Results 81 to 90 of about 2,062 (193)
Chemistry – A European Journal, EarlyView.Staggered, square, and heavily bent dimers occur in the five known solvatomorphs of paddlewheel (PW) complex [PtVO(SOCPh)4]. These and other structural motifs are well within energetic reach due to the shallow potential energy surface that guides dimerization and are included in a revised classification of available structural data on heterobimetallic ...
Olga Mironova +3 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.One‐pot transition‐metal‐free methods for the synthesis of all three bonds of the alkyne's triple bond are reviewed. After analysis of several named reactions and discussion of improvements, recent advances in the synthesis of alkynes are discussed. Each section contains a proposed reaction mechanism and analysis of the strengths and weaknesses of the ...
Eugene Kim +4 more
wiley +1 more source
Distinct Ligand‐ and Metal‐Centered Phosphorescence in a Terbium Carbazolyl Complex
Chemistry – A European Journal, EarlyView.Terbium and lanthanum carbazolide complexes show two distinct modes of luminescence: Strongly temperature‐dependent narrow‐line terbium emission could be induced. In addition, both the terbium and the lanthanum complexes show broad‐line interligand emission processes with excited states of microsecond life‐time.
Xiaofei Sun +9 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.It is a challenge to improve the selectivity of high‐denticity ligands for Mg2+ over Ca2+. We show that in aryl‐alkynyl derivatives of APTRA, electron‐withdrawing substituents lower the binding affinity for Ca2+ more than Mg2+, making the ligand more selective for Mg2+.
Laura L. Duncan +2 more
wiley +1 more source
Lanthanoid complexes of tetrazolyl-functionalised Calix[4]arenes [PDF]
, 2015 Syntheses of the bis-, tris- and tetra-tetrazolato calix[4]arene ligands were performed from their corresponding nitrile derivatives. Mono-nuclear lanthanoid complexes were characterised in the presence of triethylamine, while addition of aqueous ...
D'Alessio, Daniel Mark
core
Silent Partners in the Mill: Unveiling the Role of Additives in Mechanochemical Synthesis
Chemistry – A European Journal, EarlyView.Mechanochemistry offers a sustainable, solvent‐free alternative to traditional synthesis, often enhanced by additives in a process known as additive‐assisted grinding. This review discusses how various additives, including liquids, ionic solids, and advanced materials like ionic liquids and piezoelectric compounds, improve reaction efficiency ...
Johanna Breinsperger +3 more
wiley +1 more source
Photocatalytic Degradation of PFOA with Porous Lanthanoid Perovskites Nano Catalyst
Chemie Ingenieur Technik, EarlyView.Photocatalytic degradation of PFOA was studied using nickel‐ and lanthanide‐doped perovskites under UV–VIS irradiation. Catalyst characterization confirmed successful doping, with Ni/NdMnO3 showing the highest photocatalytic efficiency. Degradation occurred via C–C bond cleavage, forming transformation products PFHpA and PFHxA.
Julia Schowarte +5 more
wiley +1 more source
ChemPhysChem, EarlyView.A computational strategy to compute the energy of the triplet excited state in europium‐based coordination complexes is presented. This method allows for in silico screening of new systems with can be used as photosensitizers in solar cell‐based technologies.
Laura Sánchez‐Muñoz +3 more
wiley +1 more source
FlexMat, EarlyView.Abstract Salicylic acid (SA), a widely distributed environmental pollutant, requires accurate detection for effective water quality monitoring and ecological protection. In this work, we developed a highly sensitive fluorescent sensor by encapsulating boron‐doped graphene quantum dots (B‐GQDs) within amino‐functionalized lanthanum‐based metal‐organic ...
Wenkai Yu +7 more
wiley +1 more source