Results 61 to 70 of about 11,443 (267)

Anionic T‐Shaped Platinum(0) Pincer Complexes and Platinum(I) Intermediates in Radical Reactions With Alkyl Halides

Angewandte Chemie, EarlyView.
Two anionic, T‐shaped, d10 platinum(0) complexes containing a PNP pincer ligand have been isolated and characterized. These complexes react with aliphatic C‐Br bonds under formation of a platinum(II) bromide and an alkyl complex, as well as the homocoupled hydrocarbons.
Vincenz J. Kohler, Julia Rößling, Tim M. Diederich, Joachim Ballmann, Regine Herbst‐Irmer, Dietmar Stalke, Lutz H. Gade   +6 more
wiley   +2 more sources

A decision-making model based on energy concepts in Fermatean Quadripartitioned Neutrosophic fuzzy graphs [PDF]

Mathematics and Computational Sciences
Fermatean Quadripartitioned Neutrosophic fuzzy graphs (FQNFG) is the integrating form of Fermatean and Quadripartitioned Neutrosophic fuzzy graphs. Graph energy is recognized as a crucial concept in fuzzy graph theory for its ability to handle random ...
Divya Venkatesan, Jesintha Rosline Jesuraj, Anthoni Amali Asir, Chellamani Perumal   +3 more
doaj   +1 more source

Investigation of the Main Energies of Picture Fuzzy Graph and its Applications

International Journal of Computational Intelligence Systems, 2022
Picture fuzzy graph, belonging to fuzzy graphs family, has good capabilities at times when we are faced with problems that cannot be expressed by fuzzy graphs and intuitionistic fuzzy graphs.
Xiaolong Shi, Saeed Kosari, Ali Asghar Talebi, Seyed Hossein Sadati, Hossein Rashmanlou   +4 more
doaj   +1 more source

Beyond Electrostatics: Anion‐π+ Orbital Hybridization Underpins High‐Performance Chloride Storage in Poly(arylamine) Organic Cathodes

Advanced Science, EarlyView.
The fundamental nature of anion storage in p‐type organic cathodes is elucidated using rigid poly(arylamine) frameworks. This study reveals a hybrid covalent‐ionic mechanism for anion‐π+ interactions, driven by synergistic orbital hybridization and electrostatic attraction.
Tiantian She, Jiena Weng, Jie Wang, Qiao Xi, Yangyang Zhang, Zijie Zhang, Zongqiong Lin, Wei Huang   +7 more
wiley   +1 more source

Nucleophilic Gallyl Anions Enable Ga─Au Bimetallic Ammonia Activation

Angewandte Chemie, EarlyView.
Unlocking gallyl nucleophiles: Counterion control enables formation of an unsupported gallyl─gold complex. Gold coordination induces a polarity switch at gallium, enabling cooperative activation of NH3 and related N─H/O─H substrates under mild conditions.
Hellen Videa, Keelan M. Byrne, Tobias Krämer, Antonio J. Martínez‐Martínez   +3 more
wiley   +2 more sources

Strain Tuning the Occupation of Candidate Topological Weyl States in W‐Doped MoTe2

Advanced Science, EarlyView.
The present study investigates strain‐induced modifications of the electronic structure in the Weyl semimetal Td${\rm T}_d$‐Mo0.91W0.09Te2${\mathrm{Mo}}_{0.91}{\mathrm{W}}_{0.09}{\mathrm{Te}}_{2}$ using hard X‐ray angle‐resolved photoemission spectroscopy.
Amon Lanz, Olena Tkach, Yaryna Lytvynenko, Florian Diekmann, Harshit Agarwal, Sofia Michaela Souliou, Mehdi Frachet, Michael Merz, Sergii V. Chernov, Andrei Gloskovskii, Volkmar Koller, Dmytro Kutnyakhov, Moritz Hoesch, Christoph Schlueter, Philipp Rüssmann, Yuriy Mokrousov, Matthieu Le Tacon, Kai Rossnagel, Jure Demsar, Gerd Schönhense, Hans‐Joachim Elmers, Olena Fedchenko   +21 more
wiley   +1 more source

Surface Energy Modulated Self‐Assembly of Percolative Gallium Nanodroplet Films for Stretchable Electronics

Advanced Electronic Materials, EarlyView.
Surface‐energy guided self‐assembly of liquid metals enables the transformation of liquid metal micro/nanodroplets into continuous perocolative films on elastomeric substrates. By tailoring interfacial energetics and wetting behavior, uniform, conductive, and stretchable films are achieved, offering scalable pathways for high‐performance soft ...
Alwar Samy Ramasamy, Gayatri Subhalaxmi, Sneha Banerjee, Mark Vailshery, Renu Raman Sahu, Sivakumar K.S, Ajisha Chathyattu, Tapajyoti Das Gupta   +7 more
wiley   +1 more source

Potassium‐Ligand Cooperation Facilitated Chemical Bond Activation and Catalytic Hydrogenation

Angewandte Chemie, EarlyView.
A new strategy for alkali metal‐mediated catalysis based on metal–ligand cooperation (MLC) is presented. Potassium pincer complexes exhibit remarkable reactivity toward a range of molecules via an unprecedented potassium–ligand cooperative mechanism. This reactivity enables potassium‐catalyzed hydrogenation, providing efficient reduction of ketones and
Yaoyu Liang, Irena Efremenko, Thiyagarajan Subramanian, Amit Kumar, Liat Avram, Yael Diskin‐Posner, David Milstein   +6 more
wiley   +2 more sources

A Note on the Laplacian Energy of the Power Graph of a Finite Cyclic Group

Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi
In this study, the Laplacian matrix concept for the power graph of a finite cyclic group is redefined by considering the block matrix structure. Then, with the help of the eigenvalues of the Laplacian matrix in question, the concept of Laplacian energy ...
Şerife Büyükköse, Nurşah Mutlu Varlıoğlu   +1 more
doaj   +1 more source

Solutions for the Problems Involving Fractional Laplacian and Indefinite Potentials

Advanced Nonlinear Studies, 2017
In this paper, we consider a class of Schrödinger equations involving fractional Laplacian and indefinite potentials. By modifying the definition of the Nehari–Pankov manifold, we prove the existence and asymptotic behavior of least energy solutions.
Tang Zhongwei, Wang Lushun
doaj   +1 more source