Results 81 to 90 of about 6,573,124 (276)

Silatranylnitrilium Hexachloridoantimonate, its Brønsted Base‐Assisted CC‐Bond Formation and Transformation to an Unprecedented Carbene‐Type SbCl5 Complex

open access: yesChemistryEurope, EarlyView.
Reacting 1‐hydridosilatrane with triphenylcarbenium hexachloridoantimonate in acetonitrile solution and in the presence of 4‐dimethylaminopyridine combines the world of silatranes with the world of carbenes, giving an unprecedented carbene‐type antimony pentachloride complex. This finding offers a new playground for exciting new chemistry.
David Mroß   +7 more
wiley   +1 more source

New skew Laplacian energy of simple digraphs [PDF]

open access: yesTransactions on Combinatorics, 2013
For a simple digraph $G$ of order $n$ with vertex set${v_1,v_2,ldots, v_n}$, let $d_i^+$ and $d_i^-$ denote theout-degree and in-degree of a vertex $v_i$ in $G$, respectively.
Qingqiong Cai, Xueliang Li, Jiangli Song
doaj  

On the Laplacian Coefficients and Laplacian-Like Energy of Unicyclic Graphs with n Vertices and m Pendent Vertices

open access: yesJournal of Applied Mathematics, 2012
Let Φ(G,λ)=det(λIn-L(G))=∑k=0n(-1)kck(G)λn-k be the characteristic polynomial of the Laplacian matrix of a graph G of order n. In this paper, we give four transforms on graphs that decrease all Laplacian coefficients ck(G) and investigate a conjecture A.
Xinying Pai, Sanyang Liu
doaj   +1 more source

The Conformational Electrostatic Potential as Predictor for the Influence of Fluorination on Alcohol Hydrogen Bonding: Identification of a CF2H‐Mediated Cooperative Effect

open access: yesChemistryEurope, EarlyView.
With a little help… OH•••F intramolecular hydrogen bonding (HB) strongly reduces alcohol HB acidity, resulting in underestimation of predicted HB acidity based on the molecular Kenny electrostatic potential. In contrast, CF2H–OH intramolecular interaction causes a positive cooperative effect leading to HB acidity enhancement, as revealed by ...
Zhong Wang   +8 more
wiley   +1 more source

White Phosphorus Activation with Cobalt–Zinc Complexes: Access to Phosphorus‐Rich Sandwich Compounds

open access: yesChemistryEurope, EarlyView.
Heterometallic complexes showcasing Co–Zn interactions have been synthesized through straightforward salt metathesis methods. Their reaction with white phosphorus yields a dimeric sandwich complex containing bridging P2 units. A stepwise mechanism for its formation is proposed, supported by the isolation of intermediates.
Marco D. Fritz   +3 more
wiley   +1 more source

Iron‐Photocatalyzed Anti‐Markovnikov Hydrochlorination of Alkenes Based on Ligand‐to‐Metal Charge Transfer

open access: yesChemistryEurope, EarlyView.
Ligand‐to‐metal charge transfer photocatalysis and benzenethiol‐based hydrogen atom transfer catalysis are integrated to develop an iron‐promoted anti‐Markovnikov hydrochlorination of alkenes with hydrochloric acid. The results of experimental and theoretical analyses provide fundamental insights into reactivity control, paving the way for future ...
Subrata Mukherjee   +3 more
wiley   +1 more source

Seidel Laplacian energy of bipolar fuzzy graphs and enhanced score functions for decision-making applications

open access: yesAIMS Mathematics
Bipolar fuzzy sets (BPFs) provide a suitable framework for knowledge representation if some data contains imprecise and ambiguous information. In this manuscript, the lower and upper bounds of the Seidel Laplacian energy of a bipolar fuzzy graph were ...
Sivaranjani Krishnaraj   +3 more
doaj   +1 more source

Bounds of Laplacian Energy of a Hypercube Graph

open access: yesInternational journal of engineering and technology, 2018
Let  Qn denote  the n – dimensional  hypercube  with  order   2n and  size n2n-1. The  Laplacian  L  is defined  by  L = D  where D is  the  degree  matrix and  A is  the  adjacency  matrix  with  zero  diagonal  entries.  The  Laplacian  is a  symmetric 
K. Bibi   +2 more
semanticscholar   +1 more source

Side‐on Coordination in Fluorido Difluoroamido Complexes FMNF2 of Heavy Alkaline Earth Metals (M = Ca, Sr, Ba)

open access: yesChemistry – A European Journal, EarlyView.
Fluorido difluoroamido complexes F'MNF2 of heavy alkaline earth metals (M = Ca, Sr, Ba) were prepared through the reactions of laser‐ablated metal atoms with NF3 and isolated under cryogenic conditions in neon and argon matrices. The species feature a F'−− and a side‐on coordinated η3‐NF2− ligand with the F'−M−N angle decreasing from calcium to barium.
Xiya Xia, Robert Medel, Sebastian Riedel
wiley   +1 more source

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