to the shallow potential energy surface that guides dimerization and are included in a revised classification of available structural data on heterobimetallic ...
Olga Mironova   +3 more
wiley   +1 more source

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